
As a result of isobaric heating $\Delta T = 72K$, one mole of a certain ideal gas obtains an amount of heat $Q = 1.60kJ$. If the value of $\gamma$ is $\dfrac{{(10 + x)}}{{10}}$. Find $x$.
Answer
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Hint: Given that the process is isobaric, so this means that the pressure is constant. If a gas expands at a constant pressure, then this process is known as isothermal expansion. In an isobaric process work done is proportional to volume and it is reversible.
Complete step by step solution:
Step I: In an isobaric process, the work done is given by
$W = \int {P.dV} $
$W = P\int {\Delta V} $
Step II:
But according to ideal gas law,
$P\Delta V = nR\Delta T$
$W = nR\Delta T$---(ii)
$R$ is gas constant and its value is $8.314$
For one mole of ideal gas, $n = 1$
Substitute the given values in equation (ii),
$W = 1 \times 8.314 \times 72$
$W = 598.60J$
Or $W \approx 600J = 0.6kJ$
Step III: Now according to the First Law of thermodynamics, the energy can neither be created nor destroyed. It can be converted from one form to another. For first law of thermodynamics,
$\Delta U = Q - W$
Where $\Delta U$ is the change in internal energy of the system
$Q$ is the energy or heat supplied
$W$ is the amount of work done
Step IV: Substitute the given values and find the value of internal energy of the system
$\Delta U = 1.6 - 0.6$
$\Delta U = 1kJ$
Step V: In case of isobaric processes, the internal energy of the system is given by
$\Delta U = n{c_v}\Delta T$---(i)
Where ${c_v}$ is the heat capacity of the substance
$\Delta T$ is the change in temperature
And the amount of heat of the system is given by
$Q = n{c_p}\Delta T$---(ii)
Step VI:
Dividing equation (i) and (ii),
$\dfrac{Q}{{\Delta U}} = \dfrac{{n{c_p}\Delta T}}{{n{c_v}\Delta T}}$
$\dfrac{Q}{{\Delta U}} = \dfrac{{{c_p}}}{{{c_v}}}$----(iii)
Step VII: Specific heat ratio in the isobaric process is given by gamma $\gamma $. Its formula is
$\gamma = \dfrac{{{c_p}}}{{{c_v}}}$---(iv)
Comparing (iii) and (iv)
$\gamma = \dfrac{Q}{{\Delta U}}$
$\gamma = \dfrac{{1.6}}{1}$
$\gamma = 1.6$
So the value of x is $\gamma = 1.6.$
Note: It is important to note that in an isobaric process, the volume of the system is allowed to expand or contract. It is to be done in such a way that it neutralises any pressure change. In an isobaric process, work is done and due to transfer of heat, there is change in internal energy.
Complete step by step solution:
Step I: In an isobaric process, the work done is given by
$W = \int {P.dV} $
$W = P\int {\Delta V} $
Step II:
But according to ideal gas law,
$P\Delta V = nR\Delta T$
$W = nR\Delta T$---(ii)
$R$ is gas constant and its value is $8.314$
For one mole of ideal gas, $n = 1$
Substitute the given values in equation (ii),
$W = 1 \times 8.314 \times 72$
$W = 598.60J$
Or $W \approx 600J = 0.6kJ$
Step III: Now according to the First Law of thermodynamics, the energy can neither be created nor destroyed. It can be converted from one form to another. For first law of thermodynamics,
$\Delta U = Q - W$
Where $\Delta U$ is the change in internal energy of the system
$Q$ is the energy or heat supplied
$W$ is the amount of work done
Step IV: Substitute the given values and find the value of internal energy of the system
$\Delta U = 1.6 - 0.6$
$\Delta U = 1kJ$
Step V: In case of isobaric processes, the internal energy of the system is given by
$\Delta U = n{c_v}\Delta T$---(i)
Where ${c_v}$ is the heat capacity of the substance
$\Delta T$ is the change in temperature
And the amount of heat of the system is given by
$Q = n{c_p}\Delta T$---(ii)
Step VI:
Dividing equation (i) and (ii),
$\dfrac{Q}{{\Delta U}} = \dfrac{{n{c_p}\Delta T}}{{n{c_v}\Delta T}}$
$\dfrac{Q}{{\Delta U}} = \dfrac{{{c_p}}}{{{c_v}}}$----(iii)
Step VII: Specific heat ratio in the isobaric process is given by gamma $\gamma $. Its formula is
$\gamma = \dfrac{{{c_p}}}{{{c_v}}}$---(iv)
Comparing (iii) and (iv)
$\gamma = \dfrac{Q}{{\Delta U}}$
$\gamma = \dfrac{{1.6}}{1}$
$\gamma = 1.6$
So the value of x is $\gamma = 1.6.$
Note: It is important to note that in an isobaric process, the volume of the system is allowed to expand or contract. It is to be done in such a way that it neutralises any pressure change. In an isobaric process, work is done and due to transfer of heat, there is change in internal energy.
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