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Organic Chemistry Class 11 Notes: CBSE Chemistry Chapter 8

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Organic Chemistry Class 11 Chemistry Notes PDF Download

Chapter 8 of Class 11 Chemistry Organic Chemistry – Some Basic Principles and Techniques explains the fundamental concepts of organic compounds and their reactions. Organic chemistry focuses on carbon-containing compounds, which are central to both living organisms and synthetic materials. This chapter introduces the basic principles of organic chemistry, including the classification of organic compounds, nomenclature, and the different types of isomerism. Understanding these concepts is crucial for studying more complex reactions and applications in organic chemistry.

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Table of Content
1. Organic Chemistry Class 11 Chemistry Notes PDF Download
2. Access Class 11 Chemistry Chapter 8 Organic Chemistry Class 11 Notes
    2.11 Introduction
    2.22. Degrees of Carbon
    2.33. Breaking of Bonds:
    2.44. Inductive Effect:
    2.55. Resonance 
    2.66. Mesomeric Effect 
3. Class 11 Chemistry Chapter 8 Organic Chemistry - Some Basic Principles & Techniques Important Topics and Subtopics Covered
4. Class 11 Chemistry Chapters 8 Organic Chemistry - Some Basic Principles & Techniques Details, and Formulas and Concepts.
    4.11. Nomenclature:
    4.22. Reactivity of Organic Compounds:
    4.33. Isomerism:
5. Importance of Revision Notes for Class 11 Chemistry Chapter 8 Organic Chemistry - Some Basic Principles & Techniques 
6. Tips for Learning the Class 11 Chapter 8 Organic Chemistry - Some Basic Principles & Techniques 
7. Related Study Materials for Class 11 Chapter 8  Organic Chemistry - Some Basic Principles & Techniques 
8. Revision Notes Links For Class 11 Chemistry Revision Notes 
9. Related Study Material Links for Class 11 Chemistry
FAQs


Chapter 8 Organic Chemistry Class 11  Notes lets you quickly access and review the chapter content. For a comprehensive study experience, check out the Class 11 Chemistry Revision Notes FREE PDF here and refer to the CBSE Class 11 Chemistry  Syllabus for detailed coverage. Vedantu's notes offer a focused, student-friendly approach, setting them apart from other resources and providing you with the best tools for success.

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Access Class 11 Chemistry Chapter 8 Organic Chemistry Class 11 Notes

1 Introduction

Berzelius coined the term "Organic Chemistry" in 1807 to describe the study of compounds derived from natural sources. This was based on the vitalism theory, which stated that all living systems possessed a 'vital force' that non-living systems lacked. Organic compounds were thought to be fundamentally different from inorganic compounds because they were derived from living natural sources.


Philosophically, the vital force could be thought of as the mysterious force that God instilled in living systems.

Friedrich Wohler became Berzelius' student in 1823. Wohler made a discovery in 1828 that changed the definition of organic chemistry. Wohler carried out the following experiment.

Wohler was able to successfully synthesize an organic compound from an inorganic compound. Many others followed suit, synthesizing organic compounds from inorganic compounds. As a result, the theory of vitalism and the definition of organic chemistry became meaningless.

The presence of carbon, however, was shared by all of the compounds synthesized above. Catenation is a unique property of carbon. Carbon can form long chains and rings with other carbon atoms (self-catenation), as well as with atoms of many other elements in the periodic table (cross-catenation). As a result, carbon can form a wide range of compounds.

The vital force is probably explained by the fact that most of the life-giving and life-sustaining functions are performed by carbon compounds, for example, human tissues and skin are formed by proteins, respiration is possible because of hemoglobin, information in our genes is carried out in the form of DNA/RNA, and so on.

The detailed study of the fundamental concepts and factors that govern the progression and outcome of reactions is known as general organic chemistry.


Note:

Before transforming into products, bonds are typically formed and broken in a series of discrete steps. The mechanism of the reaction is a detailed sequential description of all the steps.

1.2 Sigma and Pi bond

Property

Sigma Bond

Pi Bond

Overlap

Axial/Head-on

Parallel/Lateral/Side-ways

Electron Cloud

Along the inter - nuclear axis

Perpendicular to the inter - nuclear axis

Bond - Strength

Stronger

Weaker



1.3 Structural Formulas

Organic chemists use a variety of formulas to represent organic compounds.


1.3.1 Complete Formulas

Lewis structures are used to represent all bond pairs of electrons as a dash (–) in complete formulas. A lone pair of electrons is represented by a pair of dots.


