

How Did Millikan Measure the Charge of an Electron?
Millikan’s Oil Drop Experiment stands as a major breakthrough in modern physics, directly measuring the elementary charge of the electron. Conducted by Robert Millikan in 1909, this experiment not only revealed the quantization of electric charge, but also shaped our understanding of atomic structure. In this article, we'll clearly explain Millikan’s oil drop experiment, including its aim, setup, working principle, and key results, to help you master this crucial topic in physics and chemistry.
Aim of Millikan's Oil Drop Experiment
The principal goal of Millikan’s oil drop experiment was to determine the precise value of the charge carried by a single electron. This groundbreaking work settled debates about whether electric charge was continuous or existed in discrete units.
Apparatus and Construction
The apparatus used in Millikan's experiment consists of carefully designed components for generating, observing, and controlling the motion of tiny oil droplets:
- Two parallel metal plates to create a uniform electric field (see the typical Millikan’s oil drop experiment diagram in textbooks).
- A fine spray mechanism to introduce small oil droplets between the plates.
- A DC power supply to control the electric field strength.
- A microscope for visualizing the oil drops and measuring their movement.
- An X-ray source to charge the oil drops (by ionizing surrounding air molecules).
This apparatus allowed Millikan to carefully manipulate and analyze the motion of charged oil droplets under gravity and electric forces.
Theory and Working Principle
Millikan’s oil drop experiment explained the quantization of charge by studying how oil droplets behave in a controlled environment. The experiment involves balancing the gravitational force against the electric force acting on tiny, charged droplets.
Step-by-Step Process
- Oil drops are sprayed into the space between the plates, initially falling under gravity.
- As they fall, air resistance quickly brings each droplet to a steady speed, called terminal velocity, in the absence of an electric field.
- Their terminal velocity ($v_1$) is measured using:
\( v_1 = \frac{l_1}{t_1} \)
where \( l_1 \) is the distance travelled, and \( t_1 \) is time taken. - An electric field is introduced by applying voltage across the plates. This electric force acts upward, opposing gravity.
- By adjusting the voltage, some charged oil drops can be made to suspend motionless (the net force is zero) or rise with a new terminal velocity ($v_2$).
- Careful timing allows measurement of $v_2$:
\( v_2 = \frac{l_2}{t_2} \)
Main Forces Acting on Oil Drops
- Gravity (down): \( F_g = mg \)
- Buoyancy (up): due to displaced air
- Viscous Drag: described by Stokes' Law ($ F_v = 6 \pi \eta r v $) where $\eta$ is viscosity, $r$ is drop radius
- Electric Force (up): \( F_e = qE \), $E = V/d$ (V: voltage, d: plate separation)
The balancing condition (stationary drop) is:
$$ qE = mg $$
Thus, the Millikan’s oil drop experiment formula for charge $q$ is:
$$ q = \frac{mgd}{V} $$
By repeating the experiment with different drops, Millikan found that every measured charge was an integer multiple of a smallest value, confirming that charge is quantized.
Results and Significance
- The value of the elementary charge established: \( e = 1.6 \times 10^{-19} \) C.
- Demonstrated, unequivocally, that electric charge exists in discrete units.
- Laid the foundation for advancements in atomic and modern physics.
- Supported the atomic theory of matter and revolutionized our understanding of subatomic particles. For reference on the importance of constants like the electron charge, see Planck's constant.
Related Concepts to Explore
In conclusion, Millikan’s oil drop experiment is used to find the exact charge of an electron and to prove the discrete nature of electric charge. The precise method, carefully explained here, remains a classic in physics education—often discussed in Millikan’s oil drop experiment notes for class 11 and class 12. Understanding the procedure, forces, and formula provides a foundation for further studies involving electrostatics and atomic theory. The key takeaway: the charge of the electron ($e$) is a universal constant, critical for both theoretical and practical science.
