An essential aspect of the use of metallic iron is the possibility of rusting or corrosion. Rust is a hydrated form of a compound known as iron(III)oxide. Rust is a general term that defines a series of iron oxides (red oxides). The process is formed by the reaction of iron with oxygen in the presence of air moisture or water. The rust formula is approximately Fe2O3• 32H2O, however, the exact amount of water in the formula is variable. However, there is no physical process to obtain back the iron from the rust.
The chemical formula of a compound is defined as the symbolic representation of the composition of a compound. The chemical formula for rust is Fe2O3 and is commonly known as ferric oxide or iron oxide.
The final product in a series of chemical reactions is simplified below as- The rusting of iron formula is simply 4Fe + 3O2 + 6H2O → 4Fe(OH)3.
The rusting process requires both the elements of oxygen and water. The process is usually accelerated by activities such as contact with less-active metals, acids, strains in the iron, and the presence of rust itself.
Rusting of iron involves an increase in iron oxidation, accompanied by a loss of electrons. Rust consists mainly of two different iron oxides. These vary in the iron atom's oxidation state- Iron(II) oxide or ferrous oxide with +2 oxidation state and Iron(III) oxide or ferric oxide with +3 oxidation state.
The rusting of iron formula is a series of chemical reactions which is as follows-
Fe(OH)2 ⇌ FeO + H2O
4Fe(OH)2 + O2 + xH2O → 2Fe2O3.(x+4)H2O
Fe(OH)3 ⇌ FeO(OH) + H2O
FeO(OH) ⇌ Fe2O3 + H2O
The series of rusting equations results in a reddish-brown deposit called rust, formed over a piece of iron when exposed to moist air for some time. The rusting of iron undergoes a chemical change that cannot be obtained back as pure iron by reversing the conditions.
Rust is a reddish-brown flaky coat present on the metal. Technically, rust is a Hydrated Iron (III) Oxide whose chemical formula is Fe2O3• 32H2O. The rusting of the iron formula is represented by 4Fe + 3O2 + 6H2O → 4Fe(OH)3. Rusting can be prevented by galvanization, painting, and application of grease.
Q1. What is Rust?
Ans: Rust is an orangish-reddish layer, primarily composed of ferric hydroxide and ferric oxide and created by oxidation. Rust is usually formed on the surface of iron when exposed to any air, moisture, or water. The chemical formula of rust is Fe2O3• 32H2O with a variable amount of water content.
Q2. How does Water cause Rust?
Ans: When the oxygen atom splits, water makes the element iron react with oxygen. This causes the iron to lose electrons while oxygen gains electrons during the early stages of rusting. The ferrous and ferric ions respond to ferrous hydroxide, ferric hydroxide, and hydrogen with water to form rust.
Q3. How can Rusting be Prevented?
Ans: Preventing the contact of water and air with iron objects can prevent the metal from rusting. Some prevention methods include painting to create a barrier, applying grease or oil as protection or lubrication, and electroplating with chromium. The most effective prevention tool is galvanization which prevents water and air from reacting with the metal substance.