A Detailed Analysis of Lewis Acids & Bases
Both acids and bases are important aspects when we study chemistry. Lewis acid/base motif is one of the most applicable theories, and it extends the denotation of acids and bases beyond H+ and OH- ions.
The acid-base theory of Brønsted has been used thoroughly in the history of acid and base. However, this theory is a bit restrictive and limited as it focuses mainly on the acids and bases that act as proton donors and acceptors. Some situations arise when this theory does not necessarily fit, especially when it comes to solids and gases. In any species, if there is a Lewis acid, there are high chances of accepting a pair of electrons. A Lewis base is a type of species that has the ability to donate a pair of electrons to the acceptor of the same category. The reaction of Lewis acid/base forms a bond that is known as a coordinate covalent bond.
Some of the Examples of Lewis Acids
There are a number of reactions that involves Lewis acids and bases. Some of the common examples are:
Iron (Fe2+ and Fe3+). Cations of d block elements that portray states of high oxidation
Hydrogen (H+) ions with onium ions (H2O+)
Cations of metals like Li+ and Mg2+
Arsenic, Antimony and Phosphorous
Remember, any deficiency in electron π system will be acting as an acceptor of the electron pairs. For example, enones.
Defining Lewis Base
A Lewis base is a donor of electron-pair. To make it simple, it is a substance through which a pair of electron is donated to form a covalent bond. This states that a Lewis base is a nucleophile. The reaction of Lewis acid-base can be represented by the transfer of pairing electrons to an acid medium from a base. Hence, looking at the reaction, we can say that these pair of electrons is nonbonding to acids. Nonbonding electrons are actually loose changes that take place. For instance, considering a hydrogen ion, it can accept a pair of the electron due to the lack of electrons.
Some of the Examples of Lewis Bases
Every electron-pair donors that are able to form compounds with the binding of transitional elements can be termed as Lewis bases. They are also known as ligands. Lewis bases modify the selectivity and activities of metal catalysts. Some of the common examples are:
Chemical Reactions Between Lewis Acids and Bases
When it comes to Lewis theory of acid base reactions, bases are known for donating pairs of electrons, and on the other hand, acids continue to accept those pairs of electrons. Therefore, this indicates that a Lewis acid can be any substance, like H+ ion, that accepts pairing electrons which nonbonding. To make it simpler, it can be said that Lewis acid is an acceptor of electron-pair. On the contrary, an ion of OH- can be the best of a Lewis base as it donates a pair of nonbonding electrons. Therefore, a Lewis base is an electron pair donor. One of the notable advantages of Lewis theory is, the way it complements the model of reducing oxidation reactions. The reactions of oxidation reactions include transferring of electrons from one atom to another. With this, a net change in the number of oxidation continues in one or more atoms.
Application to Lewis Acid and Bases
An alternate theory to describe acids and bases were proposed by G.N Lewis. It states a general explanation of acids and bases on the basis of bonding and structure. With the application and easy definition of acids and bases, lots of chemists can now predict a wider variation of acid base reactions. The theory of Lewis was based on electrons rather than proton transfers.
The common examples of Lewis acids and bases are:
Formation of ligands
Forming bonds with Lewis acids for the production of chelating agent
Modification of metallic catalyst
Lewis acids play a crucial role in the form of catalyst. For example, a lone pair of electrons is accepted by AlCl3 that belongs to the chloride ion. This gives to the formation of AlCl4- in the alkylation process of Friedel Crafts.
Till now, it must have been clear that acids and bases are two separate things. However, there are some substances which are both acid and base. One of the most common examples is water. It can play the role of either an acid or a base. This ability or quality of water makes this one amphoteric molecule. By donating its proton, water could act as the acid from the base. This helps to become the conjugate acid which is known as OH-. On the contrary, by accepting a proton from acid, it can also play the role of a base. This helps in becoming a conjugate base which is known as H3O+.
H2O+NH3→NH+4+OH−(3)(3)H2O+NH3→NH4++OH− (When water acts as an acid)
H2O+HCl→Cl−+H3O+(4)(4)H2O+HCl→Cl−+H3O+ (When water acts as a base)
The degree of molecular acts depends on the medium in which it has been placed. Taking the example of water, it does not act as an acid in any acidic medium or fails to acts as a base in a related medium. Therefore, the medium in which the molecules are placed plays a key role and has its effect on the molecular properties. Other molecules can also act as an acid or a base.
