Answer
Verified
37.2k+ views
Hint: If a compound forms a white precipitate with $AgN{{O}_{3}}$ then the product formed is silver chloride having formula $AgCl$. If a compound forms a white precipitate with $BaC{{l}_{2}}$ then the product formed is barium sulfate having formula $BaS{{O}_{4}}$.
Complete step by step solution:
The given coordination complex has molecular composition as $M.5N{{H}_{3}}.Cl.S{{O}_{4}}$. In the coordination compound, we know that not all the ions or elements take place in the reaction, only the elements or ions that are outside the coordination bracket.
So the question says that $M.5N{{H}_{3}}.Cl.S{{O}_{4}}$ has two isomers i.e, A and B.
So, the A isomer combined with $AgN{{O}_{3}}$ gives white precipitate, and white is formed by the formation of silver chloride, having formula $AgCl$. This means that in the isomer A chloride ion was outside the coordination bracket and its exchanges with nitrate ion.
So, the B isomer combines with $BaC{{l}_{2}}$ gives white precipitate, and white is formed by the formation of barium sulfate having formula $BaS{{O}_{4}}$. This means that in the isomer B, sulfate ion was outside the coordination bracket and its exchanges with chloride ion.
So, the isomer A can be $[M{{(N{{H}_{3}})}_{5}}S{{O}_{4}}]Cl$ and the isomer B can be $[M{{(N{{H}_{3}})}_{5}}Cl]S{{O}_{4}}$. So, in these two isomers the ions are changing so they are ionization isomers.
Therefore, the correct answer is an option (b)- Ionisation isomerism.
Note: Linkage isomers are those in which the same ligand can join from two different atoms. Coordinate isomers are those in which the positive and negative ligands of the complex interchange. Geometrical isomers are those in which the cis and trans-form can be written.
Complete step by step solution:
The given coordination complex has molecular composition as $M.5N{{H}_{3}}.Cl.S{{O}_{4}}$. In the coordination compound, we know that not all the ions or elements take place in the reaction, only the elements or ions that are outside the coordination bracket.
So the question says that $M.5N{{H}_{3}}.Cl.S{{O}_{4}}$ has two isomers i.e, A and B.
So, the A isomer combined with $AgN{{O}_{3}}$ gives white precipitate, and white is formed by the formation of silver chloride, having formula $AgCl$. This means that in the isomer A chloride ion was outside the coordination bracket and its exchanges with nitrate ion.
So, the B isomer combines with $BaC{{l}_{2}}$ gives white precipitate, and white is formed by the formation of barium sulfate having formula $BaS{{O}_{4}}$. This means that in the isomer B, sulfate ion was outside the coordination bracket and its exchanges with chloride ion.
So, the isomer A can be $[M{{(N{{H}_{3}})}_{5}}S{{O}_{4}}]Cl$ and the isomer B can be $[M{{(N{{H}_{3}})}_{5}}Cl]S{{O}_{4}}$. So, in these two isomers the ions are changing so they are ionization isomers.
Therefore, the correct answer is an option (b)- Ionisation isomerism.
Note: Linkage isomers are those in which the same ligand can join from two different atoms. Coordinate isomers are those in which the positive and negative ligands of the complex interchange. Geometrical isomers are those in which the cis and trans-form can be written.
Recently Updated Pages
To get a maximum current in an external resistance class 1 physics JEE_Main
Let f be a twice differentiable such that fleft x rightfleft class 11 maths JEE_Main
Find the points of intersection of the tangents at class 11 maths JEE_Main
For the two circles x2+y216 and x2+y22y0 there isare class 11 maths JEE_Main
The path difference between two waves for constructive class 11 physics JEE_MAIN
What is the difference between solvation and hydra class 11 chemistry JEE_Main
Other Pages
Which of the following Compounds does not exhibit tautomerism class 11 chemistry JEE_Main
An electric bulb has a power of 500W Express it in class 11 physics JEE_Main
Which of the following is a nonreducing sugar A Glucose class 12 chemistry JEE_Main
The nitride ion in lithium nitride is composed of A class 11 chemistry JEE_Main
Excluding stoppages the speed of a bus is 54 kmph and class 11 maths JEE_Main
The mole fraction of the solute in a 1 molal aqueous class 11 chemistry JEE_Main