Answer
64.8k+ views
Hint: The structure requires a leaving group and a hydrogen atom at the adjacent carbon to the carbon which is bearing the leaving group. A good leaving is usually a weak base. Benzyne involves a C-C triple bond in its structure.
Complete step by step solution:
-Benzyne is a six-member hydrocarbon ring involving two double bonds and a C-C triple bond.
-In the mechanism of formation of benzyne, it is necessary for the structure to have a good leaving group. Alongside a good leaving group, it is also necessary to have a hydrogen atom at adjacent carbon which can leave to form benzyne. In short, we can show the formation of benzyne as
![](https://www.vedantu.com/question-sets/db701f27-8010-41b9-a9a5-e2f09242b8336217425430859333600.png)
Here LG is leaving the group.
Let’s see the compounds given in all the options in order to find which one will not give benzyne.
(A)
![](https://www.vedantu.com/question-sets/37ed805b-fd9b-4325-86b4-2947af9f85448781385072050793624.png)
So, in this case, benzyne intermediate can be formed as $ - OC{H_3}$ is a good leaving group and there is a hydrogen atom at the adjacent carbon of the leaving group.
(B)
In this structure, there is a chlorine group which can act as a leaving group but there is no hydrogen atom with the adjacent carbon bearing the leaving group. So, this compound cannot give benzyne intermediate.
(C)
![](https://www.vedantu.com/question-sets/f7f6730c-b127-4f8e-920b-427fec0d39253767191238226092679.png)
Here, we can see that there is the presence of adjacent hydrogen alongside the leaving group, chlorine. So, benzyne can be formed.
(D)
![](https://www.vedantu.com/question-sets/cf43fc40-44da-46b9-b14d-f9f38a0c37602478594566205576677.png)
Here, ${N_2}^ + $ group can act as a good leaving group and there is a hydrogen atom at adjacent carbon bearing the leaving group. So, benzyne formation is also possible here.
Therefore, the correct answer is (B).
Note: Remember that in option (A), there are a total of two groups –F and methoxy group. Here, -F is a strong base and methoxy group is a weaker base. So, as weaker bases are good leaving groups, it will leave and form benzyne in suitable conditions.
Complete step by step solution:
-Benzyne is a six-member hydrocarbon ring involving two double bonds and a C-C triple bond.
-In the mechanism of formation of benzyne, it is necessary for the structure to have a good leaving group. Alongside a good leaving group, it is also necessary to have a hydrogen atom at adjacent carbon which can leave to form benzyne. In short, we can show the formation of benzyne as
![](https://www.vedantu.com/question-sets/db701f27-8010-41b9-a9a5-e2f09242b8336217425430859333600.png)
Here LG is leaving the group.
Let’s see the compounds given in all the options in order to find which one will not give benzyne.
(A)
![](https://www.vedantu.com/question-sets/37ed805b-fd9b-4325-86b4-2947af9f85448781385072050793624.png)
So, in this case, benzyne intermediate can be formed as $ - OC{H_3}$ is a good leaving group and there is a hydrogen atom at the adjacent carbon of the leaving group.
(B)
In this structure, there is a chlorine group which can act as a leaving group but there is no hydrogen atom with the adjacent carbon bearing the leaving group. So, this compound cannot give benzyne intermediate.
(C)
![](https://www.vedantu.com/question-sets/f7f6730c-b127-4f8e-920b-427fec0d39253767191238226092679.png)
Here, we can see that there is the presence of adjacent hydrogen alongside the leaving group, chlorine. So, benzyne can be formed.
(D)
![](https://www.vedantu.com/question-sets/cf43fc40-44da-46b9-b14d-f9f38a0c37602478594566205576677.png)
Here, ${N_2}^ + $ group can act as a good leaving group and there is a hydrogen atom at adjacent carbon bearing the leaving group. So, benzyne formation is also possible here.
Therefore, the correct answer is (B).
Note: Remember that in option (A), there are a total of two groups –F and methoxy group. Here, -F is a strong base and methoxy group is a weaker base. So, as weaker bases are good leaving groups, it will leave and form benzyne in suitable conditions.
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