Answer
405.3k+ views
Hint: To make a correct tautomer we see the type of functional group and then we see the movement of the lone pair. When we move the lone pair and migrate the hydrogen to the correct position, we get the tautomer.
Complete step by step answer:
The above tautomerism is a functional group isomerism. In the functional group isomerism, the carbon skeleton of that compound is totally unchanged but it shows proton transfer in an intramolecular way. Since the functional group is the amine group so the tautomerism is imine-enamine isomerism.
Amines show tautomerism by getting converted to imine form. To show isomerism or tautomerism it should contain at least \[1\] alpha-hydrogen in it. This alpha-hydrogen is shifted or migrated to the nitrogen.
Enamine Imine
For stability among these two we will see the analogy between ketones and amines. In ketones the
is more stable than
because of a stable carbon-oxygen bond. Similarly,
is less stable than
because the latter one contains a carbon- nitrogen double bond which is very stable.
So, imine is more stable than enamine form. Enamine will form only when imine form formation is difficult to form in those circumstances.
So, the correct answer is Option B.
Note: Tautomerism is a type of isomerism only as there is no change in the main carbon skeleton only migration of proton or group is there, more precisely tautomerism is a functional group isomerism.
It is compulsory for the tautomer to have alpha-hydrogen for the migration or shifting. As we know that double bonds are stronger than the single bond and if the bond is between carbon and electronegative group then it is fairly more stable.
Complete step by step answer:
The above tautomerism is a functional group isomerism. In the functional group isomerism, the carbon skeleton of that compound is totally unchanged but it shows proton transfer in an intramolecular way. Since the functional group is the amine group so the tautomerism is imine-enamine isomerism.
Amines show tautomerism by getting converted to imine form. To show isomerism or tautomerism it should contain at least \[1\] alpha-hydrogen in it. This alpha-hydrogen is shifted or migrated to the nitrogen.
![seo images](https://www.vedantu.com/question-sets/b2becf55-64f2-4af7-8c12-e9693f0735356213191627359102945.png)
Enamine Imine
For stability among these two we will see the analogy between ketones and amines. In ketones the
![seo images](https://www.vedantu.com/question-sets/28a06f71-77ec-4535-bce5-14e9b7e1217e5922037286292209264.png)
![seo images](https://www.vedantu.com/question-sets/33a65800-9eeb-4b3d-9190-6f18cf23e5ac4096237637528066207.png)
![seo images](https://www.vedantu.com/question-sets/52490d89-3c89-430a-b424-fe18808ac4e46132087139996227853.png)
![seo images](https://www.vedantu.com/question-sets/ad81535d-2aed-41ee-8186-35e2b18664d56257699998257203633.png)
So, imine is more stable than enamine form. Enamine will form only when imine form formation is difficult to form in those circumstances.
So, the correct answer is Option B.
Note: Tautomerism is a type of isomerism only as there is no change in the main carbon skeleton only migration of proton or group is there, more precisely tautomerism is a functional group isomerism.
It is compulsory for the tautomer to have alpha-hydrogen for the migration or shifting. As we know that double bonds are stronger than the single bond and if the bond is between carbon and electronegative group then it is fairly more stable.
Recently Updated Pages
How many sigma and pi bonds are present in HCequiv class 11 chemistry CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Why Are Noble Gases NonReactive class 11 chemistry CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Let X and Y be the sets of all positive divisors of class 11 maths CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Let x and y be 2 real numbers which satisfy the equations class 11 maths CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Let x 4log 2sqrt 9k 1 + 7 and y dfrac132log 2sqrt5 class 11 maths CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Let x22ax+b20 and x22bx+a20 be two equations Then the class 11 maths CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Trending doubts
Fill the blanks with the suitable prepositions 1 The class 9 english CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
At which age domestication of animals started A Neolithic class 11 social science CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Which are the Top 10 Largest Countries of the World?
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Give 10 examples for herbs , shrubs , climbers , creepers
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Difference between Prokaryotic cell and Eukaryotic class 11 biology CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Difference Between Plant Cell and Animal Cell
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Write a letter to the principal requesting him to grant class 10 english CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Change the following sentences into negative and interrogative class 10 english CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Fill in the blanks A 1 lakh ten thousand B 1 million class 9 maths CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)