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The stability of carbocation $${1^o},{2^o},{3^o}$$ and benzyl carbocation is of order:
A) $${1^o} > {2^o} > {3^o} > benzyl$$
B) $$benzyl > {3^o} > {2^o} > {1^o}$$
C) $${3^o} > {2^o} > {1^o} > benzyl$$
D) $${3^o} > benzyl > {2^o} > {1^o}$$

Last updated date: 16th Jun 2024
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Hint: The benzyl carbocation is a resonance stabilized carbocation. It has four resonance structures which makes its stability good. It shares the charges of four different atoms making itself the most stable. The tertiary carbocation is also stable due to the presence of inductive effect whereas in primary carbocation we have only resonance effect.

Complete answer:
An electron donating group is defined as the group or atom which releases its electron density to its adjacent or neighbouring atoms from itself by the resonance effect or inductive effects. The carbocations are said to be stabilized because of the presence of electron donating groups in them. The stability of the carbocations increases from primary carbocation to tertiary carbocation as the methyl group increases. This is due to the hyconjugation which therefore stabilizes by donating the electrons to carbon hydrogen sigma bonds to the empty p orbital of the carbocation. But out of all these carbocation the benzyl carbocation is considered to be most stable because of the delocalization of charge over the ring due to resonance of $$\pi electrons$$.
For more clarification look at the structure of the following benzyl carbocation:
The benzyl carbocation:
seo images

The primary carbocation :
seo images

The secondary carbocation:
seo images

The tertiary carbocation:
seo images

So the correct option for this question will be option ‘B’.

Note: Inductive effect is defined as the phenomenon where a permanent dipole arises in the molecule because of unequal sharing of electrons. The resonance or the mesomeric effect determines the polarity which is induced in the molecule by reacting the lone pair of electron and a pi bond. Hyperconjugation is referred to as the stabilising interaction that results in the interaction of electrons in a sigma bond with empty or partially filled orbital so that an extended molecular orbital is formed which increases the stability of the system.