1.3.2 Condensed Formulas

Condensed formulas do not include all of the individual bonds. Each central atom is depicted, along with the atoms that are bonded to it.


1.3.3 Line-Angle Formulas

These are also referred to as skeletal structures or stick figures. Line-angle formulas are frequently used for cyclic compounds and, on rare occasions, non-cyclic compounds. Lines represent bonds, and carbon atoms are assumed to be present where two lines intersect or where a line begins or ends. In most cases, hydrogens are implied in these drawings.


1.3.4 Tetrahedral Representation

This is the three-dimensional (3-D) representation of molecules in general. Bonds projecting behind the plane (away from the observer) or out of the plane (towards the observer) are denoted by a dashed Wedge or a solid Wedge, respectively. Bonds in the plane of paper are represented by a normal line (—).


2. Degrees of Carbon

It is defined as the number of carbons attached to the carbon under study.


2.1 Hybridization

Hybridisation is a process in which two or more atomic orbitals of comparable energy in the valence-shell of an atom (central atom of a molecule or ion) mix together and give rise to the formation of new degenerate orbitals known as hybrid orbitals.


2.2 Applications of Hybridization


Hybridisation

% Character

$\mathrm{sp}^{3}$

25

$\mathrm{sp}^{2}$

33.3

$\mathrm{sp}$

50.0


2.2.1 Size of Hybrid Orbitals

The size of the hybrid orbital decreases as the percentage of s-character increases. As a result, the size of the hybrid orbital is: sp3 > sp2 > sp.


2.2.2 Electronegativity of Hybrid Orbitals 

As the percentage of s-character increases, so does the electronegativity of the hybrid orbital. As a result, the EN of the Hybrid Orbital is sp > sp2 > sp3


2.3 Dienes

Dienes are organic compounds that have two double bonds in them. Dienes are classified into three types: Isolated, Conjugated and Cumulated


2.3.1 Isolated Diene

In this case, double bonds are separated by atleast one sp3 carbon.

Molecule

$\sigma$

$\pi$

L.P

Hybridization

Shape

$\mathrm{CH}_{4}$

4

0

0

Tetrahedral

Tetrahedral

$\mathrm{NH}_{3}$

3

0

1

Tetrahedral

Trigonal Pyramidal

$\mathrm{H}_{2} \ddot{\mathrm{O}}$

2

0

2

Tetrahedral

V-shape orbent

$\mathrm{CH}_{2}=\mathrm{CH}_{2}$

3

1

0

Trigonal Planar

Trigonal Planar

$\mathrm{CH} \equiv \mathrm{CH}$

2

2

0

Linear

Linear


2.3.2 Conjugated Diene

A single bond separates two double bonds (or 4 sp2 carbons in a row).


2.3.3 Cumulated Diene 

Both sets of double bonds are located on the same carbon atom.

$\mathrm{CH}_{3}-\mathrm{CH}=\mathrm{C}=\mathrm{CH}-\mathrm{CH}_{3}$


2.3.4 Stability Diene

The relative stabilities of dienes are arranged in the following order: 

Isolated > Conjugated > Cumulated


2.4 Commonly occurring forms of carbon

Carbon's most common forms are 

(a) diamond, 

(b) graphite 

(c) carbides.

(d) Fullerenes

(e) Charcoal


Note:

Each C in a diamond is sp3. The solid is tetrahedral.

Each C in graphite is sp2. Solid layers with weak van der Waal forces between them. 


3. Breaking of Bonds:

The bond that is important for the study of reactions in organic chemistry is the covalent bond. As a result, we investigate how a covalent bond can be broken.

(a) Homolytic Fission 

(b) Fission by Heterolysis


3.1 Homolytic Fission or Homolytic Cleavage

Each atom separates with one electron in this type of bond breaking, resulting in the formation of highly reactive species known as radicals (or free radicals).

Two half-headed or fishhook arrows represent bond breaking. One electron's movement is depicted by a half-headed arrow. Radicals are odd electron species that are neutral.


3.1 Heterolytic Fission or Homolytic Cleavage

The shared pair of electrons are transferred to the more electronegative part in this type of covalent bond breaking. As a result of this fission, a cation and an anion are formed (ion-pair).


A full-headed arrow represents the bond breaking. A full-headed arrow depicts the movement of two electrons. In organic chemistry, electron movement is always represented by curved arrows, either half-headed or full-headed.


