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What is an alpha, beta – unsaturated ketone?

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Last updated date: 13th Jul 2024
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Answer
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Hint: When any functional group is attached in a compound, then the carbon atom that is adjacent to that functional group is called alpha carbon and the hydrogen atoms on that carbon are alpha hydrogen. The carbon that is attached with alpha carbon is called the beta carbon and its hydrogen atoms are beta hydrogen.

Complete answer:
A ketone consists of the functional group called carbonyl group as$\left( -\overset{O}{\mathop{\overset{||}{\mathop{C}}\,}}\,- \right)$. This group is present in the middle of the carbon chain. The carbon attached with the carbon of this carbonyl group is called an alpha – carbon, while the carbon which is attached with the alpha carbon is called the beta – carbon. When a compound contains a double bond at this $\alpha ,\beta $- carbon alongside with the ketone group, then the compound is called an alpha, beta – unsaturated compound. The general structural formula for $\alpha ,\beta $- unsaturated ketone is,
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Where R are the alkyl groups
$\alpha ,\beta $- unsaturated ketones are formed as a result of ketol condensation that consist of reacting two ketones same or different in presence of a dilute alkali, which forms a ketol intermediate having an alcohol and a ketone group that on heating produces$\alpha ,\beta $- unsaturated ketone.
An example of self ketol condensation, where both ketones are same (propanone) is:
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An example of cross ketol condensation, where both are different ketone is,
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Hence, an alpha, beta – unsaturated ketone has a double bond on $\alpha ,\beta $- carbon adjacent to the ketone group.

Note:
For the molecules to undergo ketone reaction, it is important that the ketones possess alpha hydrogen, which are the hydrogens present on the carbon which is attached with the ketone group. Alpha hydrogen is acidic and attached with electron withdrawing groups, so the anion formed is stabilized by resonance.