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CBSE Chemistry Chapter 6 Haloalkanes and Haloarenes Class 12 Important Questions

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Haloalkanes and Haloarenes Class 12 Important Questions - Free PDF Download

In the realm of CBSE Class 12 Chemistry, Chapter 6 - Haloalkanes and Haloarenes, plays a pivotal role in understanding the world of organic compounds. This chapter delves into the intriguing world of haloalkanes and haloarenes, shedding light on their structures, nomenclature, properties, and reactions. To excel in this subject, it is imperative to have a strong grasp of the fundamental concepts and the ability to tackle a variety of questions effectively. Vedantu's Important Questions PDF for this chapter serves as an invaluable tool, meticulously curated to aid students in their preparation. These questions not only reinforce core concepts but also provide insight into the types of questions that can be expected in examinations, making learning engaging and effective.


The important questions from haloalkanes and haloarenes are now available for FREE in PDF format on Vedantu.These questions and answers are prepared by the highly experienced teachers at Vedantu according to the latest NCERT curriculum.


Important Topics Covered in CBSE Class 12 Haloalkanes and Haloarenes  

The important questions of Haloalkanes and Haloarenes of Class 12 cover the topics of:

  • Classification

  • Nomenclature

  • Nature of C-X Bond

  • Methods of Preparation

  • Types of Reactions (Elimination, substitution, etc)

  • Physical and Chemical properties, the order of reactivity.

  • Reagents

  • Polyhalogen Compounds


Extra questions of Haloalkanes and Haloarenes are very helpful to streamline the preparation and revision of these topics.


Download CBSE Class 12 Chemistry Important Questions 2024-25 PDF

Also, check CBSE Class 12 Chemistry Important Questions for other chapters:

CBSE Class 12 Chemistry Important Questions

Sl.No

Chapter No

Chapter Name

1

Chapter 1

The Solid State

2

Chapter 2

Solutions

3

Chapter 3

Electrochemistry

4

Chapter 4

Chemical Kinetics

5

Chapter 5

Surface Chemistry

6

Chapter 6

General Principles and Processes of Isolation of Elements

7

Chapter 7

The p-Block Elements

8

Chapter 8

The d and f Block Elements

9

Chapter 9

Coordination Compounds

10

Chapter 10

Haloalkanes and Haloarenes

11

Chapter 11

Alcohols, Phenols and Ethers

12

Chapter 12

Aldehydes, Ketones and Carboxylic Acids

13

Chapter 13

Amines

14

Chapter 14

Biomolecules

16

Chapter 16

Chemistry in Everyday life

Competitive Exams after 12th Science
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Important Questions For Class 12 Chemistry Chapter 6

1. Write the IUPAC names of the following compounds.

(i) 


3-Bromo-3-Methylhexane

Ans: The IUPAC name of the compound will be 3-Bromo-3-Methylhexane.

(ii) 


1-Bromo-2,3-dimethylbut-2-ene

Ans: The IUPAC name of the compound will be 1-Bromo-2,3-dimethylbut-2-ene.

(iii)


Benzyl chloride

Ans: The IUPAC name of the compound is Benzyl chloride.

(iv)


1-Bromo-2-ethyl-3,3,4-trimethylpentane

Ans: The IUPAC name of the compound is 1-Bromo-2-ethyl-3,3,4-trimethylpentane.

(v)

x$\text{C}{{\text{H}}_{\text{2}}}\text{Br-CH=CH-C}{{\text{H}}_{\text{2}}}\text{-C}\equiv \text{CH}$ 

Ans: The IUPAC name of the compound is 6-Bromohex-4-ene-1-yne,

(vi)


1-Bromo-1-methylcyclohexane

Ans: The IUPAC name of the compound is 1-Bromo-1-methylcyclohexane.

(vii)


3-sec-propyl pent-2,4-diol

Ans: The IUPAC name of the compound is 3-sec-propyl pent-2,4-diol.

(viii)

${{\text{(CC}{{\text{l}}_{\text{3}}}\text{)}}_{\text{3}}}\text{CCl}$ 

Ans: The IUPAC name of the compound is tris-(trichloromethyl) chloromethane.


2. Write the structure of the following halogen compounds

(i) 2-chloro-3-methylpentane

Ans: The structure of the compound is given below:


2-chloro-3-methylpentane

(ii) 2-(2-chlorophenyl)-1-iodooctane

Ans:  The structure of the compound is given below:


2-(2-chlorophenyl)-1-iodooctane

(iii) 1-bromo-4-sec-butyl-2–methylbenzene.

Ans: The structure of the compound is given below:


1-bromo-4-sec-butyl-2–methylebenzene

(iv) p-bromotoluene.

Ans: The structure of the compound is given below:


p-bromotoluene

(v) Chlorophenylmethane

Ans: The structure of the compound is given below:


chlorophenylmethane

3. Arrange the following in the increasing order of properly indicated :

i. bromomethane, chloromethane, dichloromethane. (Increasing order of boiling points).

Ans: As we can see that all the compounds given above are haloalkanes. The order will be:

Chloromethane < Bromomethane < Dichloromethane

This is due to the fact that as the halogen size increases the boiling point will increase and as the number of halogen atoms increases in the same chain, the boiling point will increase.

ii. 1-chloropropane, isopropyl chloride, 1-chlorobutane  (Increasing order of boiling point)

Ans: In all the compounds there is a chlorine atom present and the size of the alkyl chain is different. The order will be:

Isopropyl chloride < 1- Chloropropane < 1 – Chlorobutane 

This is due to the fact that as the branching of the chain increases the boiling point will decrease and as the size of the chain increase the boiling point will increase.

iii. dichloromethane, chloroform, carbon tetrachloride. (Increasing order of dipole moment.

Ans: Below is the three-dimensional structures of the three compounds, as well as the direction of each bond's dipole moment:


structures of the three compounds

$\text{CC}{{\text{l}}_{\text{4}}}$ has no dipole moment since it is symmetrical. When two C-Cl dipole moments are added to $\text{CHC}{{\text{l}}_{\text{3}}}$, the C-H and C-Cl bonds oppose each other. $\text{CHC}{{\text{l}}_{\text{3}}}$ has a limited dipole moment (1.03 D) because the dipole moment of the second resultant is anticipated to be less than that of the first. This means that in $\text{C}{{\text{H}}_{\text{2}}}\text{C}{{\text{l}}_{\text{2}}}$, the resulting dipole moment of C-Cl pairs is greater than in $\text{CHC}{{\text{l}}_{\text{3}}}$. Due to its dipole moment, $\text{C}{{\text{H}}_{\text{2}}}\text{C}{{\text{l}}_{\text{2}}}$ is the strongest. The order will be:

Carbon tetrachloride < Chloroform < Dichloromethane

iv. $\text{C}{{\text{H}}_{\text{3}}}\text{F}$, $\text{C}{{\text{H}}_{\text{3}}}\text{Cl}$, $\text{C}{{\text{H}}_{\text{3}}}\text{Br}$, $\text{C}{{\text{H}}_{\text{3}}}\text{I}$  (Increasing reactivity towards Nucleophilic substitution and increasing order of dipole moment)

Ans: The reaction is known as a nucleophilic substitution reaction when a nucleophile, which is an electron pair giver, interacts with an electron pair acceptor.

It is well known that as one moves down the group, the size of the components grows larger. As a result, the larger the element, the easier it will serve as a leaving group, allowing the nucleophile to connect more quickly. The order is given below:

$\text{C}{{\text{H}}_{\text{3}}}\text{F}$ < $\text{C}{{\text{H}}_{\text{3}}}\text{Cl}$ < $\text{C}{{\text{H}}_{\text{3}}}\text{Br}$ < $\text{C}{{\text{H}}_{\text{3}}}\text{I}$ 

v. o,m,p-dichlorobenzenes (Increasing order of melting points)

Ans: Because of its symmetry and structure, p-dichlorobenzene has the greatest melting point, followed by ortho, and finally meta.

