Question

Let T be the mean life of a radioactive sample, ${ 75\% }$ of the active nuclei present in the sample initially will decay in time:
A. ${ 2T }$
B. ${ 1/2=(log_{ e } }{ 2)T }$
C. ${ 4T }$
D. ${ 2(log_{ e } }{ )T }$

Answer 1

Hint: First order reaction: A first-order reaction is a reaction that proceeds at a rate that depends linearly on only one reactant concentration.
The rate increases as the number of times the concentration of reaction is increased. The half-life of first-order reactions: Half-life of a reaction is the time taken for half of the reaction to be completed.

Complete step-by-step solution:
Now,
${ t }_{ 1/2 }{ =ln2/k }$………..(1)
where , ${ t }_{ 1/2 }$ = half life
k= reaction rate constant
ln2 = base e logarithm

It is given that,
${ 75\% }$ of the active nuclei present in the sample initially will decay in time, so, ${ 25\% }$ is left undecayed.
${ 75\% }$ consumption = ${ 25\% }$ nuclei remains
Using the formula; ${ N= }{ N }_{ 0 }{ e }^{ -\lambda t }$……..(2)
where, ${ N }_{ 0 }$ = number of radioactive nuclei at any arbitrary time, ${ t }_{ 0 }$
N = number of radioactive nuclei at any time,t
${ \lambda }$ = decay constant
t = time

Let, initially decay = ${ N }_{ 0 }$
After ${ 75\% }$ decay = ${ N }_{ 0 }{ \div 4 }$
By putting the values in equation (2), we get

${ N }_{ 0 }{ \div 4 }= { N }_{ 0 }{ e }^{ -\lambda t }$
${ 1\div 4{ =1\div { e }^{ \lambda t } } }$
${ e }^{ \lambda t }{ =4 }$
Taking ln on both the sides, we get
${ ln }_{ e }{ e }^{ \lambda t }{ =ln4 }$
${ \lambda t\quad =\quad ln{ 2 }^{ 2 } }$
${ \lambda t\quad =\quad 2ln2 }$ ……….(3)

Now, as we know that ${ \lambda =1\div T }$
where, ${ \lambda }$ = decay constant
 T = mean life
 By putting the value of ${ \lambda }$ in equation (3), we get
${ (1\div T)t\quad =2(ln2) }$
${ t\quad =2(ln2)T }$
Hence, the correct option is D.

Note: The possibility to make a mistake is that you may confuse between log and ln in the formulas. ${ ln=2.303log }$. Don’t forget to apply this formula.