4. Inductive Effect:

When two unlike atoms form a covalent bond, the electron- pair that forms the sigma bond is never shared equally between the two atoms, but is shifted slightly towards the more electronegative species.

As illustrated, there are three types of groups/atoms that can be attached to carbon. Although C is more electronegative than H, the difference in electronegativity is small, and the bond is generally considered non-polar.


4.1 Nature of Inductive Effect:

The inductive effect is a permanent effect that is directly proportional to the dipole moment. It is a minor effect because electrons are only shifted via sigma bonds.


4.2 Effect of Branched Carbon Chain

An example of the operation of the inductive effect has been marked, which is self-explanatory.

4.3 Electron Donating and Electron withdrawing Groups 

The inductive effect can be caused by a single atom or by a group of atoms. The relative inductive effects are measured in relation to hydrogen. Electron-donating groups (EDG) or electron-releasing groups (ERG) are those that donate electrons to the carbon chain and are said to exert a +I effect. Electron-withdrawing groups (EWG) are those that withdraw electrons from the carbon chain and are said to exert the –I effect.


Important: 

1. I.E. of alkyl groups : 3° > 2° > 1° > CH3 – 

2. In general, the number of carbons in an alkyl group increases the +I effect.

3. To solve the problem, we assume that the electronegativity of sp hybridized carbon is greater than that of sp3 hybridized nitrogen.


4.4 Applications of Inductive Effect 

4.4.1 Effect on Acidic/Basic Strength 

EWG raises acidic strength while decreasing basic strength. ERG reduces acidic strength while increasing basic strength. 

Example: Compare the acidic strength:


Solution: An alkyl group will only donate if no other EWG is present. As a result, electron withdrawing groups such as –CH2Cl and –CH2F form.

Order of Acidic Strength  III > II > I 


4.4.2 Effect of Distance 

The inductive effect decreases as the ERG/EWG moves away.

4.4.3 Basicity of Amines 

The order in gaseous or liquid phase is: 3° > 2° > 1° > NH3 

To ascertain the basic strength of amines in aqueous solution. We must consider the inductive effect, the solvation effect, and the steric hinderance. The order of basic strength is thus experimental in the aqueous state because we cannot prioritize the stability provided by any single factor. For the aqueous phase, two results are critical: 

(a) $\left(\mathrm{CH}_{3}\right)_{2} \mathrm{NH}>\mathrm{CH}_{3} \mathrm{NH}_{2}>\left(\mathrm{CH}_{3}\right)_{3} \mathrm{~N}>\mathrm{NH} 3$


i.e. $2^{\circ}>1^{\circ}>3^{\circ}>\mathrm{NH}_{3}\left(\mathrm{R}=\mathrm{CH}_{3}\right)$


(b) $\left(\mathrm{C}_{2} \mathrm{H}_{5}\right)_{2} \mathrm{NH}>\left(\mathrm{C}_{2} \mathrm{H}_{5}\right)_{3} \mathrm{~N}>\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{NH}_{2}>\mathrm{NH}_{3}$

i.e. $2^{\circ}>3^{\circ}>1^{\circ}>\mathrm{NH}_{3}\left(\mathrm{R}=\mathrm{C}_{2} \mathrm{H}_{5}\right)$


5. Resonance 

Simple Lewis structures are commonly used to represent molecules, but some molecules cannot be represented by a single Lewis structure. As a result, the concept of resonance was discovered. The delocalization of electrons (generally pi electrons) is referred to as resonance. 


5.1 Conjugated Systems 

5.1.1 Pi alternate Pi

Resonance in benzene due to conjugated pi bond system


5.1.2 Pi alternate Positive Charge 

Example - 4

Resonance due to conjugated pi bond and positive charge system


5.1.3 Pi alternate Negative Charge 

Example - 5

Resonance due to conjugated pi bond and negative charge system


5.1.4 Pi alternate Odd Electron 

Example - 6

Resonance due to conjugated pi bond and odd electron system


5.1.5 Pi alternate Lone Pair 

Since lone pair and negative charge are treated similarly, this case is similar to 'pi alternate negative charge.

Example - 7

Resonance due to conjugated pi bond and lone pair system


5.1.6 Lone Pair and Positive Charge on Adjacent Atoms 

Example - 8

Resonance due to adjacent lone pair and positive charge system


5.2 Rules for Validity of Lewis Structures 

Rule 1: All Lewis structures must adhere to the Lewis octet rule.

Rule-2: Atoms in all resonating structures must be in the same position. Only the electrons are in motion.