The melting point of a compound is related to its symmetry. As a result, the symmetry of the compound follows the same pattern as the melting point. The order is given below:

m-Dichlorobenzene < o-Dichlorobenzen < p-Dichlorobenzene


4. Complete the following reactions: 


(i) 

styrene with hydrogen bromide


Ans: The complete reaction is given below:


Complete reaction between styrene and hydrogen bromide

(ii) $\text{C}{{\text{H}}_{\text{3}}}\text{-C}{{\text{H}}_{\text{2}}}\text{-Cl + AgN}{{\text{O}}_{\text{2}}}\text{ }\to $ 


Ans: The complete reaction is given below:

\[\text{C}{{\text{H}}_{\text{3}}}\text{-C}{{\text{H}}_{\text{2}}}\text{-Cl + AgN}{{\text{O}}_{\text{2}}}\text{ }\to \text{ C}{{\text{H}}_{\text{3}}}\text{-C}{{\text{H}}_{\text{2}}}\text{-N}{{\text{O}}_{\text{2}}}\text{ + AgCl}\] 

(iii)


alkene and hydrogen bromide

Ans: The complete reaction is given below:


Complete reaction between an alkene and hydrogen bromide

(iv)


2,4,6-Trinitrochlorobenzene and Sodium hydroxide

Ans: The complete reaction is given below:


Complete Reaction between 2,4,6-Trinitrochlorobenzene and Sodium hydroxide


(v)

ethylbenzene and bromine in the presence of heat and light


Ans: In this reaction, the amine group will be replaced with methyl bromine. The reaction is given below:


Complete reaction between ethylbenzene and bromine in the presence of heat and light

(vi)

1-Methyl cyclohexene and Hydrogen iodide

Ans: In this reaction, the iodine from the hydrogen iodide will attach to the carbon atom having the double bond as well as a methyl group. The reaction is given below:


Complete reaction between 1-Methyl cyclohexene and Hydrogen iodide


(vii)

Complete reaction between organic compound containing hydroxyl group and thionyl chloride

Ans: In this reaction, the hydroxyl group with the methyl group will be replaced with the chlorine atom. The reaction is given below:


Cyclohexene and bromine in the presence of heat or UV-light

(viii) $\text{C}{{\text{H}}_{\text{3}}}\text{C}{{\text{H}}_{\text{2}}}\text{Br + NaI }\xrightarrow{\text{acetone}}$ 

Ans: The Chlorine atom from the alkyl halide by iodine. The major product of the reaction is 1-Iodoethane. The reaction is given below:

\[\text{C}{{\text{H}}_{\text{3}}}\text{C}{{\text{H}}_{\text{2}}}\text{Br + NaI }\xrightarrow{\text{acetone}}\text{ C}{{\text{H}}_{\text{3}}}\text{C}{{\text{H}}_{\text{2}}}\text{I + NaBr}\]

(ix)

tert-Butyl bromide and potassium hydroxide in the presence of ethanol


Ans: In this reaction, the bromine atom will attack the alpha-carbon atom of the double bond. The reaction is given below:


Complete reaction between tert-Butyl bromide and potassium hydroxide in the presence of ethanol

(x) ${{\text{(C}{{\text{H}}_{\text{3}}}\text{)}}_{\text{3}}}\text{CBr + KOH }\xrightarrow{\text{Ethanol}}$ 

Ans: There will be Dehydrohalogenation and the major product of the reaction is 2-methylpropene. The reaction is given below:


bromonitrobenzene and Magnesium

(xi) $\text{C}{{\text{H}}_{\text{3}}}\text{C}{{\text{H}}_{\text{2}}}\text{Br + KCN}\xrightarrow{\text{aq}\text{.ethanol}}$ 

Ans: The bromide ion will be replaced with the cyanide ion. The major product will be propanenitrile. The reaction is given below:

\[\text{C}{{\text{H}}_{\text{3}}}\text{C}{{\text{H}}_{\text{2}}}\text{Br + KCN }\xrightarrow{\text{aq}\text{.ethanol}}\text{ C}{{\text{H}}_{\text{3}}}\text{C}{{\text{H}}_{\text{2}}}\text{CN + KBr}\]  

(xii)


Complete reaction between 3- bromonitrobenzene and Magnesium in the presence dry ether

Ans: There will be the formation of a Grignard reagent. The reaction is given below:


Reaction between 2- bromobutane and Sodium in the presence of dry ether

(xiii) ${{\text{C}}_{\text{6}}}{{\text{H}}_{\text{5}}}\text{ONa + }{{\text{C}}_{\text{2}}}{{\text{H}}_{\text{5}}}\text{Cl }\to $ 

Ans: The major product in the above reaction will be Phenetole. The reaction is given below:

\[{{\text{C}}_{\text{6}}}{{\text{H}}_{\text{5}}}\text{ONa + }{{\text{C}}_{\text{2}}}{{\text{H}}_{\text{5}}}\text{Cl }\to {{\text{C}}_{\text{6}}}{{\text{H}}_{\text{5}}}\text{-O-}{{\text{C}}_{\text{2}}}{{\text{H}}_{\text{5}}}\text{ + NaCl}\]

(xiv)


2- bromobutane and Sodium in the presence of dry ether

Ans: The product formed in this reaction will be 3,4-Dimethylhexane. The reaction is given below:


2- bromobutane and Sodium hydroxide in the presence of water

(xv) $\text{C}{{\text{H}}_{\text{3}}}\text{CH(Br)C}{{\text{H}}_{\text{2}}}\text{C}{{\text{H}}_{\text{3}}}\text{ + NaOH }\xrightarrow{\text{Water}}$ 

Ans: The bromine atom will be replaced with the hydroxyl ion. The major product will be Butan-2-ol. The reaction is given below:


Benzene and Nitric acid in the presence of Sulphuric acid

(xvi) ${{\text{C}}_{\text{6}}}{{\text{H}}_{\text{5}}}\text{N}_{\text{2}}^{\text{+}}\text{C}{{\text{l}}^{\text{-}}}\text{ + KI }\to $ 

Ans: There will be the formation of iodobenzene in this case. The reaction is given below:

\[{{\text{C}}_{\text{6}}}{{\text{H}}_{\text{5}}}\text{N}_{\text{2}}^{\text{+}}\text{C}{{\text{l}}^{\text{-}}}\text{ + KI }\to \text{ }{{\text{C}}_{\text{6}}}{{\text{H}}_{\text{5}}}\text{I + }{{\text{N}}_{\text{2}}}\text{ + KCl}\] 


