Courses for Kids
Free study material
Offline Centres

Methods of Preparation of Aldehydes and Ketones for JEE

Last updated date: 21st Feb 2024
Total views: 45.3k
Views today: 0.45k
hightlight icon
highlight icon
highlight icon
share icon
copy icon

Introduction to Carbonyl Compounds

We come across many organic compounds containing a (–C=O) group in our everyday life. Biomolecules such as protein, carbohydrate, etc. that make up all plants and animals contain carbonyl groups. The members of the aldehyde ketone and carboxylic acid group play an important role in the metabolic process. For example, pyridoxal, an aldehyde derived from vitamin B, functions as a coenzyme. Carbonyl compounds are  the main constituents of fabrics, plastic, and drugs. Formaldehyde (an aldehyde), which is used for the manufacture of bakelite and paracetamol drugs (p– acetylated aminophenol), a drug used to reduce fever, contains a carbonyl group. In this unit, we will learn about the preparation, properties, and uses of aldehyde, ketone, and carboxylic acid.

Nomenclature of Aldehydes and Ketones


(Common Name, Structural

Formula, IUPAC Name)


Prefix with

Position Number



Primary Suffix

Secondary Suffix














CH2 = CH – CHO

prop – 2- enal





CH3 – CH = CH – CHO

but – 2 – enal




Acetone / Dimethyl ketone

CH3 – CO – CH3





Mesityl oxide


4 – methylpent-3-en-2-one





Structure of Carbonyl Group

The carbonyl carbon ( –C=O) is sp2 hybridised and the carbon–oxygen bond is similar to carbon–carbon double bond in alkenes. The carbonyl carbon forms three σ bonds using their three sp2 hybridised orbital. One of the sigma bonds is formed with oxygen and the other two with hydrogen and carbon (in aldehydes) or with two carbons (in ketones). All the three 'σ' bonded atoms lie on the same plane as shown in image 1. 

The fourth valence electron of carbon remains in its unhybridized ‘2p’ orbital which lies perpendicular to the plane and overlaps with the 2p orbital of oxygen to form a carbon–oxygen p bond. The oxygen atom evidently has two nonbonding pairs of electrons, which will occupy its remaining two p-orbitals. Oxygen, the second most electronegative atom, attracts the shared pair of electrons between the carbon and oxygen towards itself. Hence, the bond is polar. This polarisation plays a major role in the reaction of aldehydes and ketones.

Structure of Carbonyl Group

Image 1: Structure of Carbonyl Group

Methods of Preparation of Aldehydes and Ketones

Preparation of Aldehydes and Ketones by Dehydrogenation of Alcohols

We know that generally the oxidation of primary alcohol gives aldehydes and secondary alcohol gives a ketone. Oxidising agents such as acidified Na2Cr2O7, KMnO4, and PCC are used for oxidation. Oxidation using PCC yields aldehydes. Other oxidising agents further oxidise the aldehydes / ketones into carboxylic acids. When vapours of alcohol are passed over heavy metal catalysts such as Cu and Ag, alcohols give aldehydes and ketones.

Ozonolysis of Alkenes to Form Aldehydes and Ketones

Alkenes react with ozone molecules to form ozonide, which on subsequent cleavage with zinc atoms and water give aldehydes and ketones. Zinc dust removes H2O2 formed, which otherwise can oxidise aldehydes/ketones. Terminal olefins give formaldehyde as one of the products.

Ozonolysis of Alkenes

Image 2: Ozonolysis of Alkenes

Hydration of Alkynes

We know that the hydration of alkynes in presence of 40% dilute sulfuric acid and 1% HgSO4 gives the corresponding aldehydes / ketones.

(i) Hydration of Acetylene Yields Acetaldehyde

Hydration of Acetylene

Image 3: Hydration of Acetylene

(ii) Hydration of Alkynes, Other than Acetylene gives Ketones

Hydration of Alkynes

Image 4: Hydration of Alkynes

(iii) From Calcium Salts of Carboxylic Acids

Aldehydes and ketones may be obtained by the dry distillation of calcium salts of carboxylic acid groups.

a) Aldehydes can be prepared when the mixture of calcium salt of carboxylic acid and calcium formate is subjected to dry distillation.

Preparation of Aldehydes from Calcium Methanoate

Image 5: Preparation of Aldehydes from Calcium Methanoate

b) Symmetrical ketones can be obtained by the dry distillation of the calcium salt of a member of the carboxylic acid group. Formic acid is an exception.

Preparation of Ketones from Calcium Ethanoate

Image 6: Preparation of Ketones from Calcium Ethanoate

Rosenmund Reduction

Aldehydes can be prepared by the hydrogenation of acid chloride, in the presence of a palladium catalyst supported by barium sulphate (BaSO4). This reaction is called Rosenmund reduction.


