Answer
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Hint:
The full form of 2,4-DNPH is 2,4-dinitrophenylhydrazine. It has a nucleophilic nitrogen atom which can attack the electrophilic atom. It is also called Brady’s reagent.
Complete step by step solution:
We first need to know what 2,4-DNPH is in order to find and solve this question.
- 2,4-DNPH stands for 2,4-dinitrophenylhydrazine. It is red to orange coloured powder. It is slightly soluble in water.
- 2,4-DNPH is used to identify the functional group present in the compound. So, it is used in organic qualitative analysis.
- 2,4-DNPH is used to identify the aldehydes and ketone, functional groups. It is also called Brady’s reagent. The reaction of 2,4-DNPH with aldehydes or ketones can be given as below with mechanism.
- We can see that the nucleophilic nitrogen atom of 2,4-DNPH attacks the electrophilic carbonyl carbon and C-O double bond is cleaved. Then the loss of the water molecule gives phenyl hydrazone as a final product which is orange in colour. This reaction can be considered as a condensation reaction.
- Thus, the derivative obtained can be checked for the melting point and we can confirm the organic compound from this test.
- So, we can conclude that 2,4-DNPH is used to identify aldehyde and ketones.
Note: Remember that this reagent cannot give orange precipitates with other functional groups that have carbonyl groups like esters, acids, etc. This happens because they are romance stabilized and hence do not give these types of additional reactions easily.
The full form of 2,4-DNPH is 2,4-dinitrophenylhydrazine. It has a nucleophilic nitrogen atom which can attack the electrophilic atom. It is also called Brady’s reagent.
Complete step by step solution:
We first need to know what 2,4-DNPH is in order to find and solve this question.
- 2,4-DNPH stands for 2,4-dinitrophenylhydrazine. It is red to orange coloured powder. It is slightly soluble in water.
- 2,4-DNPH is used to identify the functional group present in the compound. So, it is used in organic qualitative analysis.
- 2,4-DNPH is used to identify the aldehydes and ketone, functional groups. It is also called Brady’s reagent. The reaction of 2,4-DNPH with aldehydes or ketones can be given as below with mechanism.
![seo images](https://www.vedantu.com/question-sets/99193782-0665-4aa8-8da9-b0364932d5fc910290911593779431.png)
- We can see that the nucleophilic nitrogen atom of 2,4-DNPH attacks the electrophilic carbonyl carbon and C-O double bond is cleaved. Then the loss of the water molecule gives phenyl hydrazone as a final product which is orange in colour. This reaction can be considered as a condensation reaction.
- Thus, the derivative obtained can be checked for the melting point and we can confirm the organic compound from this test.
- So, we can conclude that 2,4-DNPH is used to identify aldehyde and ketones.
Note: Remember that this reagent cannot give orange precipitates with other functional groups that have carbonyl groups like esters, acids, etc. This happens because they are romance stabilized and hence do not give these types of additional reactions easily.
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