5. How will you bring about the following conversions?

i. benzene to 3-bromonitrobenzene

Ans: Benzene will first react with concentrated sulfuric acid and nitric acid to form nitrobenzene. Now, this nitrobenzene will react with bromine in the presence of $\text{FeB}{{\text{r}}_{\text{3}}}$ to form 3-Bromonitrobenzene. The reaction is given below:


enzene and Bromine in the presence of Ferric bromide to yield 4-Bromonitrobenzene

ii. ethanol to but-1-yne

Ans: Ethanol will react with $\text{SOC}{{\text{l}}_{\text{2}}}$ and pyridine to Chloroethane. Acetylene will react with $\text{NaN}{{\text{H}}_{\text{2}}}$ to form sodium acetylide. Now Chloroethane and Sodium acetylide will react to form But-1-yne. The reactions are given below:

\[\text{C}{{\text{H}}_{\text{3}}}\text{C}{{\text{H}}_{\text{2}}}\text{OH }\xrightarrow{\text{SOC}{{\text{l}}_{\text{2}}}\text{, Pyridine}}\text{ C}{{\text{H}}_{\text{3}}}\text{C}{{\text{H}}_{\text{2}}}\text{-Cl}\] 

\[\text{CH}\equiv \text{CH + NaN}{{\text{H}}_{\text{2}}}\xrightarrow{\text{Liq}\text{. N}{{\text{H}}_{\text{3}}}\text{, 196K}}\text{ HC}\equiv {{\text{C}}^{\text{-}}}\text{N}{{\text{a}}^{\text{+}}}\] 

\[\text{C}{{\text{H}}_{\text{3}}}\text{C}{{\text{H}}_{\text{2}}}\text{Cl + HC}\equiv {{\text{C}}^{\text{-}}}\text{N}{{\text{a}}^{\text{+}}}\text{ }\to \text{ C}{{\text{H}}_{\text{3}}}\text{C}{{\text{H}}_{\text{2}}}\text{-C}\equiv \text{CH + NaCl}\]

iii. 1-bromopropane to 2-bromopropane

Ans: 1-Bromopropane will react with alcoholic KOH to form propene. Propene will react with HBr to form 2-Bromopropane. The reaction is given below:

\[\text{C}{{\text{H}}_{\text{3}}}\text{C}{{\text{H}}_{\text{2}}}\text{C}{{\text{H}}_{\text{2}}}\text{Br}\xrightarrow{\text{Alc}\text{.KOH}}\text{C}{{\text{H}}_{\text{3}}}\text{CH=C}{{\text{H}}_{\text{2}}}\xrightarrow{\text{HBr}}\text{C}{{\text{H}}_{\text{3}}}\text{-CH(Br)-C}{{\text{H}}_{\text{3}}}\]

iv. benzene to 4-bromo-1-nitrobenzene

Ans: Benzene will react with Bromine in the presence of $\text{FeB}{{\text{r}}_{\text{3}}}$ to form Bromobenzene. Bromobenzen will react with concentrated nitric acid and concentrated sulfuric acid to form 4-Bromonitrobenzene. The reaction is given below:


aniline to yield chlorobenzene

v. aniline to chlorobenzene

Ans: Aniline will undergo diazotization to form Benzene diazonium chloride. The Benzene diazonium chloride will react with copper chloride in the presence of hydrochloric acid to given Chlorobenzene. The reaction is given below:


2-methyl-1-propene to yield 2-chloro-2-methylpropane, benzene to yield phenyl chloromethane

vi. 2-methyl-1-propene to 2-chloro-2-methylpropane

Ans: 2-Methyl-1-propene will react with Hydrogen chloride to give 2-Chloro-2-methylpropane. The reaction is given below:


tert-butyl bromide to yield isobutyl bromide

vii. ethyl chloride to propanoic acid

Ans: Ethyl chloride will react with KCN to give propanenitrile. Propanenitrile on hydrolysis will give propanoic acid. The reaction is given below:

\[\text{C}{{\text{H}}_{\text{3}}}\text{C}{{\text{H}}_{\text{2}}}\text{Cl}\xrightarrow{\text{KCN}}\text{C}{{\text{H}}_{\text{3}}}\text{C}{{\text{H}}_{\text{2}}}\text{CN}\xrightarrow{{{\text{H}}^{\text{+}}}\text{/}{{\text{H}}_{\text{2}}}\text{O}}\text{C}{{\text{H}}_{\text{3}}}\text{C}{{\text{H}}_{\text{2}}}\text{COOH}\]  

viii. but-1-ene to n-butyl iodide

Ans: But-1-ene will react with HBr in the presence of peroxide to form 1-Bromobutane. 1-Bromobutane will react with NaI in the presence of Acetone to give n-butyl iodide. The reaction is given below:

\[\text{C}{{\text{H}}_{\text{3}}}\text{C}{{\text{H}}_{\text{2}}}\text{CH=C}{{\text{H}}_{\text{2}}}\xrightarrow[\text{peroxide}]{\text{HBr}}\text{C}{{\text{H}}_{\text{3}}}\text{C}{{\text{H}}_{\text{2}}}\text{C}{{\text{H}}_{\text{2}}}\text{C}{{\text{H}}_{\text{2}}}\text{Br}\]

\[\text{C}{{\text{H}}_{\text{3}}}\text{C}{{\text{H}}_{\text{2}}}\text{C}{{\text{H}}_{\text{2}}}\text{C}{{\text{H}}_{\text{2}}}\text{Br}\xrightarrow[\text{Acetone}]{\text{NaI}}\text{C}{{\text{H}}_{\text{3}}}\text{C}{{\text{H}}_{\text{2}}}\text{C}{{\text{H}}_{\text{2}}}\text{C}{{\text{H}}_{\text{2}}}\text{I}\] 

ix. benzene to phenyl chloromethane.

Ans: Benzene will first react with chloromethane in the presence of ferric chloride to form toluene. Now, the toluene will react with chlorine in the presence of sunlight. The reaction is given below:


aryl halide with Sodium cyanide which further hydrolysed

x. tert-butyl bromide to isobutyl bromide.

Ans: Tert-butyl bromide will react with alcoholic KOH to form 2-Methyl-1-propene. 2-Methyl-1-propene will react with HBr in the presence of peroxide to form isobutyl bromide. The reaction is given below:


Substituted aryl halide with Sodium cyanide which further hydrolysed

6. Identify the products formed in the following sequence :

(i)

Alkyl bromide with alcoholic potassium hydroxide which further treated with Hydrogen bromide

Ans: The complete reaction is given below:


2-bromo propane with alcoholic potassium hydroxide

ii. $\text{Br-C}{{\text{H}}_{\text{2}}}\text{-C}{{\text{H}}_{\text{2}}}\text{-Br }\xrightarrow{\text{alc}\text{.KOH}}\text{ A }\xrightarrow{\text{NaN}{{\text{H}}_{\text{2}}}}\text{ B}$ 

Ans: The complete reaction is given below:

\[\text{Br-C}{{\text{H}}_{\text{2}}}\text{-C}{{\text{H}}_{\text{2}}}\text{-Br }\xrightarrow{\text{alc}\text{.KOH}}\text{ C}{{\text{H}}_{\text{2}}}\text{=CHBr }\xrightarrow{\text{NaN}{{\text{H}}_{\text{2}}}}\text{CH}\equiv \text{CH}\] 

iii.${{\text{C}}_{\text{6}}}{{\text{H}}_{\text{5}}}\text{C}{{\text{H}}_{\text{2}}}\text{CHBrC}{{\text{H}}_{\text{3}}}\xrightarrow{\text{alc}\text{.KOH}}\text{A }\xrightarrow{\text{HBr}}\text{B}$ 

Ans: The complete reaction is given below:


Complete reaction of 2-bromo propane with alcoholic potassium hydroxide


iv. 


utene with bromine in the presence of carbon tetrachloride

Ans: The complete reaction is given below:


Butene with bromine in the presence of heat and UV light

v. $\text{C}{{\text{H}}_{\text{3}}}\text{-C}{{\text{H}}_{\text{2}}}\text{CH=C}{{\text{H}}_{\text{2}}}\text{+B}{{\text{r}}_{\text{2}}}\xrightarrow{\text{CC}{{\text{l}}_{\text{4}}}}\text{A}$ 

Ans: The complete reaction is given below:


Butene with bromine in the presence of heat and UV light

vi.$\text{C}{{\text{H}}_{\text{3}}}\text{C}{{\text{H}}_{\text{2}}}\text{CH=C}{{\text{H}}_{\text{2}}}\text{ + B}{{\text{r}}_{\text{2}}}\xrightarrow[\text{UV light}]{\text{heat}}\text{ B}$ 

Ans: The complete reaction is given below:


Wurtz-Fitting reaction

(vii)

Friedel-Crafts alkylation reaction


Ans: In this reaction, the reactant is an alkyl halide while the product is an alkene and there is the elimination of HBr from the reactant so, the catalyst will be alcoholic KOH. Therefore, A will be an alcoholic KOH.

