Answer
Verified
396.6k+ views
Hint: We can prepare chlorobenzene from aniline by using Sandmeyer reaction, by using fittig reaction we can prepare diphenyl from chlorobenzene.
Complete step by step answer:
Sandmeyer reaction: “The Sandmeyer reaction is a chemical reaction used to synthesize aryl halides from aryl diazonium salts using copper salts as reagents or catalysts. It is an example of a radical-nucleophilic aromatic substitution”.
It is a two-step reaction
In the first step aniline is going to convert to benzene diazonium chloride using sodium Nitrate and aqueous hydrochloric acid.
In the second step benzene diazonium chloride reacts with cuprous chloride and forms chloro benzene. Aryl diazonium chloride is very reactive, whenever aryldiazonium chloride forms it will react with cuprous chloride and forms chlorobenzene.
Fittig reaction: “Fittig reaction is the chemical reaction of aryl halides with sodium metal in the presence of dry ether to give substituted aromatic compounds”.
Two moles of chlorobenzene react in presence of sodium and dry ether and forms biphenyl compounds and 2 moles of sodium chloride (insoluble in dry ether).
Note: Don’t be get confused with Sandmeyer reaction and Fittig reaction
Sandmeyer reaction: Preparation of chlorobenzene from Aniline by using sodium nitrate, aq. Hydrochloric acid and cuprous chloride.
Fittig reaction: Preparation of Diphenyl form Chlorobenzene by using sodium metal and dry ether.
Complete step by step answer:
Sandmeyer reaction: “The Sandmeyer reaction is a chemical reaction used to synthesize aryl halides from aryl diazonium salts using copper salts as reagents or catalysts. It is an example of a radical-nucleophilic aromatic substitution”.
It is a two-step reaction
In the first step aniline is going to convert to benzene diazonium chloride using sodium Nitrate and aqueous hydrochloric acid.
In the second step benzene diazonium chloride reacts with cuprous chloride and forms chloro benzene. Aryl diazonium chloride is very reactive, whenever aryldiazonium chloride forms it will react with cuprous chloride and forms chlorobenzene.
Fittig reaction: “Fittig reaction is the chemical reaction of aryl halides with sodium metal in the presence of dry ether to give substituted aromatic compounds”.
Two moles of chlorobenzene react in presence of sodium and dry ether and forms biphenyl compounds and 2 moles of sodium chloride (insoluble in dry ether).
Note: Don’t be get confused with Sandmeyer reaction and Fittig reaction
Sandmeyer reaction: Preparation of chlorobenzene from Aniline by using sodium nitrate, aq. Hydrochloric acid and cuprous chloride.
Fittig reaction: Preparation of Diphenyl form Chlorobenzene by using sodium metal and dry ether.
Recently Updated Pages
Basicity of sulphurous acid and sulphuric acid are
Three beakers labelled as A B and C each containing 25 mL of water were taken A small amount of NaOH anhydrous CuSO4 and NaCl were added to the beakers A B and C respectively It was observed that there was an increase in the temperature of the solutions contained in beakers A and B whereas in case of beaker C the temperature of the solution falls Which one of the following statements isarecorrect i In beakers A and B exothermic process has occurred ii In beakers A and B endothermic process has occurred iii In beaker C exothermic process has occurred iv In beaker C endothermic process has occurred
What is the stopping potential when the metal with class 12 physics JEE_Main
The momentum of a photon is 2 times 10 16gm cmsec Its class 12 physics JEE_Main
How do you arrange NH4 + BF3 H2O C2H2 in increasing class 11 chemistry CBSE
Is H mCT and q mCT the same thing If so which is more class 11 chemistry CBSE
Trending doubts
Difference between Prokaryotic cell and Eukaryotic class 11 biology CBSE
Fill the blanks with the suitable prepositions 1 The class 9 english CBSE
Write an application to the principal requesting five class 10 english CBSE
Difference Between Plant Cell and Animal Cell
a Tabulate the differences in the characteristics of class 12 chemistry CBSE
Change the following sentences into negative and interrogative class 10 english CBSE
What organs are located on the left side of your body class 11 biology CBSE
Discuss what these phrases mean to you A a yellow wood class 9 english CBSE
List some examples of Rabi and Kharif crops class 8 biology CBSE