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Lanthanum Chemical Element Overview and Properties

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What is Lanthanum Atomic Number Electronic Configuration and Uses

Electronic Configuration of Lanthanum

Lanthanum, denoted by La, is a chemical element and a rare earth metal present in the Group 3 of the modern periodic table. It is known to be the prototype of the lanthanide series of the elements of the periodic table.


Lanthanum is a malleable and ductile metal, which is silvery-white in colour. It is softer enough that it can be even easily cut through a knife. Lanthanum is known to be the second most reactive rare-earth metals, the first being europium. The lanthanum compound tends to oxidize in the presence of air when kept at a room temperature and forms La₂O₃. It tends to react slowly with water and dissolves faster in the dilute acids, with an exception being the hydrofluoric acid, HF. this is due to the formation of the protective layer of fluoride, LaF₃ on the metal surface.

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What is Lanthanum

Lanthanum is a type of a chemical element denoted by the symbol La. The atomic number of lanthanum is 57. It is ductile and soft silvery-white metal which slowly tarnishes when it is exposed to the air. Lanthanum acts as the eponym of the lanthanide series, which is a group of 15 elements similar to one another starting from lanthanum to lutetium in the modern periodic table. Lanthanum lies first in the group and is hence the prototype. 


Lanthanum is regarded traditionally amongst the rare earth metals. It possesses an oxidation state of +3. The element does not show any biological role when it comes to humans, but it is important to a few bacterial species. It does not prove toxic to humans but possesses antimicrobial activity.


Lanthanum Chemical Formula/Symbol

La

Lanthanum Atomic Number

57

Lanthanum Atomic Mass

198.905 g.mol⁻¹ 

Discovered by

Carl Gustav Mosander in 1839


Chemical Properties of Lanthanum

Group

Lanthanides

Melting point

920°C or 1688°F or 1193 K

Period

6

Boiling point

3464°C or 6267°F or 3737 K

Block

d

Lanthanum Density(g/cm³)

6.15

Atomic number

57

Relative atomic mass

138.905

State at 20°C

Solid

Key isotopes

139La

Lanthanum Electronic configuration

[Xe]5d¹6s²

CAS number

7439-91-0

ChemSpider ID

22369

ChemSpider is a type of a free chemical structure database.


Properties of Lanthanum

  1. Lanthanum is found abundantly in the environment.

  2. It is silvery-white in colour

  3. Lanthanum is active, ductile and soft.

  4. Lanthanum tends to oxidize when reacted with water and forms its respective hydroxide.

  5. The lanthanum salts are not soluble in water.


Uses of Lanthanum

  1. Chemical form of lanthanum has its usage in the modern energy-saving lamps, televisions, fluorescent lamps and tubes, etc.

  2. Lanthanum is also used in optics in the form of radiation-absorbing glasses and lenses.

  3. It also increases the malleability and the resistivity of the steel. 

  4. Lanthanum is used to polish glass and to produce catalysts.

  5. It is also used in the petroleum refineries for catalysis.


Health-Related Facts of Lanthanum

  1. The primary problem associated with the lanthanum element is its disposal by the industries. The industrial wastes get dumped directly into the water bodies, mainly from the petroleum industries.

  2. It tends to cause severe damage to both plants and animals and nervous system disorders amongst us humans. 

FAQs on Lanthanum Chemical Element Overview and Properties

1. What is lanthanum?

Lanthanum is a chemical element with atomic number 57 and symbol La, belonging to the lanthanide series of the periodic table.

  • It is a soft, silvery-white metal.
  • It is classified as a rare earth element.
  • It commonly forms a +3 oxidation state in compounds.
  • It is placed in period 6 and group 3 of the periodic table.
Lanthanum is the first element of the lanthanide series and is widely used in alloys, catalysts, and optical materials.

2. What is the electron configuration of lanthanum?

The electron configuration of lanthanum (La) is [Xe] 5d1 6s2.

  • Atomic number = 57, so it has 57 electrons.
  • The configuration is based on the noble gas core [Xe] (54 electrons).
  • After xenon, electrons fill the 5d and 6s orbitals.
Lanthanum does not have electrons in the 4f orbital in its ground state, which distinguishes it from most other lanthanides.

3. What is the oxidation state of lanthanum?

Lanthanum most commonly exhibits an oxidation state of +3 in its compounds.

  • It loses three electrons to form the ion La3+.
  • These electrons are typically removed from the 6s and 5d orbitals.
  • The +3 state is highly stable due to its resulting noble gas configuration.
Almost all lanthanum compounds, such as LaCl3 and La2O3, contain lanthanum in the +3 oxidation state.

4. Is lanthanum a transition metal or a lanthanide?

Lanthanum is classified as a lanthanide, although it is sometimes grouped with transition metals due to its position in group 3.

  • It is the first element of the lanthanide series.
  • Lanthanides are also called inner transition metals.
  • Unlike most lanthanides, lanthanum has no 4f electrons in its ground state.
In modern periodic table classification, lanthanum is considered the starting element of the lanthanide series.

5. What is the atomic mass of lanthanum?

The atomic mass of lanthanum is approximately 138.91 u.

  • Its most abundant natural isotope is La-139.
  • Lanthanum has one stable isotope and several radioactive isotopes.
  • The atomic mass reflects the weighted average of its naturally occurring isotopes.
This value is used in molar mass calculations for lanthanum-containing compounds.

6. How does lanthanum react with oxygen?

Lanthanum reacts readily with oxygen to form lanthanum(III) oxide, La2O3.

  • The balanced reaction is: 4La(s) + 3O2(g) → 2La2O3(s).
  • This reaction occurs when lanthanum is exposed to air.
  • The oxide layer forms on the metal surface.
Lanthanum is quite reactive compared to many transition metals and tarnishes quickly in air.

7. What are the common compounds of lanthanum?

Common lanthanum compounds include LaCl3, La2O3, and La(OH)3.

  • Lanthanum chloride (LaCl3) is used in catalysts and research.
  • Lanthanum oxide (La2O3) is used in optical glasses.
  • Lanthanum hydroxide (La(OH)3) forms when La3+ reacts with OH- ions.
In nearly all its compounds, lanthanum exists in the +3 oxidation state.

8. What are the uses of lanthanum in chemistry and industry?

Lanthanum is used in catalysts, optical glass, batteries, and hydrogen storage materials.

  • Lanthanum oxide improves refractive index in special glasses.
  • Lanthanum is used in nickel–metal hydride (NiMH) batteries.
  • Lanthanum compounds act as catalysts in petroleum refining.
  • Lanthanum alloys are used in lighter flints.
Its chemical reactivity and stable +3 state make it valuable in industrial and materials chemistry.

9. How is lanthanum extracted from its ores?

Lanthanum is extracted from rare earth minerals such as monazite and bastnäsite through chemical separation processes.

  • The ore is first treated with acid or alkali to dissolve rare earth elements.
  • Lanthanum is separated using solvent extraction or ion-exchange methods.
  • The metal is obtained by reduction of anhydrous LaCl3 with calcium: 2LaCl3(l) + 3Ca(s) → 2La(s) + 3CaCl2(l).
This multi-step process is necessary because rare earth elements have very similar chemical properties.

10. What is the difference between lanthanum and other lanthanides?

Lanthanum differs from most other lanthanides because it has no electrons in the 4f subshell in its ground state.

  • Electron configuration: [Xe] 5d1 6s2.
  • Other lanthanides typically have partially filled 4f orbitals.
  • Lanthanum commonly forms only the +3 oxidation state, similar to most lanthanides.
Although chemically similar to other rare earth elements, its electronic structure makes it unique within the lanthanide series.