Preparation of Acetaldehyde from Acetyl Chloride

Image 7: Preparation of Acetaldehyde from Acetyl Chloride

In this reaction, barium sulphate acts as a catalytic poison to palladium catalyst, so this does not lead to the conversion of aldehyde to alcohol. Formaldehyde and Keto group members cannot be prepared by this method.

Stephen's Reaction

When alkyl cyanides are reduced using SnCl2 /HCl , imines are formed, which on

hydrolysis give the corresponding aldehyde.

Stephen’s Reaction

Image 8: Stephen’s Reaction

Side Chain Oxidation of Toluene and Toluene Derivatives

When we use chromyl chloride as an oxidising agent, toluene gives benzaldehyde. This reaction is called the Etard reaction. Acetic anhydride and Chromyl Chloride (CrO3) can also be used for this reaction.

Conversion of Methyl Benzene to Benzaldehyde

Image 9: Conversion of Methyl Benzene to Benzaldehyde

Oxidation of toluene by chromic oxide gives benzylidene diacetate, which on hydrolysis gives benzaldehyde.

Gattermann – Koch Reaction

This reaction is a variant of Friedel – Crafts acylation reaction. In this method, the reaction of carbon monoxide (CO) and hydrochloric acid (HCl) generates an intermediate which reacts like formyl chloride.

Gattermann - Koch Reaction

Image 10: Gattermann - Koch Reaction

Manufacture of Benzaldehyde From Toluene

Side chain chlorination of toluene yields benzal chloride, which when hydrolysed gives the compound benzaldehyde. This is the commercial method that is used for the manufacture of benzaldehyde.

Manufacture of Benzaldehyde from Toluene

Image 11: Manufacture of Benzaldehyde from Toluene

Preparation of Ketones

Ketones can be prepared by the reaction between acid chloride with dialkyl cadmium.

Preparation of Ketone

Image 12: Preparation of Ketone 

Friedel – Crafts Acylation

The Friedel Crafts Acylation is the best method ever known for preparing alkyl aryl ketones or diaryl ketones. The success of this reaction can only be seen with benzene and activated benzene derivatives.


Friedel Craft’s Acylation

Image 13: Friedel Craft’s Acylation


The carbonyl compounds containing the (–C=O) are generally called aldehydes and ketones. Aldehydes and ketones can be prepared by many methods like oxidation and catalytic dehydrogenation of alcohols, ozonolysis of alkenes, Gattermann – Koch reaction, Friedel – Crafts acylation, etc. 40% of the aqueous solution of formaldehyde is termed as formalin. We studied the preparation reactions of aldehydes and ketones. It can be used for preserving the biological specimens. Paraldehyde is used in medicine as a hypnotic while acetaldehyde is used for silvering of mirrors. We can use acetone as a nail polish remover. Benzophenone is used in perfumery and in the preparation of benzhydrol, which is an eye drop.

Competitive Exams after 12th Science

FAQs on Methods of Preparation of Aldehydes and Ketones for JEE

1. Explain the tests to identify the presence of aldehyde groups.

Tollens Reagent Test

Tollens reagent is an ammoniacal silver nitrate solution. When an aldehyde is warmed with the Tollens reagent, a bright silver mirror is formed due to the formation of silver metal in the test tube. This reaction is also called the silver mirror test for aldehydes.

$\mathrm{CH}_{3} \mathrm{CHO}+2\left[\mathrm{Ag}\left(\mathrm{NH}_{3}\right)_{2}\right]^{+}+3 \mathrm{OH}^{-} \longrightarrow \mathrm{CH}_{3} \mathrm{COO}^{-}+4 \mathrm{NH}_{3}+2 \mathrm{Ag}+2 \mathrm{H}_{2} \mathrm{O}$

Fehling's solution Test

Fehling's solution is prepared by mixing equal volumes of Fehling's solution ‘A’ containing aqueous copper sulphate and Fehling's solution ‘B’ containing alkaline solution of sodium potassium tartrate (Rochelle salt). When aldehyde is warmed with Fehling's solution, the deep blue colour solution is changed to red precipitate of cuprous oxide.

2. Explain the oxidation of ketones.

Ketones are not easily oxidised. Under drastic conditions or with powerful oxidising agents like Conc.HNO3, H+/KMnO4, H+/K2Cr2O7, cleavage of carbon-carbon bond takes place to give a mixture of carboxylic acids with less number of carbon atom than the parent ketone.

Image 14: Oxidation of Ketone

It is important to note that Popoff’s rule governs the oxidation of unsymmetrical ketones. It states that during the oxidation of an unsymmetrical ketone, a (C–CO) bond is cleaved in such a way that the keto group stays with the smaller alkyl group.

Image 15: Oxidation of Ketones to Carboxylic Acid