Answer
Verified
446.4k+ views
Hint: Isomerism is defined as the process where more than just one compound contains the same chemical formulas, but they have different chemical structures. There exists two types of isomerism namely structural isomerism and stereoisomerism.
Complete step-by-step solution:
Let us see the difference between structural and stereoisomers:
> The isomers in which the molecules having the same molecular formula are arranged with different bonding patterns and atomic orientation are called the structural isomerism. Structural isomerism is classified as chain isomers, positional isomers, functional isomers, metamerism, tautomerism and ring chain.
> The isomers in which the molecular bonds are placed in the same order and where the spatial arrangements differ are called the stereoisomers. Stereoisomers are classified as geometrical isomers and optical isomers.
> Ionisation isomerism is shown by such compounds in solution that give different ions although they possess the same chemical composition. Ionisation isomerism is seen to occur in a complex salt when its counter ion is a potential ligand and this counter ion can displace a ligand making it to behave or become a counter ion.
> One example of ionisation isomerism is $\left[ {{\rm{Co}}{{\left( {{\rm{N}}{{\rm{H}}_{\rm{3}}}} \right)}_{\rm{5}}}{\rm{S}}{{\rm{O}}_{\rm{4}}}} \right]{\rm{Br}}$ and $\left[ {{\rm{Co}}{{\left( {{\rm{N}}{{\rm{H}}_{\rm{3}}}} \right)}_{\rm{5}}}{\rm{Br}}} \right]{\rm{S}}{{\rm{O}}_{\rm{4}}}$.
> The structure of both the isomers $\left[ {{\rm{Co}}{{\left( {{\rm{N}}{{\rm{H}}_{\rm{3}}}} \right)}_{\rm{5}}}{\rm{S}}{{\rm{O}}_{\rm{4}}}} \right]{\rm{Br}}$ and $\left[ {{\rm{Co}}{{\left( {{\rm{N}}{{\rm{H}}_{\rm{3}}}} \right)}_{\rm{5}}}{\rm{Br}}} \right]{\rm{S}}{{\rm{O}}_{\rm{4}}}$are given below.
$\left[ {{\rm{Co}}{{\left( {{\rm{N}}{{\rm{H}}_{\rm{3}}}} \right)}_{\rm{5}}}{\rm{Br}}} \right]{\rm{S}}{{\rm{O}}_{\rm{4}}}$ $\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,$ $\left[ {{\rm{Co}}{{\left( {{\rm{N}}{{\rm{H}}_{\rm{3}}}} \right)}_{\rm{5}}}{\rm{S}}{{\rm{O}}_{\rm{4}}}} \right]{\rm{Br}}$
We can prepare these ionisation isomers in the following way:
$\begin{array}{l}\left[ {{\rm{CoBr}}{{\left( {{\rm{N}}{{\rm{H}}_{\rm{3}}}} \right)}_{\rm{5}}}} \right]{\rm{S}}{{\rm{O}}_{\rm{4}}} \to {\left[ {{\rm{CoBr}}{{\left( {{\rm{N}}{{\rm{H}}_{\rm{3}}}} \right)}_{\rm{5}}}} \right]^{2 + }} + {\rm{SO}}_4^{2 - }\\{\rm{ Red - Violet}}\end{array}$
$\begin{array}{l}\left[ {{\rm{Co S}}{{\rm{O}}_{\rm{4}}}{{\left( {{\rm{N}}{{\rm{H}}_{\rm{3}}}} \right)}_{\rm{5}}}} \right]{\rm{Br}} \to {\left[ {{\rm{Co SO}}_4^{2 - }{{\left( {{\rm{N}}{{\rm{H}}_{\rm{3}}}} \right)}_{\rm{5}}}} \right]^ + } + {\rm{B}}{{\rm{r}}^ - }\\{\rm{ Red}}\end{array}$
Note: Students may get confused about how ionisation isomerism looks like. In ionisation isomerism, the compounds in solution give different ions although they possess the same chemical composition. The difference in ionisation isomerism is due to the difference in position of placing the atoms or groups in the coordination sphere.
Complete step-by-step solution:
Let us see the difference between structural and stereoisomers:
> The isomers in which the molecules having the same molecular formula are arranged with different bonding patterns and atomic orientation are called the structural isomerism. Structural isomerism is classified as chain isomers, positional isomers, functional isomers, metamerism, tautomerism and ring chain.
> The isomers in which the molecular bonds are placed in the same order and where the spatial arrangements differ are called the stereoisomers. Stereoisomers are classified as geometrical isomers and optical isomers.
