
The cyclopentadienyl cation is antiaromatic while the cyclopentadienyl anion is aromatic. If true enter 1, else enter 0.
Answer
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Hint: (1) A compound is said to be aromatic if it is cyclic and has planar ring, and also it must have cyclic delocalized pi-electron clouds lying above and below the plane of the ring.
(2) It must also follow Huckel’s electron rule where n is any integer.
(3) For antiaromaticity, the rule is that the molecule must have electrons where n is any integer.
Complete step-by-step answer: Both the cyclopentadienyl cation and cyclopentadienyl anion are formed from cyclopentadiene by the loss of a hydride ion and the abstraction of a proton respectively. Cyclopentadiene is not an aromatic compound because of the presence of a hybridized ring carbon on its ring due to which it does not contain an uninterrupted cyclic pi-electron cloud. When a hydride anion is removed from the hybridized ring carbon of cyclopentadiene, the cyclopentadienyl cation will be formed and the hybridization of the hybridized ring carbon will be changed from to . As a result of this conversion of hybridization, the cyclopentadienyl cation formed will be planar and will contain a cyclic pi-electron cloud above and below the ring. However, it fails to meet the Huckel’s rule of aromaticity as it does not have electrons and so it is not aromatic. But, it does have electrons (n is equal to 1 as there are 4 pi electrons). Hence, it is antiaromatic.
When a proton is abstracted from the hybridized ring carbon of cyclopentadiene, the cyclopentadienyl anion is formed and the hybridization of the hybridized ring carbon will be changed from to . As a result of this conversion of hybridization, the cyclopentadienyl anion formed will be planar and will contain a cyclic pi-electron cloud above and below the ring. Moreover, it also satisfies the Huckel’s rule for aromaticity as it has electrons (n is equal to 1 as there are 6 pi electrons) and so it is aromatic. Thus, the cyclopentadienyl anion is an aromatic compound.

Thus, the given statement is true and so 1.
Note: In the rule, n is not a property of the molecule. This rule is applied just to generate a series: n is equal to 2, 6, 10, 14 etc. and if our pi electron value matches any number in this series, then it possesses aromaticity.
(2) It must also follow Huckel’s
(3) For antiaromaticity, the rule is that the molecule must have
Complete step-by-step answer: Both the cyclopentadienyl cation and cyclopentadienyl anion are formed from cyclopentadiene by the loss of a hydride ion and the abstraction of a proton respectively. Cyclopentadiene is not an aromatic compound because of the presence of a
When a proton is abstracted from the

Thus, the given statement is true and so 1.
Note: In the
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