Rule-3: All resonating structures must have the same number of paired and unpaired electrons, that is, the sum of bond pairs and lone pairs must be constant.

Rule-4: All of the atoms in a molecule that participate in resonance must be coplanar. This is required for effective p orbital overlap and electron delocalization, as in buta-1,3-diene.


5.3 Criteria for Major/Minor Contributors 

The following criteria, in the following order, can be used to compare resonance forms:

1. Use as many octets as you can (a neutral molecule is always more stable in which its octet is complete).

2. Attempt to form as many bonds as possible.

3. The presence of a negative charge on a more electronegative atom is stable.

4. The separation of charges

(a) Similar charges - Keep them as far away from each other as possible to reduce repulsion and instability.

(b) Opposite charges should be kept as close together as possible to maximize attraction and stability.


Example - 9 

Which of the following structures is more stable?

II is more stable as all the octets are complete


Solution: II is more stable as all the octets are complete. 


6. Mesomeric Effect 

The permanent polarization caused by a group conjugated with a pi bond or a set of alternate bonds is transmitted through the system's electrons, resulting in a different electron distribution in the unsaturated chain. Mesomeric Effect or Resonance Effect refers to the redistribution of electrons in unsaturated compounds conjugated with electron-releasing or electron-drawing groups (or atoms). The dipole moment indicates that this effect is permanent. 


6.1 Electron-Releasing and Electron-Withdrawing Groups 

The M or R effect refers to groups that release or withdraw electrons via resonance. 


6.1.1 Electron-Releasing Groups (+R or +M effect)

Electron-releasing groups


The atom connected with the conjugated system has a lone pair to donate, which is shared by all of the groups listed. As a result, a generic representation can be represented.

Lone pairs act as electron-releasing groups


6.1.2 Electron-Withdrawing Groups (–R or –M effect)

Electron-withdrawing groups


All of the groups listed have one thing in common: the atom connected with the conjugated system has a bond with another more electronegative atom that either withdraws electrons or directly has a positive charge on them. As a result, a generic representation can be represented - Y=Z (ENZ > ENY


6.1.3 Dual Behaviour 

As shown, some groups are both electron-releasing and electron-drawing. 


Example - 12 

As electron releasing group

-NO group as electron-releasing group


As electron withdrawing group

-NO group as electron-withdrawing group


Which behaviour dominates and which is used in a particular context will be discussed later in Electrophilic Aromatic Substitution later. 


Resonance Effect does NOT depend upon distance unlike inductive effect. 


6.2 Applications of Mesomeric Effect 

6.2.1 Effect on Acidic Strength of Carboxylic Acids and Phenols 

The resonating structure of carboxylic acid results in a charge-separated structure that is less stable than the charge-delocalized carboxylate ion. As a result, carboxylic acid easily loses proton (H) to form a carboxylate ion.

Similarly, in phenol, resonance causes charge separation, which increases the rate of ionization and results in the formation of phenoxide ion, which is stabilized by charge delocalization.


6.2.2 Effect on Reactivity of Carboxylic Acid Derivatives 

A typical nucleophilic reaction is represented as : The stronger is the bond between C and Z, the more difficult it is for a nucleophile to break a bond and therefore, lower reactivity. Reactivity order of carboxylic acid derivatives towards nucleophilic acyl substitution is : Acyl Chloride > Acid Anhydride > Ester > Amide


6.2.3 Effect of ERG/EWG on Acidic/Basic Strength 

EWG increases the acidic strength and decreases the basic strength. ERG decreases the acidic strength and increases the acidic strength.


Class 11 Chemistry Chapter 8 Organic Chemistry - Some Basic Principles & Techniques Important Topics and Subtopics Covered

Topic

Subtopics

Introduction to Organic Chemistry

Definition and importance of organic chemistry


Historical background and development

Classification of Organic Compounds

Alkanes, alkenes, alkynes


Aromatic hydrocarbons

Nomenclature of Organic Compounds

IUPAC naming rules for alkanes, alkenes, and alkynes


Nomenclature of functional groups

Isomerism

Structural isomerism


Geometric isomerism (cis-trans isomerism)


Optical isomerism

Functional Groups

Alcohols, aldehydes, ketones, carboxylic acids


Ethers, esters, amines

Basic Organic Reactions

Addition reactions


Substitution reactions


Elimination reactions



Class 11 Chemistry Chapters 8 Organic Chemistry - Some Basic Principles & Techniques Details, and Formulas and Concepts.