(viii) $\text{C}{{\text{H}}_{\text{3}}}\text{Br}\xrightarrow{\text{KCN}}\text{A}\xrightarrow{{{\text{H}}_{\text{3}}}{{\text{O}}^{\text{+}}}}\text{B}\xrightarrow{\text{LiAl}{{\text{H}}_{\text{4}}}}\text{C}$ 

Ans: The complete reaction is given below:

\[\text{C}{{\text{H}}_{\text{3}}}\text{Br}\xrightarrow{\text{KCN}}\text{C}{{\text{H}}_{\text{3}}}\text{CN}\xrightarrow{{{\text{H}}_{\text{3}}}{{\text{O}}^{\text{+}}}}\text{C}{{\text{H}}_{\text{3}}}\text{COOH}\xrightarrow{\text{LiAl}{{\text{H}}_{\text{4}}}}\text{C}{{\text{H}}_{\text{3}}}\text{C}{{\text{H}}_{\text{2}}}\text{OH}\] 


7. Explain the following reactions with suitable examples:

(i) Finkelstein reaction.

Ans: In the traditional Finkelstein reaction, an alkyl bromide or alkyl chloride is converted to an alkyl iodide, which is then treated with a sodium iodide solution in acetone. The reaction is given below:

\[\text{C}{{\text{H}}_{\text{3}}}\text{C}{{\text{H}}_{\text{2}}}\text{Br + NaI }\to \text{ C}{{\text{H}}_{\text{3}}}\text{C}{{\text{H}}_{\text{2}}}\text{I + NaBr}\] 

(ii) Swarts reaction.

Ans: Swarts' reaction is commonly used to make alkyl fluorides from alkyl chlorides or alkyl bromides. This is accomplished by heating the alkyl chloride / bromide in the presence of fluoride in certain heavy metals. The reaction is given below:

\[\text{C}{{\text{H}}_{\text{3}}}\text{-Br + AgF }\to \text{ C}{{\text{H}}_{\text{3}}}\text{F + AgBr}\] 

(iii) Wurtz reaction.

Ans: To generate higher alkanes, alkyl halides are treated with sodium metal in a dry ethereal (moisture-free) solution. It can also be utilized to create higher alkanes with an even number of carbon atoms. The reaction is given below:

\[\text{2 R-X + 2Na }\to \text{ R-R + 2 NaX}\] 

(iv) Wurtz-Fitting reaction

Ans: The Wurtz–Fitting reaction is a chemical reaction that produces substituted aromatic compounds by combining aryl halides with alkyl halides and sodium metal in the presence of dry ether. The reaction is given below:


Friedel-Crafts acylation reaction

(v) Friedel-Crafts alkylation reaction.

Ans: This reaction permitted alkylbenzenes to be formed from alkyl halides, but it was hampered with undesired supplementary activity, which decreased its efficiency. The reaction is given below:


andmeyer reaction


(vi) Friedel-Crafts acylation reaction

Ans: The Friedel–Crafts acylation uses a strong Lewis acid catalyst to react an arene with acyl chlorides or anhydrides. This process produces monoacetylated compounds by electrophilic aromatic substitution. The reaction is given below:


2-bromo butane with potassium hydroxide and ethanol

(vii) Sandmeyer reaction.

Ans: The Sandmeyer reaction is a chemical process that uses copper salts as reagents or catalysts to synthesize aryl halides from aryl diazonium salts. The reaction is given below:


Complete reaction of 2-bromo butane with potassium hydroxide and ethanol


8. Write the major products and name the rule responsible for the formation of the product.

(i)


reaction of butene with hydrogen bromide

Ans: In this reaction, the alkyl halide is treated with KOH and ethanol so, first, there will be the formation of alkene and then there will be the addition of water molecules. This is called a substitution reaction. The reaction is given below:


butene with hydrogen bromide in the presence of organic peroxide

(ii)

chlorine with benzene in the presence of Ferric chloride in dark

Ans: In this reaction, the alkyl halide is treated with HBr in the presence of peroxide so, the Br will attack the carbon atom having larger number of hydrogen atoms and the hydrogen will attack the carbon atom having less number of hydrogen atoms. This is called Anti-Markovnikov’s rule. Therefore, the product will be Bromobutane. The reaction is given below:


1-Chloro-4-nitrobenzene with Sodium hydroxide

9. Write the Difference Between

(i) Enantiomers and Diastereomers

Ans: This is tabulated below:

Enantiomers

Diastereomers

Chiral compounds with non-superimposable mirror images are known as enantiomers.

Diastereomers are stereoisomers that contain molecules that do not mirror images of one another and cannot be superimposed. They are mirror copies of each other that cannot be superimposed.


(ii) Retention and Inversion of configuration.

Ans: This is tabulated below:

Retention of configuration

Inversion of configuration

Retention is described as a condition in which the atoms or molecule’s absolute and relative configurations are maintained.

Inversion is described as a condition in which the atoms or molecule’s absolute and relative configurations are not preserved.


(iii) Electrophilic and Nucleophilic substitution reactions.

Ans: This is tabulated below:

Electrophilic substitution reaction

Nucleophilic substitution reaction

In electrophilic substitutions, an electrophile replaces a functional group (generally a hydrogen atom). Electrophilic compounds are said to be electron-loving species and consist of a positive charge.

Nucleophilic substitutions occur when a nucleophile attacks a positively charged (or partly positively charged) atom or group. Species that may give an electron pair are known as nucleophiles.


10. Give a chemical test to distinguish between the following pairs of compounds:

(i) Chlorobenzene and Cyclohexylchloride.

Ans: Cyclohexylchloride can react with KOH to give Cyclohexanol and KCl. The KCl from the product can be reacted with $\text{AgN}{{\text{O}}_{\text{3}}}$ to give white ppt. AgCl. Whereas, chlorobenzene will not give this reaction.


(ii) Vinyl chloride and ethyl chloride.

Ans: Bromine water can be used to tell the difference. When vinyl chloride reacts with bromine water, it becomes decolorized, but ethyl chloride does not.

(iii) N-propyl bromide and isopropyl bromide.

Ans: When isopropyl bromide reacts with KOH, 2-propanol is produced. 2-propanol reacts with HCl and $\text{ZnC}{{\text{l}}_{\text{2}}}$  to generate 2-propyl chloride, which causes turbidity after 5 minutes, whereas n-propyl bromide reacts with KOH to produce propanol, and propanol reacts with HCl and $\text{ZnC}{{\text{l}}_{\text{2}}}$ to make 2-propyl chloride, which does not cause turbidity.


11. Give mechanism of the following reactions:

(i) ${{\text{(C}{{\text{H}}_{\text{3}}}\text{)}}_{\text{3}}}\text{C-Cl +}{{\text{ }}^{\text{-}}}\text{OH }\to \text{ (C}{{\text{H}}_{\text{3}}}{{\text{)}}_{\text{3}}}\text{-OH}$ 

Ans: This reaction will follow the unimolecular Nucleophilic substitution reaction mechanism (${{\text{S}}_{\text{N}}}\text{1}$). The mechanism is given below:


halogen compounds

(ii) $\text{C}{{\text{H}}_{\text{3}}}\text{-Cl + O}{{\text{H}}^{\text{-}}}\text{ }\to \text{ C}{{\text{H}}_{\text{3}}}\text{-OH}$ 

Ans: This reaction will follow the bimolecular Nucleophilic substitution reaction mechanism (${{\text{S}}_{\text{N}}}2$). The mechanism is given below:


2-methylbutane with Chlorine to yield 2-Chloro-2-methylbutane

(iii)


Reaction of 2-methylbutane with Chlorine to yield 2-Chloro-3-methylbutane


Ans: In this reaction, there will be an elimination mechanism, as there is the formation of an alkene by the elimination of HCl molecules. The mechanism is given below:


2-methylbutane with Chlorine to yield 1-Chloro-3-methylbutane


(iv)

2-methylbutane with Chlorine to yield 1-Chloro-2-methylbutane

Ans: In this reaction, there is a substitution mechanism as the hydrogen atom from the benzene is substituted with the chlorine atom thus forming chlorobenzene.

