

How Is Ammonium Sulfate Used in Fertilizers and Agriculture?
Ammonium sulfate is a widely recognized inorganic compound, mainly valued for its role as a nitrogen and sulfur fertilizer in agriculture. With its high solubility and consistent performance, ammonium sulfate is used in various farming and industrial applications. This article explores its formula, production process, properties, and diverse uses, with a special focus on why ammonium sulfate fertilizer remains essential to modern agriculture.
Ammonium Sulfate: Structure, Formula, and Properties
Understanding the core details of ammonium sulfate is important for both agricultural and chemical applications. Its molecular structure and key features help explain why it is so versatile.
Ammonium Sulfate Formula and Molar Mass
- The chemical name is ammonium sulfate; the formula is \( (NH_4)_2SO_4 \).
- It is made of two ammonium ions ($ NH_4^+ $) and one sulfate ion ($ SO_4^{2-} $).
- The molar mass of ammonium sulfate is approximately 132.14 g/mol.
Physical and Chemical Properties
- Appearance: Colorless to white crystals; may appear beige based on impurities.
- Solubility: Highly soluble in water (about 750 g/L at room temperature), making it easy to apply.
- pH in Solution: Typically 5 to 6.
- Nitrogen Content: 21% N by weight, as labeled by "ammonium sulfate 21-0-0."
- Sulfur Content: About 24%, beneficial for plant growth.
How Ammonium Sulfate is Manufactured
Today, ammonium sulfate is produced using efficient chemical reactions and byproduct streams from various industries.
- Main industrial process: React heated ammonia gas ($ NH_3 $) with sulfuric acid ($ H_2SO_4 $).
The reaction is:
$$ 2NH_3 (g) + H_2SO_4 (aq) \rightarrow (NH_4)_2SO_4 (s) $$
- Other sources use byproducts from steel, coal, or nylon manufacturing to meet demand.
- Crystal size and purity are managed through drying and screening for target applications, such as fertilizer or industrial uses.
Agricultural Uses of Ammonium Sulfate
Ammonium sulfate fertilizer is valued for delivering both nitrogen and sulfur, especially where these nutrients are low in soil. Its use is common in many settings, including lawns, crops, and specialty gardens.
Advantages for Lawns and Crops
- Supplies nitrogen (N) and sulfur (S), which are crucial for protein synthesis and healthy plant growth.
- High solubility allows quick uptake by plants and easy application, either directly to fields or in solution sprays.
- Lowers soil pH over time, which can help with alkaline soils.
- Ideal for rice and flooded fields, as the ammonium ion ($ NH_4^+ $) resists microbial denitrification better than nitrate fertilizers.
Because ammonium sulfate contains only 21% nitrogen, it is bulkier than other high-N fertilizers, but it is especially preferred where sulfur supplementation is needed. This makes it popular for commercial agriculture and home use, including products offered at outlets like ammonium sulfate Home Depot and Lowes.
Application Methods and Management
- Should be incorporated into the soil or applied before irrigation to minimize ammonia loss, especially on alkaline soils.
- In warm, moist soils, microbes convert ammonium sulfate to nitrate through nitrification, lowering the soil’s pH.
The key nitrification process:
$$ 2NH_4^+ + 3O_2 \rightarrow 2NO_3^- + 2H_2O + 4H^+ $$
- Acidifying effect comes from ammonium conversion, not from the sulfate itself.
- Frequently used as an additive to herbicide sprays, helping weed control in "hard" water (high calcium, magnesium, or sodium).
Other Applications of Ammonium Sulfate
Besides its primary role as a fertilizer, ammonium sulfate (CAS number available in ammonium sulfate SDS) serves important industrial purposes:
- Additive in bread as a dough conditioner.
- Component of fire extinguisher powders and fireproofing agents.
- Used in textile, pharmaceutical, and wood pulp industries.
Important Safety and Storage Information
Ammonium sulfate is considered stable and safe for normal storage and handling. Guidance can be found in the ammonium sulfate SDS for precautions. Most retailers who offer ammonium sulfate "nearby" ensure the crystals are dry and caking-resistant.
