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Name the reagent used to convert benzyl alcohol to benzoic acid.

Last updated date: 20th Jun 2024
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Hint: We will need to convert $-C{{H}_{2}}OH$ group of benzyl alcohol into –COOH group to complete this reaction. This is a simple oxidation reaction. An inorganic compound which contains a transition metal in its structure can be used in this conversion.

Complete step by step answer:
- Look, Benzyl alcohol is a primary alcohol and benzoic acid contains a carboxylic acid functional group. So, if we can oxidise the carbon of benzyl alcohol which contains hydroxyl group, then we will get the product benzoic acid.
- We can use an acidic, neutral or alkaline solution of $KMn{{O}_{4}}$ to oxidise any primary alcohol to carboxylic acid. So, we can use alkaline potassium permanganate solution to convert benzyl alcohol to benzoic acid.
- It is proved that out of these types of solutions, acidic potassium permanganate is the most strong reagent. $KMn{{O}_{4}}$ in neutral medium is weaker than it in acidic medium and in when $KMn{{O}_{4}}$ is in alkaline medium, it is weakest amongst three.
- We can write the reaction as follows:
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- Remember that Jones reagent ($Cr{{O}_{3}}+{{H}_{2}}S{{O}_{4}}$) can also convert most primary alcohols to carboxylic acids but in case of Benzyl alcohol, Jones reagent will first convert it into Benzaldehyde but this reaction will involve formation of hydrates of aldehyde while, benzaldehyde is not able to form stable hydrates. So, this is the reason that we will not be able to use Jones reagent for this conversion.

Do not get confused in between benzyl, benzal and benzo prefixes. When ‘benzyl’ prefix is used, it means that the carbon that is attached to the benzene ring has two hydrogen atoms. While in case of benzal, this carbon carries one hydrogen atom and in case of benzo, there is no hydrogen attached to the carbon that is directly bonded to the benzene ring.