(v)

2,3-dimethylbutane with Chlorine to yield 1-Chloro-2,3-dimethyl butane

Ans: In this reaction, there is a substitution mechanism as the chlorine atom from the benzene is substituted with the hydroxyl ion thus forming p-nitrophenol.


12. Which compound in each of the following pairs will react faster in ${{\text{S}}_{\text{N}}}\text{2}$  reaction with $\text{O}{{\text{H}}^{\text{-}}}$?

(i) $\text{C}{{\text{H}}_{\text{3}}}\text{Br}$ or $\text{C}{{\text{H}}_{\text{3}}}\text{I}$ 

Ans: Both the compounds are alkyl halide but the iodide ion is a larger atom than bromide ion. So, ${{\text{I}}^{\text{-}}}$ ion is better leaving group than $\text{B}{{\text{r}}^{\text{-}}}$ ion. Therefore, $\text{C}{{\text{H}}_{\text{3}}}\text{I}$ will react faster than $\text{C}{{\text{H}}_{\text{3}}}\text{Br}$ towards ${{\text{S}}_{\text{N}}}\text{2}$ reaction with hydroxyl ion.

(ii) ${{\text{(C}{{\text{H}}_{\text{3}}}\text{)}}_{\text{3}}}\text{CCl}$ or $\text{C}{{\text{H}}_{\text{3}}}\text{Cl}$ 

Ans: In ${{\text{S}}_{\text{N}}}\text{2}$reaction the steric hindrance should be very less. ${{\text{(C}{{\text{H}}_{\text{3}}}\text{)}}_{\text{3}}}\text{CCl}$ has very high steric hindrance and $\text{C}{{\text{H}}_{\text{3}}}\text{Cl}$ has less steric hindrance. So, $\text{C}{{\text{H}}_{\text{3}}}\text{Cl}$ will react faster to the ${{\text{S}}_{\text{N}}}\text{2}$ reaction with hydroxyl ion.


13. In the following pairs of halogen compounds, which compound undergoes faster ${{\text{S}}_{\text{N}}}\text{1}$  reaction?

Ans: For the ${{\text{S}}_{\text{N}}}1$ reaction the order of reactivity is ${{3}^{\circ }} > {{2}^{\circ }} > {{1}^{\circ }}$, so we can solve the question according to the order of the reactivity.

(i) 

2,3-dimethylbutane with Chlorine to yield 2-Chloro-2,3-dimethyl butane

Ans: The first compound is a tertiary compound and the second compound is a secondary compound. So, the first compound will undergo faster ${{\text{S}}_{\text{N}}}1$reaction.

(ii)

Reaction of 3-methylbutan-2-ol with hydrogen bromide

Ans: The first compound is a secondary compound and the second compound is the primary compound. So, the first compound will undergo a faster ${{\text{S}}_{\text{N}}}1$reaction.

(iii) ${{\text{(C}{{\text{H}}_{\text{3}}}\text{)}}_{\text{3}}}\text{C-Cl}$ and ${{\text{C}}_{\text{6}}}{{\text{H}}_{\text{5}}}\text{C}{{\text{H}}_{\text{2}}}\text{Cl}$ 

Ans: The first compound is a tertiary compound and the second compound is primary compound. So, the first compound will undergo a faster ${{\text{S}}_{\text{N}}}1$reaction.

(iv)${{\text{C}}_{\text{6}}}{{\text{H}}_{\text{5}}}\text{C}{{\text{H}}_{\text{2}}}\text{Cl}$ and ${{\text{C}}_{\text{6}}}{{\text{H}}_{\text{5}}}\text{C(Cl)}{{\text{C}}_{\text{6}}}{{\text{H}}_{\text{5}}}$ 

Ans: The first compound is the primary compound and the second compound is the secondary compound. So, the second compound will undergo faster ${{\text{S}}_{\text{N}}}1$reaction.

(v) $\text{C}{{\text{H}}_{\text{2}}}\text{=CH-Cl}$ and $\text{C}{{\text{H}}_{\text{2}}}\text{=CH-C}{{\text{H}}_{\text{2}}}\text{Cl}$ 

Ans: The first compound is the vinylic primary compound and the second compound is the primary compound. So, the second compound will undergo faster ${{\text{S}}_{\text{N}}}1$reaction because in the first there will be resonance.


14. Give reasons for the following :

(i) The bond length of the C–Cl bond is larger in haloalkanes than that in haloarenes.

Ans: The C linked to the halogen atom in haloalkanes is $\text{s}{{\text{p}}^{\text{3}}}$  hybridized, whereas it is $\text{s}{{\text{p}}^{2}}$  hybridized in haloarenes.

In haloarene, the halogen is in resonance with the benzene ring. Due to this, there is a partial double bond character between halogen and carbon which results in a shorter bond length.

(ii) Although alkyl halides are polar in nature but are not soluble in water.

Ans: Dipole-dipole attractions exist in alkyl halides, whereas hydrogen bonding and van der Waals force exist in water. Alkyl halides have a hard time breaking those hydrogen bonds, thus they're nearly insoluble in water.

(iii) tert-butyl bromide has a lower boiling point than n-Butyl bromide.

Ans: Because the boiling point of n-butyl bromide increases as branching decreases, it has a higher boiling point than tert butyl bromide. This is due to the fact that when the surface area of the molecule decreases, the molecule becomes more spherical. Intermolecular forces weaken, as a result, resulting in a lower boiling point.

(iv) haloalkanes react with KCN to form alkyl cyanide as the main product while with AgCN alkyl isocyanide is the main product.

Ans: KCN is primarily an ionic compound that produces cyanide ions in solution. Although both the carbon and nitrogen atoms of CN have the ability to contribute electron pairs, the assault is focused on the carbon atom rather than the nitrogen atom because the C-C bond is more stable than the C-N link. However, in nature, AgCN is mostly covalent, and nitrogen is free to contribute electron pairs, resulting in isocyanide as the primary product.

(v) Sulphuric acid is not used in the reaction of alcohol with Kl.

Ans: Because sulfuric acid is an oxidizing agent, it will convert KI to equivalent HI and oxidize the HI if it is used in the process. As a result, no sulfuric acid is needed in the reaction of alcohols with KI.

(vi) Thionyl chloride is the preferred reagent for converting ethanol to chloroethane.

Ans: Thionyl chloride is favored for preparing alkyl chlorides from alcohols because the reaction's by-products include SO2 and HCl, both of which are gaseous and escape into the atmosphere, leaving only pure alkyl chlorides behind.

(vii) Haloalkanes undergo nucleophilic substitution reaction easily but haloarenes do not undergo nucleophilic substitution under ordinary conditions.

Ans: Because haloalkanes are more polar than haloarenes, they are more prone to nucleophilic substitution reactions. The reason for this is that the carbon atom linked to the halogen atom in haloalkanes is $\text{s}{{\text{p}}^{\text{3}}}$ hybridized, whereas it is $\text{s}{{\text{p}}^{2}}$ hybridised in haloarenes. The electronegativity difference in the CX bond of haloalkanes is higher because an $\text{s}{{\text{p}}^{\text{3}}}$ hybridized carbon is less electronegative than a $\text{s}{{\text{p}}^{2}}$ hybridised carbon, making them more polar.

