Answer
Verified
389.1k+ views
Hint: To prepare the diethyl ketone one can think about the methods which use relevant alcohol for the preparation and a suitable reagent must be used for that. The decarboxylation means a process in which removal of the carbon dioxide group takes place. One can use the reagent used for decarboxylation of acetophenone.
Complete step by step answer:
i) First of all we will prepare the Diethyl ketone: The diethyl ketone has five carbon in it having carbonyl group at the center. Hence, we can obtain this by oxidation of the alcohol group of secondary alcohol i.e. $3 - $pentanol. For this reaction to happen one can use any oxidizing agent such as ${K_2}C{r_2}{O_7}$ and the reaction will go as follows.
$C{H_3} - C{H_2} - CH(OH) - C{H_2}C{H_3} + \left[ O \right]\xrightarrow[{{H_2}S{O_4}}]{{{K_2}C{r_2}{O_7}}}{C_2}{H_5} - CO - {C_2}{H_5} + {H_2}O$
ii) Now let us see the reaction of preparation of acetophenone from the decarboxylation method: The anhydrous calcium benzoate and dry calcium acetate which is acetic acid derivative are blended and this blend is brought into an iron cylinder which is closed toward one side and appended by a long air condenser to a beneficiary. The cylinder is warmed very strongly and the product formed is acetophenone. The decarboxylation means a process in which the removal of the carbon dioxide group happens as a byproduct. The reaction scheme is shown below,
Note:
The oxidizing agent used for the preparation of diethyl ketone is ${K_2}C{r_2}{O_7}$ which is commonly used for oxidation of only primary and secondary alcohols to form relevant aldehydes and ketones respectively. The dry calcium acetate which is a calcium salt of acetic acid and this anhydrous structure is exceptionally hygroscopic which leads to decarboxylation.
Complete step by step answer:
i) First of all we will prepare the Diethyl ketone: The diethyl ketone has five carbon in it having carbonyl group at the center. Hence, we can obtain this by oxidation of the alcohol group of secondary alcohol i.e. $3 - $pentanol. For this reaction to happen one can use any oxidizing agent such as ${K_2}C{r_2}{O_7}$ and the reaction will go as follows.
$C{H_3} - C{H_2} - CH(OH) - C{H_2}C{H_3} + \left[ O \right]\xrightarrow[{{H_2}S{O_4}}]{{{K_2}C{r_2}{O_7}}}{C_2}{H_5} - CO - {C_2}{H_5} + {H_2}O$
ii) Now let us see the reaction of preparation of acetophenone from the decarboxylation method: The anhydrous calcium benzoate and dry calcium acetate which is acetic acid derivative are blended and this blend is brought into an iron cylinder which is closed toward one side and appended by a long air condenser to a beneficiary. The cylinder is warmed very strongly and the product formed is acetophenone. The decarboxylation means a process in which the removal of the carbon dioxide group happens as a byproduct. The reaction scheme is shown below,
Note:
The oxidizing agent used for the preparation of diethyl ketone is ${K_2}C{r_2}{O_7}$ which is commonly used for oxidation of only primary and secondary alcohols to form relevant aldehydes and ketones respectively. The dry calcium acetate which is a calcium salt of acetic acid and this anhydrous structure is exceptionally hygroscopic which leads to decarboxylation.
Recently Updated Pages
Basicity of sulphurous acid and sulphuric acid are
Three beakers labelled as A B and C each containing 25 mL of water were taken A small amount of NaOH anhydrous CuSO4 and NaCl were added to the beakers A B and C respectively It was observed that there was an increase in the temperature of the solutions contained in beakers A and B whereas in case of beaker C the temperature of the solution falls Which one of the following statements isarecorrect i In beakers A and B exothermic process has occurred ii In beakers A and B endothermic process has occurred iii In beaker C exothermic process has occurred iv In beaker C endothermic process has occurred
What is the stopping potential when the metal with class 12 physics JEE_Main
The momentum of a photon is 2 times 10 16gm cmsec Its class 12 physics JEE_Main
How do you arrange NH4 + BF3 H2O C2H2 in increasing class 11 chemistry CBSE
Is H mCT and q mCT the same thing If so which is more class 11 chemistry CBSE
Trending doubts
Difference Between Plant Cell and Animal Cell
Difference between Prokaryotic cell and Eukaryotic class 11 biology CBSE
Fill the blanks with the suitable prepositions 1 The class 9 english CBSE
Change the following sentences into negative and interrogative class 10 english CBSE
Summary of the poem Where the Mind is Without Fear class 8 english CBSE
Give 10 examples for herbs , shrubs , climbers , creepers
Write an application to the principal requesting five class 10 english CBSE
What organs are located on the left side of your body class 11 biology CBSE
What is the z value for a 90 95 and 99 percent confidence class 11 maths CBSE