1. Nomenclature:

  • IUPAC (International Union of Pure and Applied Chemistry) rules are used for naming organic compounds systematically based on their structure and functional groups.

  • Prefixes, suffixes, and numbering systems are employed to denote substituents, parent chains, and functional groups.


2. Reactivity of Organic Compounds:

  • Organic compounds exhibit diverse reactivity patterns based on functional groups and structural features.

  • Common reactions include addition, elimination, substitution, oxidation, and reduction reactions.


3. Isomerism:

  • Isomers are compounds with the same molecular formula but different structural arrangements or spatial orientations.


Importance of Revision Notes for Class 11 Chemistry Chapter 8 Organic Chemistry - Some Basic Principles & Techniques 

  • Summarises Key Points: Condenses important concepts for quick review.

  • Saves Time: Provides a fast way to revise before exams.

  • Highlights Essentials: Focuses on crucial topics and definitions.

  • Improves Memory: Helps in better retention of information.   

  • Enhances Exam Prep: Targets weak areas for more effective study.

  • Clarifies Concepts: Simplifies complex ideas for easier understanding.

  • Includes Visuals: Uses diagrams and charts for better grasp.

  • Boosts Confidence: Prepares students thoroughly for exams.


Tips for Learning the Class 11 Chapter 8 Organic Chemistry - Some Basic Principles & Techniques 

  1. Focus on core processes with illustrations and examples of Common reactions including addition, elimination, substitution, oxidation, and reduction reactions.

  2. Draw and label diagrams of the reactivity of organic compounds for clarity. 

  3. Create summaries of each process like isomerism.

  4. Connect concepts to examples of Nomenclature.

  5. Solve past exam questions to test understanding.

  6. Explain concepts to others to reinforce learning.

  7. Revisit material frequently to retain information.


Conclusion

Chapter 8 Organic Chemistry - Some Basic Principles & Techniques provides a foundational understanding of organic compounds, their classification, and their reactions. By mastering the basics of nomenclature, isomerism, and functional groups, students lay the groundwork for more advanced studies in organic chemistry. This chapter is essential for developing a comprehensive understanding of how organic compounds behave and interact, which is crucial for both academic success and practical applications in chemistry.


Related Study Materials for Class 11 Chapter 8  Organic Chemistry - Some Basic Principles & Techniques 



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Related Study Material Links for Class 11 Chemistry

FAQs on Organic Chemistry Class 11 Notes: CBSE Chemistry Chapter 8

1. What are the main subjects covered in Organic Chemistry - Some Basic Principles & Techniques Class 11 notes?

The notes cover organic compounds’ classification, bonding, structure, nomenclature, and reaction mechanisms.

2. Where can I obtain the Organic Chemistry - Some Basic Principles & Techniques Class 11 Notes PDF?

The PDF can be obtained by visiting the Vedantu website and navigating to the Class 11 Chemistry resources section.

3. What does the Some Basic Principles and Techniques Class 11 Notes PDF download include?

This PDF download includes essential principles of organic chemistry, such as molecular structure, reaction types, and experimental techniques.

4. How are reaction mechanisms explained in the "Organic Chemistry - Some Basic Principles & TechniquesSome Basic Principles and Techniques notes"?

Organic Chemistry - Some Basic Principles & TechniquesSome Basic Principles and Techniques notes provide detailed explanations of reaction mechanisms, including step-by-step descriptions of how reactions occur and the role of intermediates.

5. What are the primary topics discussed in the Some Basic Principles and Techniques Class 11 PDF?

The primary topics include hybridisation, resonance, functional groups, and basic laboratory techniques in Some Basic Principles and Techniques Class 11 PDF.

6. What laboratory techniques are outlined in the Organic Chemistry - Some Basic Principles & Techniques Class 11 Notes?

The notes outline techniques such as distillation, filtration, crystallisation, and chromatography.

7. What methods of purification are covered in the Organic Chemistry - Some Basic Principles & Techniques Class 11 Notes PDF?

Methods of purification discussed include sublimation, recrystallisation, and column chromatography.

8. How does the "Some Basic Principles and Techniques Class 11 notes" explain functional groups?

The notes explain functional groups by detailing their chemical properties, reactions, and their role in determining the reactivity and classification of organic compounds.

9. What concepts related to organic reactions are included in the "Organic Chemistry - Some Basic Principles & Techniques Class 11 notes"?

Concepts include the classification of reactions (addition, elimination, substitution), mechanisms, and examples of each type of reaction.