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Which of the following resonating structures will contribute minimum to resonance hybrid?

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(A) I
(B) II
(D) All the structures contribute equally

Last updated date: 13th Jun 2024
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Hint: All the canonical structures equivalently share the overall energy of the molecule. They contribute equally to the resonance hybrid.

Complete step-by-step answer:
Let us talk about resonance first. Resonance can be defined as the permanent delocalisation of electrons within a molecule between conjugated pi-bonds. We define this dynamic phenomenon as a permanent effect because it is not limited to any structure or condition. A molecule which can resonate continuously does so, until it does not.
Not all molecules which have conjugated pi-bonds resonate. Only a certain group of compounds which are known as aromatic compounds do so. We can identify these compounds with a special rule known as Huckel’s rule. It states that molecules which contain $\left( 4n+2 \right)\pi $electrons, where n is any natural number, are regarded as aromatic compounds. If we put n is equal to 1 then we get the result as 6 pi-electrons. Benzene, which is a very common molecule in organic chemistry, has 6 pi-electrons and therefore is an aromatic compound.
Now, these structures which resonate go through intermediate states which are relatively unstable or short lived. These intermediate states are also known as canonical structures. The number of canonical structures is directly proportional to the stability of the overall compound. The molecule benzene in the above case has two such structures. But the actual structure of benzene is somewhere in between, in other words, the two canonical structures contribute equally to the actual structure of benzene. The overall structure of any resonating molecule is known as the resonance hybrid and is derived from its canonical structures. The resonance of benzene is as shown below-

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Therefore, in the above question, the answer is option (D) All the structures contribute equally. The resonance hybrid of the given molecule is as shown below-

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As you can see, both the bonds have partial double bond character.

Note: There is a difference between conjugation of double bonds and resonance. There are many compounds which show conjugation but do not resonate. Resonance is regarded as a permanent effect and has the highest stabilizing potential among all the other effects.