Answer
414.9k+ views
Hint: E2 elimination happens followed by ozonolysis.The strength of the base used in the reaction is more important for the elimination reactions.
Complete step by step solution:
Here the base used was potassium tert-butoxide which is a strong and bulky base. The proton from the carbon next to the halide ( \[\beta \] to halide) was abstracted and leads to the formation of olefin. The elimination is the concerted mechanism. The selectivity of picking protons from which \[\beta \] carbon is depends on the base. Less hindered bases are easily abstract the proton for the highly substituted carbon and yields the saytzeff's product as major product. Highly hindered bases are unable to pick the hydrogen from highly substituted carbon but easily from the primary carbon.
According to the Hofmann rule the less hindered proton could be easily picked up by the bulkier base and resulted in the less substituted alkene, kinetically controlled product. Whereas, the highly substituted alkene was formed as the major product while using a less hindered base.
The next step is the ozonolysis
This step results with the cleavage of alkene by adding the ozone along the double bond.
Hence, the correct option is (A) i.e Methanol + Propanal
Note: Hofmann reaction is the reaction of bromine with sodium hydroxide forms sodium hypobromite. Initially base abstracts the acidic \[N - H\] proton. That will form an anion. This anion will react with bromine to give N-bromo amide.
Complete step by step solution:
Here the base used was potassium tert-butoxide which is a strong and bulky base. The proton from the carbon next to the halide ( \[\beta \] to halide) was abstracted and leads to the formation of olefin. The elimination is the concerted mechanism. The selectivity of picking protons from which \[\beta \] carbon is depends on the base. Less hindered bases are easily abstract the proton for the highly substituted carbon and yields the saytzeff's product as major product. Highly hindered bases are unable to pick the hydrogen from highly substituted carbon but easily from the primary carbon.
![seo images](https://www.vedantu.com/question-sets/6813aa9f-c130-4412-8295-4d271b5ab9152504851321036489214.png)
According to the Hofmann rule the less hindered proton could be easily picked up by the bulkier base and resulted in the less substituted alkene, kinetically controlled product. Whereas, the highly substituted alkene was formed as the major product while using a less hindered base.
The next step is the ozonolysis
![seo images](https://www.vedantu.com/question-sets/26afb8a2-4b7e-4519-ba02-f03a3862ef171625799146340774533.png)
This step results with the cleavage of alkene by adding the ozone along the double bond.
Hence, the correct option is (A) i.e Methanol + Propanal
Note: Hofmann reaction is the reaction of bromine with sodium hydroxide forms sodium hypobromite. Initially base abstracts the acidic \[N - H\] proton. That will form an anion. This anion will react with bromine to give N-bromo amide.
Recently Updated Pages
How many sigma and pi bonds are present in HCequiv class 11 chemistry CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Why Are Noble Gases NonReactive class 11 chemistry CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Let X and Y be the sets of all positive divisors of class 11 maths CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Let x and y be 2 real numbers which satisfy the equations class 11 maths CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Let x 4log 2sqrt 9k 1 + 7 and y dfrac132log 2sqrt5 class 11 maths CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Let x22ax+b20 and x22bx+a20 be two equations Then the class 11 maths CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Trending doubts
Fill the blanks with the suitable prepositions 1 The class 9 english CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
At which age domestication of animals started A Neolithic class 11 social science CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Which are the Top 10 Largest Countries of the World?
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Give 10 examples for herbs , shrubs , climbers , creepers
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Difference between Prokaryotic cell and Eukaryotic class 11 biology CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Difference Between Plant Cell and Animal Cell
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Write a letter to the principal requesting him to grant class 10 english CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Change the following sentences into negative and interrogative class 10 english CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Fill in the blanks A 1 lakh ten thousand B 1 million class 9 maths CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)