FAQs on Understanding Millikan’s Oil Drop Experiment and Its Impact
1. What is Millikan's oil drop experiment?
Millikan's oil drop experiment was a revolutionary experiment designed to measure the elementary electric charge of an electron. In this experiment, small oil droplets were suspended in an electric field and observed under a microscope.
Key steps include:
- Spraying tiny oil droplets into a chamber
- Balancing the gravitational force with an external electric field
- Measuring the charge required to suspend the droplet
- Calculating the charge on each droplet, revealing the quantization of electric charge
2. What is the principle behind Millikan's oil drop experiment?
The principle behind Millikan's oil drop experiment is balancing the gravitational force on tiny oil drops with an electric field to determine the elementary charge (e) of the electron.
In summary:
- Oil droplets are charged by friction or ionization
- Their downward force due to gravity is balanced by the upward electric force
- The equilibrium enables precise charge calculation on each drop, proving that charge is quantized in integral multiples of the elementary charge
3. What are the observations made by Millikan in his oil drop experiment?
Millikan observed that the charges on oil drops were always whole number multiples of a basic unit, confirming the quantization of electric charge.
Key observations:
- Each oil droplet carried a charge that is an integer multiple of a smallest value
- The smallest value was determined to be 1.6 × 10⁻¹⁹ C, now known as the charge of a single electron
- This observation supported the idea that electric charge is not continuous
4. What are the applications of Millikan's oil drop experiment?
Millikan's oil drop experiment has several important scientific applications.
Main applications:
- Accurate determination of the elementary charge (e)
- Confirmation of the quantization of charge
- Supporting evidence for the atomic theory of matter
- Foundation for advancements in understanding atomic and subatomic particles
5. How did Millikan determine the charge of an electron using oil drops?
Millikan determined the electron's charge by observing oil drops balanced in an electric field, then calculating the charge using their motion and equilibrium.
Process summary:
- The oil drop was suspended using a precisely controlled electric field
- The mass of each drop was calculated from its terminal velocity
- By equating gravitational and electrical forces, the charge on each drop was calculated
- The smallest common charge observed was assigned as the value of e, the charge of an electron
6. What are the limitations of Millikan's oil drop experiment?
Millikan's oil drop experiment has some limitations related to experimental accuracy and assumptions.
Key limitations:
- Difficulties in measuring very small forces and drops
- Possible error due to air currents or Brownian motion
- Assumption that the oil drops are perfect spheres
- Influence of humidity and ionization processes
7. What are the important features of Millikan's oil drop experiment?
The important features of the oil drop experiment involve its precision and its demonstration of fundamental physical laws.
Key features:
- Use of a finely controlled electric field to balance oil drops
- Observation of charge quantization
- Direct measurement of the elementary charge
- Innovative use of microscopy and atomizer techniques
8. Why is Millikan's oil drop experiment important in physics?
Millikan's oil drop experiment is crucial because it provided direct evidence of the quantization of electric charge and measured the value of the electron's charge.
It played a vital role in:
- Establishing the elementary charge as fundamental
- Supporting atomic structure theories
- Advancing experimental physics techniques
- Receiving the Nobel Prize in Physics (1923) for its achievements
9. Who performed the oil drop experiment and what did it prove?
Robert A. Millikan performed the famous oil drop experiment in the early 20th century.
It proved that:
- Electric charge exists in discrete units called elementary charge (e)
- The charge of a single electron is 1.6 × 10⁻¹⁹ coulombs
- Electric charge is always a whole number multiple of this elementary value
10. What are the steps involved in Millikan's oil drop experiment?
The steps in Millikan's oil drop experiment enable measurement of tiny charges on oil droplets.
Main steps:
- Spraying fine oil droplets between two charged plates
- Charging the oil drops using X-rays or friction
- Observing droplets through a microscope
- Adjusting the electric field to balance gravitational force
- Calculating the charge on the drops using observed equilibrium and known constants





















