Answer
Verified
95.1k+ views
Hint: To solve this, proceed step wise and identify A, B and then arrive at C. Remember that tin with hydrochloric acid will reduce nitrobenzene and will give you an amine. Upon reaction with sodium nitride the amine will give you a salt. The salt will react with sodium amide and again arrive at phenyl amine.
Complete step by step solution:
To solve this, let’s see the reaction of nitrobenzene with the given reagents and then arrive at the final result.
In the first step, nitrobenzene reacts with tin and hydrochloric acid. It is a redox reaction and here the nitrobenzene is reduced to phenylamine. The reaction proceeds via formation of a phenyl ammonium cation by reduction of nitrobenzene. We can write the reaction as-
So, phenylamine is ‘A’. To this, sodium nitrite is added which will cause the amine to undergo diazotization. The hydrochloric acid in the reaction will react with it thus leading to the formation of a diazonium salt of benzene called benzene diazonium chloride. We can write the reaction as-
The diazonium salt thus obtained is our ‘B’.
To this diazonium salt when we add sodium amide we will again get the phenyl amine. We can write the reaction as-
The phenyl amine is ‘C’. It is also known as aniline.
We can see from the above discussion that the ‘C’ in the reaction series is aniline.
Therefore, the correct answer is option [D] Aniline.
Note: Primary amines give us a diazonium salt which forms alcohols in addition to water but secondary amines have one hydrogen atom attached to them therefore, they cannot complete the diazotization reaction and give us a yellow oily nitrosamine product. Three degree amines have no hydrogen atoms attached to them thus they undergo simple acid- base reactions and give us soluble salts.
Complete step by step solution:
To solve this, let’s see the reaction of nitrobenzene with the given reagents and then arrive at the final result.
In the first step, nitrobenzene reacts with tin and hydrochloric acid. It is a redox reaction and here the nitrobenzene is reduced to phenylamine. The reaction proceeds via formation of a phenyl ammonium cation by reduction of nitrobenzene. We can write the reaction as-
So, phenylamine is ‘A’. To this, sodium nitrite is added which will cause the amine to undergo diazotization. The hydrochloric acid in the reaction will react with it thus leading to the formation of a diazonium salt of benzene called benzene diazonium chloride. We can write the reaction as-
The diazonium salt thus obtained is our ‘B’.
To this diazonium salt when we add sodium amide we will again get the phenyl amine. We can write the reaction as-
The phenyl amine is ‘C’. It is also known as aniline.
We can see from the above discussion that the ‘C’ in the reaction series is aniline.
Therefore, the correct answer is option [D] Aniline.
Note: Primary amines give us a diazonium salt which forms alcohols in addition to water but secondary amines have one hydrogen atom attached to them therefore, they cannot complete the diazotization reaction and give us a yellow oily nitrosamine product. Three degree amines have no hydrogen atoms attached to them thus they undergo simple acid- base reactions and give us soluble salts.
Recently Updated Pages
Write a composition in approximately 450 500 words class 10 english JEE_Main
Arrange the sentences P Q R between S1 and S5 such class 10 english JEE_Main
Write an article on the need and importance of sports class 10 english JEE_Main
Name the scale on which the destructive energy of an class 11 physics JEE_Main
Choose the exact meaning of the given idiomphrase The class 9 english JEE_Main
Choose the one which best expresses the meaning of class 9 english JEE_Main