
The reagent used for obtaining the osazone derivative of fructose is
A. \[N{H_2}OH\]
B. \[N{H_2}-N{H_2}\]
C. \[N{H_2}-NH{C_6}{H_5}\]
D. \[2,{\rm{ }}4 - DNP\]
Answer
162.9k+ views
Hint: Fructose, or fruit sugar, is a ketogenic simple sugar set up in numerous plants. Osazones are a category of carbohydrate derivatives formed from the reaction of reducing sugars with excess phenylhydrazine at boiling temperatures.
Complete Step by Step Answer:
Reducing sugar is any sugar that is apt to work as a reducing agent.
In an alkaline solution, a reducing sugar yields some aldehyde or ketone, which lets it work as a reducing agent, such as Benedict's reagent.
Every monosaccharide is a reducing sugar.
Fructose is a monosaccharide that has a ketone group.
So, it is a type of ketose that undergoes tautomerization to aldoses and then acts as reducing sugars.
Fructose in presence of excess phenylhydrazine forms an osazone derivative.
This reaction is a reduction of phenylhydrazine by fructose.
Fructose acts as a reducing agent by undergoing oxidation itself.
Hence, osazone is an oxidation product.
Step-1: The carbonyl group present in the fructose reacts with phenylhydrazine to form phenylhydrazone. During this phase, one molecule of hydrazine is used.
Step-2: This phenylhydrazone then reacts with two molecules of phenylhydrazine to form osazone.
The second molecule of phenylhydrazine oxidises the reactive hydroxyl group to develop the aldehyde group. This is because the ketone group had undergone a reaction in the first step itself.
Step-3: Lastly, the molecule of the phenylhydrazine that is left reacts with the newly created carbonyl group and converts fructose into osazone.
The mechanism is as follows:

Image: Mechanism of conversion of fructose into its osazone derivative.
Out of the given options, option C i.e., \[N{H_2}-NH{C_6}{H_5}\] is the formula for phenylhydrazine.
So, option C is correct.
Note: This reaction needs a free carbonyl group. So, reducing sugars like glucose, and fructose undergoes this type of reaction. Sucrose is a non-reducing sugar that does not constitute an osazone. Sucrose is a disaccharide sugar made up of glucose and fructose subunits. It has glycosidic bonds with the carbon atoms of fructose and glucose and its transition into an open-chain form with an aldehyde group is not possible as they contain a cyclic structure.
Complete Step by Step Answer:
Reducing sugar is any sugar that is apt to work as a reducing agent.
In an alkaline solution, a reducing sugar yields some aldehyde or ketone, which lets it work as a reducing agent, such as Benedict's reagent.
Every monosaccharide is a reducing sugar.
Fructose is a monosaccharide that has a ketone group.
So, it is a type of ketose that undergoes tautomerization to aldoses and then acts as reducing sugars.
Fructose in presence of excess phenylhydrazine forms an osazone derivative.
This reaction is a reduction of phenylhydrazine by fructose.
Fructose acts as a reducing agent by undergoing oxidation itself.
Hence, osazone is an oxidation product.
Step-1: The carbonyl group present in the fructose reacts with phenylhydrazine to form phenylhydrazone. During this phase, one molecule of hydrazine is used.
Step-2: This phenylhydrazone then reacts with two molecules of phenylhydrazine to form osazone.
The second molecule of phenylhydrazine oxidises the reactive hydroxyl group to develop the aldehyde group. This is because the ketone group had undergone a reaction in the first step itself.
Step-3: Lastly, the molecule of the phenylhydrazine that is left reacts with the newly created carbonyl group and converts fructose into osazone.
The mechanism is as follows:

Image: Mechanism of conversion of fructose into its osazone derivative.
Out of the given options, option C i.e., \[N{H_2}-NH{C_6}{H_5}\] is the formula for phenylhydrazine.
So, option C is correct.
Note: This reaction needs a free carbonyl group. So, reducing sugars like glucose, and fructose undergoes this type of reaction. Sucrose is a non-reducing sugar that does not constitute an osazone. Sucrose is a disaccharide sugar made up of glucose and fructose subunits. It has glycosidic bonds with the carbon atoms of fructose and glucose and its transition into an open-chain form with an aldehyde group is not possible as they contain a cyclic structure.
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