(viii) Chlorobenzene on reaction with fuming sulphuric acid gives ortho and para chlorosulphonic acids.

Ans: Although chlorine is an electronegative molecule, it possesses a lone pair of electrons that have a tendency to be added to the benzene ring's resonance structure, resulting in partial negative charges on ortho and para positions, with the electron density being lowest at meta.

Now, we know that when sulphuric acid is introduced to this molecule, the mechanism is electrophile ($\text{S}{{\text{O}}_{\text{3}}}$)attacks, and since it will approach the position with greater electron density, it will attack the negative, ortho/para positions, yielding ortho and para chloro sulphonic acid.

(ix) 2, 4-dinitro chlorobenzene is much more reactive than chlorobenzene towards hydrolysis reaction with NaOH.

Ans: On the benzene ring, the lone pair of electrons on chlorobenzene are delocalized. As a result, the C-Cl bond takes on a partial double bond appearance. As a result, the C-Cl bond in chlorobenzene is extremely strong and difficult to break. However, in the case of 2,4-dinitro chlorobenzene, the presence of $\text{N}{{\text{O}}_{\text{2}}}$ groups at ortho and para positions pulls electrons away from the benzene ring, making the nucleophile attack on para chlorobenzene easier. The resonance stabilizes the carbanion that results. In comparison to chlorobenzene, 2,4-dinitrochlorobenzene is more reactive towards nucleophilic substitution processes.

(x) The Grignard reagent should be prepared under anhydrous conditions.

Ans: Grignard reagents have a high degree of reactivity. When they come into contact with moisture, they react to form alkanes. Grignard reagents should thus be produced in anhydrous circumstances.

(xi) The dipole moment of chlorobenzene is lower than that of cyclohexyl chloride.

Ans: Chlorobenzene has a lower dipole potential than cyclohexyl chloride because the C-Cl bond in chlorobenzene is $\text{s}{{\text{p}}^{2}}$ hybridised, whereas the C-Cl link in cyclohexyl chloride is $\text{s}{{\text{p}}^{\text{3}}}$ hybridized. Because $\text{s}{{\text{p}}^{2}}$ has a higher s character and is more electronegative than $\text{s}{{\text{p}}^{\text{3}}}$, it is more electronegative. Compared to cyclohexyl chloride, chlorobenzene is less polar.

(xii) Neopentyl bromide undergoes nucleophilic substitution reactions very slowly.

Ans: Bromine is sterically hindered because it is linked to carbon where the surrounding carbon group contains a significant number of alkyl substituents ( like a shielding effect to prevent nucleophilic attack). This is why this nucleophilic substitution takes so long.

(xiii) Vinyl chloride is unreactive in nucleophilic substitution reactions.

Ans: Due to resonance, vinyl chloride is unreactive in nucleophilic substitution reactions. The lone pair of electrons on chlorine in vinyl chloride is in resonance with the C-C double bond, giving the C-Cl bond a partial double bond nature. The C-Cl connection grows stronger and more difficult to break as a result of its double bond nature.

(xiv) An optically inactive product is obtained after the hydrolysis of optically active 2- bromobutane.

Ans: The ${{\text{S}}_{\text{N}}}\text{1}$  reaction is used to hydrolyze 2-bromobutane. The ${{\text{S}}_{\text{N}}}\text{1}$  reaction is triggered by the creation of a carbocation, in which the OH-attack the carbocation from both sides, culminating in the production of 2-butanol, a racemic product. As a result of the production of the racemic product, 2-butanol is optically inactive.


15.  Write the different products and their number formed by the monochlorination of following compounds:

(i) $\text{C}{{\text{H}}_{\text{3}}}\text{C}{{\text{H}}_{\text{2}}}\text{C}{{\text{H}}_{\text{2}}}\text{C}{{\text{H}}_{\text{3}}}$

Ans: There will be the formation of 2 products. 

When this compound is monochlorinated then one product will be 1-Chlorobutane. The reaction is given below:

\[\text{C}{{\text{H}}_{\text{3}}}\text{-C}{{\text{H}}_{\text{2}}}\text{-C}{{\text{H}}_{\text{2}}}\text{-C}{{\text{H}}_{\text{3}}}\text{ + C}{{\text{l}}_{\text{2}}}\text{ }\to \text{ C}{{\text{H}}_{\text{3}}}\text{-C}{{\text{H}}_{\text{2}}}\text{-C}{{\text{H}}_{\text{2}}}\text{-C}{{\text{H}}_{\text{2}}}\text{Cl}\] 

Another product when the compound is chlorinated will be 2-Chlorobutane. The reaction is given below:

\[\text{C}{{\text{H}}_{\text{3}}}\text{-C}{{\text{H}}_{\text{2}}}\text{-C}{{\text{H}}_{\text{2}}}\text{-C}{{\text{H}}_{\text{3}}}\text{ + C}{{\text{l}}_{\text{2}}}\text{ }\to \text{ C}{{\text{H}}_{\text{3}}}\text{-CHCl-C}{{\text{H}}_{\text{2}}}\text{-C}{{\text{H}}_{\text{3}}}\] 

(ii) ${{\text{(C}{{\text{H}}_{\text{3}}}\text{)}}_{\text{2}}}\text{CHC}{{\text{H}}_{\text{2}}}\text{C}{{\text{H}}_{\text{3}}}$ 

Ans: There will be the formation of 4 products.

First, the product will be 2-Chloro-2-methylbutane. The reaction is given below:


3-methylbutan-2-ol with hydrogen bromide

Second, the product will be 2-Chloro-3-methylbutane. The reaction is given below:


hydrolysis of 3,3-Dimethyl butene

Third, the product formed will be 1-Chloro-3-methylbutane. The reaction is given below:


1,2-methyl

Fourth, the product formed will be 1-Chloro-2-methylbutane. The reaction is given below:


1,2-methyl

(iii) ${{\text{(C}{{\text{H}}_{\text{3}}}\text{)}}_{\text{2}}}\text{CHCH(C}{{\text{H}}_{\text{3}}}{{\text{)}}_{\text{2}}}$ 

Ans: There will be the formation of 2 products.

First, there will be the formation of 1-Chloro-2,3-dimethyl butane. The reaction is given below:


1,2-methyl

Second, there will be the formation of 2-Chloro-2,3-dimethyl. The reaction is given below:


1,2-methyl

16. 

(a)  When 3-methylbutan-2-ol is treated with HBr, the following reaction takes places :


hydrolysis of 3,3-Dimethyl butene

Give the mechanism of this reaction.

Ans: Below is the process for the reaction between 3-methyl butane-2-ol and HBr.

The -OH group is protonated in the first step. A water molecule is lost in the second stage, resulting in secondary carbocation.

The third stage is the 1,2-hydride shift, which converts less stable secondary carbocation to more stable tertiary carbocation.

The nucleophilic assault of bromide ion on the tertiary carbocation to produce 2-Bromo-2-methyl butane is the last step.


alkyl halide resulting in the production of dextro and laevo-rotatory alcohols in equal quantities

(b) In the following reaction:


Molecules with a benzene nucleus

Major and minor products are:

(i) 

Molecules are 2-Chloro-2,3-dimethyl butane

(ii)

2,3-Dimethylbut-2-ene and 2,3-Dimethylbut-1-enerespectively

(iii) 

Structure of the Compound C formed

(iv) 

Structure of the tertiary-butyl bromide

Ans: The terminal carbon atom will take the electrons of the double which will form a secondary carbocation. Now there will be a 1,2-methyl shift to form tertiary carbocation because of more stability. The hydroxyl will attack the carbocation and the product will be (iii). In another case, the electrons of the double bond will be taken by the second carbon and there will be the formation of primary carbocation and the hydroxyl ion will attack the carbocation which will form the product as (iv). The major product will be (iii) and the minor product will be (iv). The reaction is given below:


Structures of the Compounds (A),(B),(C),(D) and (E) formed

17. Give one use of each of the following:

(i) Freon-12

Ans: Industry uses Freon-12 ($\text{CC}{{\text{l}}_{\text{2}}}{{\text{F}}_{\text{2}}}$), which is the most prevalent form of the refrigerant.

