Answer
405k+ views
Hint: The answer here is based on the concept of calculating equivalent weight based on the definition and the formula which is given by $Eq.Wt.=\dfrac{M}{n-factor}$ and by finding n- factor according to reaction gives you the required answer.
Complete step – by – step solution:
We have come across the chapters in physical chemistry that is based on several measurement techniques like conductometry, potentiometry, iodometry etc.
- Now, let us see what does iodometry means and how is equivalent weight calculated in this technique.
- Iodometry or which is also known as iodimetric titration is a method of volumetric analysis where the appearance or disappearance of iodine indicates the end point and it is the redox reaction.
The reaction is as follows,
$26{{H}^{+}}+3{{S}_{2}}Ol3+4C{{r}_{2}}{{O}_{7}}^{2-}\to 6S{{O}_{4}}^{2-}+8C{{r}^{3+}}+13{{H}_{2}}O$
Here, in ${{K}_{2}}C{{r}_{2}}{{O}_{7}}(C{{r}_{2}}{{O}_{7}}^{2-})$, chromium is in +6 oxidation state and in the product it changes to +3 state.
Thus, there is net change of +3 in oxidation state.
Now, the net change in oxidation per formula is from $4C{{r}_{2}}{{O}_{7}}^{2-}$ to $8C{{r}^{3+}}$ is 2
Thus, net change for oxidation = $2\times 3=+6$
Thus, n-factor = +6
Now according to the formula of equivalent weight, $Eq.Wt.=\dfrac{M}{n-factor}$ where M is the molecular weight.
Substituting values, we have$Eq.Wt.=\dfrac{M}{6}$
Therefore, the correct answer is option B) mol.wt./6
Note: There are chances to be confused between iodometry and iodimetry. Here, iodometry involves indirect titration of the iodine that is liberated by the reaction with that of analyte and iodimetry involves direct titration using iodine itself as the titrant.
Complete step – by – step solution:
We have come across the chapters in physical chemistry that is based on several measurement techniques like conductometry, potentiometry, iodometry etc.
- Now, let us see what does iodometry means and how is equivalent weight calculated in this technique.
- Iodometry or which is also known as iodimetric titration is a method of volumetric analysis where the appearance or disappearance of iodine indicates the end point and it is the redox reaction.
The reaction is as follows,
$26{{H}^{+}}+3{{S}_{2}}Ol3+4C{{r}_{2}}{{O}_{7}}^{2-}\to 6S{{O}_{4}}^{2-}+8C{{r}^{3+}}+13{{H}_{2}}O$
Here, in ${{K}_{2}}C{{r}_{2}}{{O}_{7}}(C{{r}_{2}}{{O}_{7}}^{2-})$, chromium is in +6 oxidation state and in the product it changes to +3 state.
Thus, there is net change of +3 in oxidation state.
Now, the net change in oxidation per formula is from $4C{{r}_{2}}{{O}_{7}}^{2-}$ to $8C{{r}^{3+}}$ is 2
Thus, net change for oxidation = $2\times 3=+6$
Thus, n-factor = +6
Now according to the formula of equivalent weight, $Eq.Wt.=\dfrac{M}{n-factor}$ where M is the molecular weight.
Substituting values, we have$Eq.Wt.=\dfrac{M}{6}$
Therefore, the correct answer is option B) mol.wt./6
Note: There are chances to be confused between iodometry and iodimetry. Here, iodometry involves indirect titration of the iodine that is liberated by the reaction with that of analyte and iodimetry involves direct titration using iodine itself as the titrant.
Recently Updated Pages
How many sigma and pi bonds are present in HCequiv class 11 chemistry CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Why Are Noble Gases NonReactive class 11 chemistry CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Let X and Y be the sets of all positive divisors of class 11 maths CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Let x and y be 2 real numbers which satisfy the equations class 11 maths CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Let x 4log 2sqrt 9k 1 + 7 and y dfrac132log 2sqrt5 class 11 maths CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Let x22ax+b20 and x22bx+a20 be two equations Then the class 11 maths CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Trending doubts
Fill the blanks with the suitable prepositions 1 The class 9 english CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
At which age domestication of animals started A Neolithic class 11 social science CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Which are the Top 10 Largest Countries of the World?
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Give 10 examples for herbs , shrubs , climbers , creepers
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Difference between Prokaryotic cell and Eukaryotic class 11 biology CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Difference Between Plant Cell and Animal Cell
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Write a letter to the principal requesting him to grant class 10 english CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Change the following sentences into negative and interrogative class 10 english CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Fill in the blanks A 1 lakh ten thousand B 1 million class 9 maths CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)