Al(OH)3+3H+→Al3++3H2O(5)(5)Al(OH)3+3H+→Al3++3H2O (When Al(OH)3 acts as a Lewis base)
Al(OH)3+OH−→Al(OH)−4(6)(6)Al(OH)3+OH−→Al(OH)4− (When Al(OH)3 acts as Lewis acid)
You should take note of the amphoteric properties of Al(OH)3 as it depends on the environment where the molecules have been placed.
Beyond Generic Acid-base Chemistry
Apart from specific substances, if we consider electron pairs for treating acid base reactions, the definition of Lewis can be applied to reactions that do not typically categorise under the explanation of acid base reactions. Taking the example of silver, a cation of silver behaves in the form of Lewis acid with respect to ammonia. Here, ammonia plays the role of Lewis base.
The result of the reaction shows the formation of diamminesilver(I). It is a complex ion that is described by Lewis acid base chemistry. However, it cannot be classified in terms of traditional definitions like Arrhenius and Bronsted-Lowry. In terms of organic chemistry, it is crucial to determine that Lewis bases are actually nucleophiles and Lewis acids are electrophiles. Almost all the reactions are considered as Lewis acid base processes in organic chemistry.
Q1. Present a Symbolic Example of Lewis Acids and Bases
Ans. Lewis acids and bases can be defined as hard and soft. Symbolic examples include:
Lewis Acid example: CO2, Mg2+, AlCl3, H+, K+, Fe3+, BF3, SO3, RMgX, Br2.
Lewis Base example: NH3, PR3, H2O, OH-, F-, ROH, SO42-, H-, CO, C6H6.
Q2. How to Determine the Differences Between Lewis Acid and Bronsted Acid?
Ans. Lewis are usually compounds that are deficient in electrons like BF3. It is an electron pair acceptors. On the contrary, bronsted acids are compounds which donate a proton.
Q3. Which of the Following are Lewis Acid Base Reactions?
CuCL2 + 4H2O > [Cu(H2o)4]2 + 2Cl-
KI + 4SO2 (s) > K+ [(SO4) 4 I-]
BF3 + NH3 > [H3N . BF3]
Ans. BF3 + NH3 > [H3N . BF3]
Q4. How it is Possible for Water to be Determined as Lewis Base?
Ans. Water could be Lewis acid as well as the base. Water (H2O) is amphoteric, and thus, it means it has the ability of "self-ionizing". H2O + H2O = H3O+ + OH−
This reaction indicates one of the molecules form water molecules is acting as Lewis acid (H3O+), and another acts as Lewis base (OH−). As per the definition of Lewis theory, the Lewis base is anything that donates one pair of the electron, while one Lewis acid does accept it. At the time of water ionizing, the OH− have the ability of donating electrons to one other acid apart from the H3O+ ion; therefore, this causes the reaction.
Q 5. How to Predict a Lewis acid or Base Reactions?
Ans. In most cases, A Lewis acid comes with one vacant orbital. Numerous species might act as Lewis acid. For example:
All cations (e.g., Fe²⁺, Fe³⁺, Cu²⁺),
from Cu²⁺ + 4NH₃ to Cu(NH₃)₄²⁺
Any ion, atom, or any molecule with one octet that is of electrons (example, BF₃, AlF₃).
from BH₃ + NH₃ to H₃B⁻-N⁺H₃
Any Lewis base would have a single pair of electrons. Many species can possibly act as Lewis bases. For example:
Anions (e.g. CN⁻, CH₃COO⁻, OH⁻)
from HO⁻ + H-CN to HO-H + CN⁻
Molecules having double/triple bonds (example: (CH₃)₂C=CH₂)
from (CH₃)₂C=CH₂ + H-Br to (CH₃)₃C⁺ + Br⁻
Q6. Define Lewis Base
Ans. In the definitions of Lewis theory, acids and bases are categorized on the basis of electrons. A Lewis acid can be defined as the acceptor of electron pair that acquires electron pair. A Lewis base is a substance that donates the pair of electron, and hence, it is termed as a donor.