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The ratio between the root mean square velocity of H2 at 50K and that of O2 at 800K is:
(a) 0.25
(b) 1
(c) 2
(d) 4

Answer
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Hint: The root mean square velocity is the measure of the speed of a particle in a gas. We can solve the above problem by using the formula 3RTM

Complete step by step answer:
1: The root mean square velocity or vrms is directly proportional to the square root of temperature and is inversely proportional to the square root of molecular weight.
2: Now, we calculate vrms of H2 at 50K using the formula 3RTM
Where, R is the universal gas constant (8.314 J mol-1 K-1 )
     T is the temperature, here it is 50K
     M is the molecular mass which is 2 g/mol for H2
vrmsfor H2 is =3R×502
vH2=75R
(Since R is common in both and we need to calculate the ratio, we will leave it as R for simplicity and it will get cancelled at the end.)
3: Similarly,vrmsfor O2 is =3R×80032 (Since molecular mass of O2 IS 32 g/mol)
vO2=75R
4: Now taking the ratio between vH2 and vO2 , we get:
vH2vO2=75R75RvH2vO2=1
Thus, the correct option is (a).

Note:
We mostly use vrmsinstead ofvavgbecause for a typical gas sample, the net velocity is zero. This is because the particles are moving randomly constantly in all directions. This is a key formula as the velocity of the particles is what determines both the diffusion and effusion rates. The faster the root mean square velocity, the faster the diffusion. Effusion occurs by a difference of pressures while diffusion occurs due to difference in concentrations.