# Give a test to differentiate ${ 1,1-dichloroethane }$ and ${ 1,2-dichloroethane }$:A) ${ 2,4-DNP }$ and then aq. KOHB) aq. KOH and then ${ 2,4-DNP }$C) ${ NaHSO }_{ 3 }$ D) Lucas reagent

Verified
146.1k+ views
Hint: The only difference between 1,1-dichloroethane and 1,2-dichloroethane is that the two chlorine atoms are present on the same carbon atom in case of 1,1-dichloroethane, they are present in the adjacent carbon atoms in case of 1,2-dichloroethane. So we can oxidize both the compounds and 1,1-dichloroethane will form acetaldehyde while 1,2-dichloroethane will form ethan-1,2-diol. There is a particular reagent which can be used to distinguish between these two and it gives a yellow precipitate in presence of aldehydes.

> ${ NaHSO }_{ 3 }$ It is known as Sodium bisulfite is a weakly acidic compound. It is usually used as a mild reducing agent, so typically used as an aqueous solution.
> The reaction of ${ 1,1-dichloroethane }$ and ${ 1,2-dichloroethane }$ with ${ 2,4-DNP }$ firstly, and then aqueous KOH won’t occur as ${ 2,4-DNP }$ is used to differentiate between an aldehyde and a ketone, so firstly when aqueous KOH reacts with these compounds then geminal diol will be formed. Hence, this is not the correct option.
> When ${ 1,1-dichloroethane }$ reacts with aq. KOH then ethanal will be produced which is a pungent-smelling aldehyde which when further reacts with ${ 2,4-DNP }$ then ${ 2,4-dinitrophenylhydrazine }$ will be produced which is insoluble and yellow colored precipitate.
When ${ 1,2-dichloroethane }$ reacts with aq. KOH then ${ ethan-1,2diol }$ will be produced which is odorless and when it reacts with ${ 2,4-DNP }$ then no precipitate formation occurs.
Therefore, we can say that we can differentiate ${ 1,1-dichloroethane }$ and ${ 1,2-dichloroethane }$ from aq. KOH and then ${ 2,4-DNP }$.