Refrigerant or air-conditioning components, aerosol propellants.

(ii) DDT

Ans: Its efficacy against mosquitoes that carry malaria and other insects that harm crops led to a dramatic increase in its usage worldwide following World War II.

DDT, on the other hand, has been widely used since the 1940s. Toxic for fishes, DDT acquired tolerance in many insect species. When it comes to animals, DDT is not readily metabolized, but instead accumulates and is retained in fatty tissues. As long as the animals continue to eat DDT at the same rate, it builds up in their bodies.

(iii) Carbon tetrachloride

Ans: For oil, fats, and resins in the industrial sector, as well as in dry cleaning.

In addition, $\text{CC}{{\text{l}}_{\text{4}}}$ vapours are extremely inflammable, according to the manufacturer. As a result, $\text{CC}{{\text{l}}_{\text{4}}}$ is sold as pyrene, a fire extinguishing agent.

Used in the production of aerosol can refrigerants and propellants.

(iv) Iodoform

Ans: Early on it was considered to be an antiseptic, however, the characteristics are attributable to the free iodine that is released, not the substance itself. It has been superseded by other iodine-containing formulations due to its offensive odor.


18. An optically active compound having molecular formula ${{\text{C}}_{\text{7}}}{{\text{H}}_{\text{15}}}\text{Br}$ reacts with aqueous KOH to give ${{\text{C}}_{\text{7}}}{{\text{H}}_{\text{15}}}\text{OH}$, which is optically inactive. Give a mechanism for the reaction.

Ans: Because the intermediate carbocation produced is $\text{s}{{\text{p}}^{2}}$ hybridized and planar, racemization occurs when an optically alkyl halide undergoes the ${{\text{S}}_{\text{N}}}\text{1}$  process. The nucleophile ($\text{O}{{\text{H}}^{\text{-}}}$ ) has an equal chance of attacking it from both sides, resulting in the production of dextro and laevo-rotatory alcohols in equal quantities.

Although the compound ${{\text{C}}_{\text{7}}}{{\text{H}}_{\text{15}}}\text{Br}$ can have a variety of structures, the ${{\text{S}}_{\text{N}}}\text{1}$  mechanism is based on a tertiary alkyl halide. The reaction is given below:


4-Bromo-2,4-dimethylhexane

19. An organic compound ${{\text{C}}_{\text{8}}}{{\text{H}}_{\text{9}}}\text{Br}$ has three isomers A, B and C. A is optically active. Both A and B gave the white precipitate when warmed with alcoholic $\text{AgN}{{\text{O}}_{\text{3}}}$ solution in alkaline medium. Benzoic acid, terephthalic and p- bromobenzoic acid were obtained on oxidation of A, B and C respectively. Identify A, B and C.

Ans: Because all three chemicals produce molecules with a benzene nucleus when oxidized, they must all be benzene compounds. Because A and B produce white ppt. when reacting with $\text{AgN}{{\text{O}}_{\text{3}}}$, Br must be in the free form, i.e. Br is not directly linked to benzene in A and B but is in C. All the structures of A, B and C are given below:


2-Methyl-3-phenylpentane

20. An alkyl halide X having molecular formula ${{\text{C}}_{\text{6}}}{{\text{H}}_{\text{13}}}\text{Cl}$ on treatment with potassium tert-butoxide gives two isomeric alkenes Y and Z but alkene y is symmetrical. Both alkenes on hydrogenation give 2, 3-dimethylbutane.

Identify X, Y, and Z.

Ans: The given formula ${{\text{C}}_{\text{6}}}{{\text{H}}_{\text{13}}}\text{Cl}$  shows that it is an alkyl halide. Since the treatment of tert-butoxide gives alkene and both these on hydrogenation give 2, 3-Dimethylbutane, so the X compound will be 2-Chloro-2,3-dimethyl butane. Y is a symmetrical alkene so, its name will be 2,3-Dimethylbut-2-ene and Z is unsymmetrical alkene so, its name will be 2,3-Dimethylbut-1-ene. The structures of X, Y, and Z are given below:


5-Oxohexanoic acid

21. An organic compound (A) having molecular formula ${{\text{C}}_{\text{3}}}{{\text{H}}_{\text{7}}}\text{Cl}$ on reaction with alcoholic solution of KCN gives compound B. The compound B on hydrolysis with dilute HCl gives compound C. C on reduction with ${{\text{H}}_{\text{2}}}$ / Ni gives 1-aminobutane. Identify A, B and C.

Ans: The given formula ${{\text{C}}_{\text{3}}}{{\text{H}}_{\text{7}}}\text{Cl}$  shows that is it an alkyl halide. This reaction with KCN gives B and the compound B on hydrolysis with KCN gives C. When compound C is reduced with hydrogen and nickel it gives 1-aminobutane which means that all the compounds in the question are straight-chain compounds. So, compound A will be 1-Chloropropane, compound B will be Propionitrile, compound C will be Butanamide. The reactions are given below:

\[\text{C}{{\text{H}}_{\text{3}}}\text{-C}{{\text{H}}_{\text{2}}}\text{-C}{{\text{H}}_{\text{2}}}\text{-Cl + KCN }\to \text{ C}{{\text{H}}_{\text{3}}}\text{-C}{{\text{H}}_{\text{2}}}\text{-C}{{\text{H}}_{\text{2}}}\text{-CN + KCl}\] 

\[\text{C}{{\text{H}}_{\text{3}}}\text{-C}{{\text{H}}_{\text{2}}}\text{-C}{{\text{H}}_{\text{2}}}\text{-CN }\xrightarrow{{{\text{H}}_{\text{2}}}\text{O/HCl}}\text{ C}{{\text{H}}_{\text{3}}}\text{-C}{{\text{H}}_{\text{2}}}\text{-C}{{\text{H}}_{\text{2}}}\text{-CON}{{\text{H}}_{\text{2}}}\] 

\[\text{C}{{\text{H}}_{\text{3}}}\text{C}{{\text{H}}_{\text{2}}}\text{C}{{\text{H}}_{\text{2}}}\text{-CON}{{\text{H}}_{\text{2}}}\xrightarrow{{{\text{H}}_{\text{2}}}\text{/Ni}}\text{ C}{{\text{H}}_{\text{3}}}\text{C}{{\text{H}}_{\text{2}}}\text{C}{{\text{H}}_{\text{2}}}\text{C}{{\text{H}}_{\text{2}}}\text{N}{{\text{H}}_{\text{2}}}\] 


22. Identify A, B, C, D, E, R and ${{\text{R}}^{\text{1}}}$ in the following:


seo images

Ans: The compound A in the reaction is cyclohexylmagnesium bromide, compound B is Cyclohexane. 

Compound R –Br will be 2-Bromopropane and the compound C is given below:


seo images

The third part of the question is incorrect because the tertiary-alkyl halides do not undergo Wurtz reaction but they undergo dehydrohalogenation to give alkenes. 

So, the compound ${{\text{R}}^{\text{1}}}\text{-Br}$ is given below:


seo images

Compound D is Tertiary butyl magnesium bromide and compound E is 2-Methylpropane.

