When the temperature gets increased, then the volume of the material also gets increased. In general, this is called thermal expansion. We can describe thermal expansion as the fractional change in volume or length per unit change in the temperature. In the case of a solid expansion, normally, the linear expansion coefficient is employed.
In solid thermal expansion, it is expressed in terms of change in height, thickness, and length. However, for both liquid and gas, the volume expansion coefficient is more useful. In general, if the material is a fluid, we can explain it in terms of volume change.
[Image will be uploaded soon]
Among the molecules and atoms, the bonding forces differ from material to material. The characteristics of compounds and elements are known as expansion coefficients. If a crystalline solid has a similar structural configuration throughout (isometric), then the expansion will be uniform in all dimensions of the crystal.
However, if the crystal is not isometric, then the expansion coefficient also varies for different crystallographic directions. As the temperature will change, then resultantly, the crystal will also change the shape. Softer materials have a higher Coefficient of Expansion (CTE), whereas the harder materials like tungsten have a lower CTE.
Let us look at the types of expansion.
The linear expansion is described as the increase in the length of the solid. For example, if we consider a rod, where the rod's length is l, and suppose that we increase the temperature of a rod by a small amount. Then, the Linear Expansion is given by,
ΔT is the change in temperature,
ΔL is the change in length
𝛼L is the linear coefficient of thermal expansion
L is the origin length
The Coefficient of the linear expansion of a given solid is represented as ‘a.’ Then, for ‘a,’ the unit is per degree Celsius in the SI and CGS system it is per kelvin i.e. K-1.
The volume expansion is described as the increase in the volume of the solid on heating. With a change in temperature of ∆t, the change in volume of a solid can be given by,
∆v = Vy ∆t
Where, ‘y’ is the coefficient of volume expansion.
Area or Superficial Expansion
The Area or Superficial expansion is described as an increase in surface area of the solid on heating. If we consider the area at 0℃ of a solid is A0, then its area at t0c can be given by,
A0 (l + βt)
The Unit of β is given by,
0C-1 or K-1
Where β is called the coefficient of superficial expansion.
6𝛼 = 3β = 2γ
This equation represents the relationship between α as the linear expansion, and β as the superficial expansion, and as the volume expansion. These three coefficients of expansion for a given solid are not given as constant because these values depend totally on the temperature.
Some examples of thermal expansion in our day-to-day life are riveting, on wooden wheels fixing the metal tires, thermometers, and more.
Unlike liquids or gases, solid materials tend to maintain their shape when participating in thermal expansion.
In general, thermal expansion decreases with increasing bond energy, affecting the melting point of solids. So, the high melting point materials are more likely to contain a lower thermal expansion. Generally, liquids expand slightly more to that of solids. The thermal expansion of glasses is higher when compared to crystals. At the given glass transition temperature, the rearrangements in an amorphous material lead to the characteristic discontinuities of the coefficient of specific heat and thermal expansion. These discontinuities allow the glass transition temperature detection, where a supercooled liquid transforms into a glass.
The absorption or desorption of water or other solvents can change many of the common materials; many organic materials change much more, and because of this effect than thermal expansion. Common plastics can be exposed to water, in the long term, expand by more percent.
Let us look at the Thermal expansion concept used in our daily life.
Thermal expansion in thermometers is used in temperature measurements.
Removal of Tight Lids
To open a bottle cap that is tight enough, immerse it in hot water for a minute or so. Then the metal cap expands and becomes loose, which would become easy to turn it to open.
The red hot rivets are forced through holes in the plates to join the steel plates together tightly. Then, the end of hot rivets is hammered. Whereas, on cooling, the rivets contract and bring the plates gripped tightly.
1. Explain the consequences of Thermal Expansion?
Ans: If we observe the gaps left in railway tracks, the expansion of solids can damage the bridges, roads, and railway tracks, as they are constantly subjected to the temperature changes.
So a provision is made during the contraction for both expansion and contraction with temperature. For example, railway tracks are buckled on a hot summer day because of expansion if gaps are not left between the sections.
[Image will be uploaded soon]
Bridges made of steel girders also expand during the day times because of high temperatures and contract during the night. They will also bend if their ends are fixed to allow the thermal girder to rest on rollers in the gap left for the expansion.
[Image will be uploaded soon]
The overhead transmission lines are also given a specific amount of sag to contract in winter without any snapping.
2. Give some examples on Thermal Expansion?
Ans: There are various examples that we observe in our daily life. However, since we do not know it happens because of Thermal Expansion, we do not notice them much keener.
A few of the examples of thermal expansion in our daily life are listed below:
Sags present in electrical power lines
The road cracks when the road expands on heating
Metal-framed windows need rubber spacers to avoid thermal expansion
The metal bar length getting longer on heating
Expansion joints (such as joint of two railway tracks)
Tire bursts on hot days when filled with full air due to thermal expansion