Conclusion
Ammonium sulfate is an essential compound in both agriculture and industry. Its unique combination of high water solubility, stable storage, and ability to supply vital nitrogen and sulfur makes ammonium sulfate fertilizer a trusted choice for improving crop health and productivity. Whether you are searching for "ammonium sulfate near me" or learning about its chemistry, understanding its formula $(NH_4)_2SO_4$, molar mass, and best practices for use empowers smarter application decisions. For more on how chemical compounds support agriculture and the environment, explore topics like the Earth’s atmosphere, properties of water, and energy in physical systems on Vedantu.
FAQs on Understanding Ammonium Sulfate: Key Facts for Students
1. What is ammonium sulfate and what is it used for?
Ammonium sulfate is an inorganic salt commonly used as a fertilizer in agriculture and as a laboratory reagent.
Key points:
- Its chemical formula is (NH4)2SO4.
- Provides essential nitrogen and sulfur nutrients to plants.
- Also used in water treatment and food processing.
- Aids in soil acidity regulation.
2. How is ammonium sulfate prepared in the laboratory?
Ammonium sulfate can be prepared in the laboratory by reacting ammonia (NH3) with sulfuric acid (H2SO4).
The procedure includes:
- Combine concentrated sulfuric acid with ammonia gas or aqueous ammonia solution.
- The reaction forms ammonium sulfate and is represented by:
2 NH3 + H2SO4 → (NH4)2SO4 - The solid product is filtered, washed, and dried for use.
3. What are the physical properties of ammonium sulfate?
Ammonium sulfate appears as a colorless, odorless crystalline solid with several notable physical properties.
Key physical properties include:
- Molecular weight: 132.14 g/mol
- Melting point: Decomposes above 235°C
- Solubility: Highly soluble in water
- Appearance: White granular or crystalline powder
4. What are the common uses of ammonium sulfate in agriculture?
Ammonium sulfate is mainly used as a nitrogen fertilizer for crops.
- Provides two essential plant nutrients: nitrogen (N) and sulfur (S).
- Useful for soils that need additional sulfur.
- Helps maintain proper soil pH by adding slight acidity.
- Promotes healthy growth in cereals, fruits, and vegetables.
5. Is ammonium sulfate acidic or basic?
Ammonium sulfate is acidic in nature when dissolved in water.
- It slightly lowers the pH of soil, making it suitable for alkaline soils.
- It helps in managing soil alkalinity and improves nutrient uptake.
6. What are the hazards and safety precautions for ammonium sulfate?
Ammonium sulfate is generally regarded as safe for handling but requires some precautions.
- Avoid inhaling dust as it can cause mild respiratory irritation.
- Wear gloves to prevent skin irritation during handling.
- Store in a dry, cool location away from incompatible substances.
- It is non-flammable but should not be mixed with oxidizing agents.
7. Write the balanced chemical equation for the preparation of ammonium sulfate from ammonia and sulfuric acid.
The balanced equation for ammonium sulfate preparation is:
2 NH3 (aq) + H2SO4 (aq) → (NH4)2SO4 (aq)
- This reaction involves the neutralization of ammonia with sulfuric acid.
- The product, ammonium sulfate, is collected as a soluble solid.
8. What are the main differences between ammonium sulfate and urea as fertilizers?
Ammonium sulfate and urea are both nitrogenous fertilizers but have different properties.
- Ammonium sulfate: Contains 21% nitrogen and 24% sulfur; acidic; suitable for sulfur-deficient soils.
- Urea: Contains 46% nitrogen; does not add sulfur; neutral to slightly alkaline in soil.
- Ammonium sulfate helps correct soil acidity, while urea is best for rapid nitrogen needs.
9. List some industrial applications of ammonium sulfate other than fertilizers.
Ammonium sulfate is also used in various industries outside agriculture.
- Food industry: As an acidity regulator in baking.
- Water treatment: For precipitation of impurities.
- Laboratory use: In protein purification (salting-out agent).
- Textile industry: For dyeing and printing fabrics.
10. State two advantages and two disadvantages of using ammonium sulfate as a fertilizer.
Ammonium sulfate offers both benefits and limitations as a fertilizer.
Advantages:
- Provides both nitrogen and sulfur to plants.
- Helps lower soil pH in alkaline soils.
- Can cause soil acidification with overuse.
- Lower nitrogen content compared to some other fertilizers (like urea).





















