Answer
Verified
398.7k+ views
Hint: Think about why metals react with alcohol. Which property of alcohol is responsible for the reaction of alcohols and metals? Think about the electron density on the oxygen of the alcohol group in primary, secondary, and tertiary alcohols.
Complete step by step solution:
We know that alcohols react with active metals e.g. Na, K, etc. to give corresponding alkoxides. Alcohols contain hydrogen attached to oxygen. Compounds containing hydrogen attached more electronegative elements such as oxygen are acidic. Alcohols are acids but their acidic strength is very less. So, alcohol does not take place in the reactions in which acids take place.
Sodium metal reacts with alcohol and liberates hydrogen. But the order of reactivity depends on the acidic strength of the alcohol. Acids with higher acidic strength react with sodium faster than weaker acids. We need to identify the acidic strength of primary, secondary, and tertiary alcohols.
In tertiary alcohols connected alkyl groups pump the electron density towards the oxygen of alcohol this reduces the acidic strength of alcohol. So, as the alkyl groups on carbon connected to the alcohol group increases the acidic strength of that alcohol decreases. So, the reactivity of sodium towards alcohol will be primary > secondary > tertiary alcohols.
Note: Na, K are highly electropositive metals which react with acids and liberate hydrogen. Though alcohols are weak acids, the strong electropositive character of Na, K allows them to react with alcohol and release hydrogen gas.
Complete step by step solution:
We know that alcohols react with active metals e.g. Na, K, etc. to give corresponding alkoxides. Alcohols contain hydrogen attached to oxygen. Compounds containing hydrogen attached more electronegative elements such as oxygen are acidic. Alcohols are acids but their acidic strength is very less. So, alcohol does not take place in the reactions in which acids take place.
Sodium metal reacts with alcohol and liberates hydrogen. But the order of reactivity depends on the acidic strength of the alcohol. Acids with higher acidic strength react with sodium faster than weaker acids. We need to identify the acidic strength of primary, secondary, and tertiary alcohols.
In tertiary alcohols connected alkyl groups pump the electron density towards the oxygen of alcohol this reduces the acidic strength of alcohol. So, as the alkyl groups on carbon connected to the alcohol group increases the acidic strength of that alcohol decreases. So, the reactivity of sodium towards alcohol will be primary > secondary > tertiary alcohols.
Note: Na, K are highly electropositive metals which react with acids and liberate hydrogen. Though alcohols are weak acids, the strong electropositive character of Na, K allows them to react with alcohol and release hydrogen gas.
Recently Updated Pages
Basicity of sulphurous acid and sulphuric acid are
Three beakers labelled as A B and C each containing 25 mL of water were taken A small amount of NaOH anhydrous CuSO4 and NaCl were added to the beakers A B and C respectively It was observed that there was an increase in the temperature of the solutions contained in beakers A and B whereas in case of beaker C the temperature of the solution falls Which one of the following statements isarecorrect i In beakers A and B exothermic process has occurred ii In beakers A and B endothermic process has occurred iii In beaker C exothermic process has occurred iv In beaker C endothermic process has occurred
What is the stopping potential when the metal with class 12 physics JEE_Main
The momentum of a photon is 2 times 10 16gm cmsec Its class 12 physics JEE_Main
How do you arrange NH4 + BF3 H2O C2H2 in increasing class 11 chemistry CBSE
Is H mCT and q mCT the same thing If so which is more class 11 chemistry CBSE
Trending doubts
Difference Between Plant Cell and Animal Cell
Difference between Prokaryotic cell and Eukaryotic class 11 biology CBSE
Fill the blanks with the suitable prepositions 1 The class 9 english CBSE
Change the following sentences into negative and interrogative class 10 english CBSE
Summary of the poem Where the Mind is Without Fear class 8 english CBSE
Give 10 examples for herbs , shrubs , climbers , creepers
Write an application to the principal requesting five class 10 english CBSE
What organs are located on the left side of your body class 11 biology CBSE
What is the z value for a 90 95 and 99 percent confidence class 11 maths CBSE