The complete reaction is given below


seo images

23. Which nomenclature is not according to the IUPAC system.

(i) $\text{Br-C}{{\text{H}}_{\text{2}}}\text{CH=C}{{\text{H}}_{\text{2}}}$ : 1-Bromoprop-2-ene

Ans: This is the wrong name because the numbering preference will be given to the double bond, therefore, the numbering will start from the double bond. Hence, the correct name will be 3-Bromoprop-1-ene.

(ii)

seo images

4-Bromo-2,4-dimethylhexane 

Ans: The name of the compound given is correct as it follows the IUPAC rules.

(iii)

seo images

2-Methyl-3-phenylpentane

Ans: The name of the compound given is correct as it follows the IUPAC rules.

(iv) 


seo images

5-Oxohexanoic acid

Ans: The name of the compound given is correct as it follows the IUPAC rules. 


Important Topics Covered in CBSE Class 12 Haloalkanes and Haloarenes  

The important questions of Haloalkanes and Haloarenes of Class 12 cover the topics of:

  • Classification

  • Nomenclature

  • Nature of C-X Bond

  • Methods of Preparation

  • Types of Reactions (Elimination, substitution, etc)

  • Physical and Chemical properties, the order of reactivity.

  • Reagents

  • Polyhalogen Compounds


Extra questions of Haloalkanes and Haloarenes are very helpful to streamline the preparation and revision of these topics.


Important Questions for Class 12 Chemistry Chapter 6 - Extra Questions for Practice

  1. Distinguish between C2H5Br and C6H5Br with a chemical test.

  2. Arrange the following according to the increasing order of their boiling points:

I. CH3CH2CH2CH2Br

II. (CH3)3.Br

III. (CH3)2C.Br 

  1. Why Chlorobenzene is less reactive with a nucleophilic substitution reaction?

  2. Benzyl chloride and Chlorobenzene - Distinguish between the two with the help of a chemical test.

  3. Why is the dipole moment of chlorobenzene lower than cyclohexyl chloride?

  4. Explain ambident nucleophiles.


Salient Features of Class 12 Chemistry Chapter 6 Important Questions

Take a look at the important features of this study material which will help the students to prepare for their Class 12 Chemistry examination:

  • Important questions of Haloalkanes and Haloarenes of Class 12 PDF can be downloaded easily from our website and students can learn from it anywhere and at any time. 

  • These PDFs include various questions and answers along with the problems given in the exercise, for the better practice of students. 

  • These questions and solutions are carefully prepared by our subject experts in such a way that by referring to them students can clear their doubts and boost their exam preparation.

  • All the important concepts of this chapter are included in this content in the form of important questions.

  • The important questions are presented in the form of a free PDF, which helps in convenient learning of this chapter. 


Important Questions for Class 12 Chemistry Chapter 6 - Summary of the Chapter

Haloalkanes and Haloarenes are formed by the replacement of a hydrogen atom with a halogen atom in an aromatic compound or aliphatic hydrocarbons. Haloalkanes are formed by substitution of H atom in aliphatic hydrocarbon and the same replacement in aromatic compounds gives rise to Haloarenes. The chemical is used as a solvent in the case of non-polar compounds. Its application can be seen in refrigerants, pharmaceuticals, etc. 

 

Important Questions for Class 12 Chemistry Chapter 6 - Study With Vedantu 

The solutions to important questions from Haloalkanes and Haloarenes along with NCERT solutions, MCQs, assignments, and worksheets on Vedantu will help students to learn the concepts comprehensively. Also, it will help them in making notes for the competitive examinations. How else Vedantu will guide you?

  • In addition to the solutions, Vedantu also provides some of the best subject experts who can guide students to learn the subject in a more simplified and conceptual manner. 

  • Along with that, we provide free access to all our study materials.  

  • The study materials have been set in a manner to help students learn quickly and remember the concepts for longer. 

So, go through the set of important questions of Haloalkanes and Haloarenes of Class 12 and prepare well for your exams.

 

Well, this content is specially targeted to the CBSE Class 12 Chemistry students who are willing to know and study the important questions and answers from the chapter - Haloalkanes and Haloarenes. 


We have provided the pdf of the important questions from this chapter in order to have a convenient study. Additionally, we also have provided some extra questions for practice and the students are suggested to refer to the added links at the end of this content. 


Important Related Links for CBSE Class 12 Chemistry 

CBSE Class 12 Chemistry Study Materials

CBSE Class 12 Chemistry NCERT Solutions

CBSE Class 12 Chemistry Important Questions

CBSE Class 12 Chemistry NCERT Exemplar Solutions

CBSE Class 12 Chemistry Sample Papers

CBSE Class 12 Chemistry Previous Year Question Papers

CBSE Class 12 Chemistry Syllabus


Conclusion 

The compilation of Important Questions for CBSE Class 12 Chemistry Chapter 6 - Haloalkanes and Haloarenes serves as a vital tool for students' exam preparation. These questions are carefully curated to cover key concepts, reactions, and topics within the chapter, ensuring comprehensive revision. They provide students with a strategic approach to studying, helping them identify crucial areas to focus on and assess their knowledge. These questions also mirror the exam pattern and difficulty level, thus aiding in building confidence and readiness for the final assessment. Overall, these important questions are an indispensable resource for Class 12 Chemistry students, offering a structured pathway towards academic success in this challenging subject.

FAQs on CBSE Chemistry Chapter 6 Haloalkanes and Haloarenes Class 12 Important Questions

1. What are the important subtopics in Haloalkanes and Haloarenes of Class 12 Chemistry for NEET?

According to past observations, the question papers for NEET over the years consisted of 3% of the total question based on Haloalkanes and Haloarenes. So, it is necessary to prepare the important subtopics from the chapter. These include:

  • Preparation of haloalkanes

  • Stereochemistry

  • Physical and chemical properties of haloalkanes

  • Preparation of haloarenes

  • Nucleophilic substitution mechanism

  • Uses and environmental effects of some haloalkanes and haloarenes

  • Physical and chemical properties of haloarenes

2. What are Haloalkanes and Haloarenes according to Chapter 6 of Class 12 Chemistry?

As discussed in Chapter 6 of Class 12 Chemistry, Haloalkanes are hydrocarbons containing aliphatic alkane with one or more hydrogen atoms replaced by halogens while Haloarenes are hydrocarbons containing aromatic alkane with halogens replacing one or more hydrogen atoms. Haloalkanes are aliphatic hydrocarbons, however, haloarenes are aromatic hydrocarbons. Students can find further explanations and differences between the two available on Vedantu’s e-platform.

3. Where can I find important questions for Chapter 6 Class 12 Chemistry?

Vedantu is an e-platform providing the students with one of the best study materials meant to help them enhance their understanding, practice in a more efficient way, revise easily, and make their preparation stronger for their Class 12 exams. You can access such study material like Important Questions for CBSE Class 12 Chemistry Chapter 6  available on Vedantu’s online website as well as the mobile app.

4. What are the rules of nomenclature of Haloalkanes?

The following are the rules of nomenclature of Haloalkanes 

  • Look for the longest carbon chain.

  • Put the longest carbon chain in numerical order in a way that the carbon atoms to which the halogens are attached get the lowest numbers. 

  • In case there is more than one halogen atom attached to the same carbon atom, the numeral is repeated many times. But if there are different types of halogens attached, name them alphabetically.

  • Denote the position of the halogen atom by writing the name and position of the halogen right before the name of the parent hydrocarbon.

5. Do I need to practice all questions covered in Important Questions for Class 12 Chemistry Chapter 6?

Questions that have been covered by Vedantu in the Important Questions for CBSE Class 12 Chemistry Chapter 6 - Haloalkanes and Haloarenes all need to be practised well before your Class 12 Chemistry Exam. This is necessary because it cannot be predicted which questions are asked in the exam and ignoring any questions during your preparation may lead to a loss of marks. Hence, students must ensure that they thoroughly prepare all the important questions provided.