> Ionisation isomerism is shown by such compounds in solution that give different ions although they possess the same chemical composition. Ionisation isomerism is seen to occur in a complex salt when its counter ion is a potential ligand and this counter ion can displace a ligand making it to behave or become a counter ion.
> One example of ionisation isomerism is $\left[ {{\rm{Co}}{{\left( {{\rm{N}}{{\rm{H}}_{\rm{3}}}} \right)}_{\rm{5}}}{\rm{S}}{{\rm{O}}_{\rm{4}}}} \right]{\rm{Br}}$ and $\left[ {{\rm{Co}}{{\left( {{\rm{N}}{{\rm{H}}_{\rm{3}}}} \right)}_{\rm{5}}}{\rm{Br}}} \right]{\rm{S}}{{\rm{O}}_{\rm{4}}}$.
> The structure of both the isomers $\left[ {{\rm{Co}}{{\left( {{\rm{N}}{{\rm{H}}_{\rm{3}}}} \right)}_{\rm{5}}}{\rm{S}}{{\rm{O}}_{\rm{4}}}} \right]{\rm{Br}}$ and $\left[ {{\rm{Co}}{{\left( {{\rm{N}}{{\rm{H}}_{\rm{3}}}} \right)}_{\rm{5}}}{\rm{Br}}} \right]{\rm{S}}{{\rm{O}}_{\rm{4}}}$are given below.
$\left[ {{\rm{Co}}{{\left( {{\rm{N}}{{\rm{H}}_{\rm{3}}}} \right)}_{\rm{5}}}{\rm{Br}}} \right]{\rm{S}}{{\rm{O}}_{\rm{4}}}$ $\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,$ $\left[ {{\rm{Co}}{{\left( {{\rm{N}}{{\rm{H}}_{\rm{3}}}} \right)}_{\rm{5}}}{\rm{S}}{{\rm{O}}_{\rm{4}}}} \right]{\rm{Br}}$
We can prepare these ionisation isomers in the following way:
$\begin{array}{l}\left[ {{\rm{CoBr}}{{\left( {{\rm{N}}{{\rm{H}}_{\rm{3}}}} \right)}_{\rm{5}}}} \right]{\rm{S}}{{\rm{O}}_{\rm{4}}} \to {\left[ {{\rm{CoBr}}{{\left( {{\rm{N}}{{\rm{H}}_{\rm{3}}}} \right)}_{\rm{5}}}} \right]^{2 + }} + {\rm{SO}}_4^{2 - }\\{\rm{ Red - Violet}}\end{array}$
$\begin{array}{l}\left[ {{\rm{Co S}}{{\rm{O}}_{\rm{4}}}{{\left( {{\rm{N}}{{\rm{H}}_{\rm{3}}}} \right)}_{\rm{5}}}} \right]{\rm{Br}} \to {\left[ {{\rm{Co SO}}_4^{2 - }{{\left( {{\rm{N}}{{\rm{H}}_{\rm{3}}}} \right)}_{\rm{5}}}} \right]^ + } + {\rm{B}}{{\rm{r}}^ - }\\{\rm{ Red}}\end{array}$
Note: Students may get confused about how ionisation isomerism looks like. In ionisation isomerism, the compounds in solution give different ions although they possess the same chemical composition. The difference in ionisation isomerism is due to the difference in position of placing the atoms or groups in the coordination sphere.
Recently Updated Pages
How many sigma and pi bonds are present in HCequiv class 11 chemistry CBSE
Mark and label the given geoinformation on the outline class 11 social science CBSE
When people say No pun intended what does that mea class 8 english CBSE
Name the states which share their boundary with Indias class 9 social science CBSE
Give an account of the Northern Plains of India class 9 social science CBSE
Change the following sentences into negative and interrogative class 10 english CBSE
Trending doubts
Which are the Top 10 Largest Countries of the World?
Fill the blanks with the suitable prepositions 1 The class 9 english CBSE
How do you graph the function fx 4x class 9 maths CBSE
The Equation xxx + 2 is Satisfied when x is Equal to Class 10 Maths
One Metric ton is equal to kg A 10000 B 1000 C 100 class 11 physics CBSE
Give 10 examples for herbs , shrubs , climbers , creepers
Differentiate between homogeneous and heterogeneous class 12 chemistry CBSE
Difference between Prokaryotic cell and Eukaryotic class 11 biology CBSE
Why is there a time difference of about 5 hours between class 10 social science CBSE