Answer
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Hint: Knowing the scientific name of Hinsberg’s reagent will help. It is an aromatic compound with a sulfonyl group.
Complete step-by-step answer:
Hinsberg’s reagent is used to distinguish between primary, secondary and tertiary amines. Its chemical formula is benzene sulphonyl chloride (${{C}_{6}}{{H}_{5}}S{{O}_{2}}Cl$). Its structure is as below:
The correct answer for the above question is option (A)${{C}_{6}}{{H}_{5}}S{{O}_{2}}Cl$.
Additional information:
Let’s know more about the reactions using Hinsberg’s reagent that distinguish the amines of different degrees.
- When a primary amine says ethyl amine reacts with this reagent, we get $N-methylbenzenesulfonamide$. This product is soluble in alkali due to the highly acidic hydrogen atom which is shown in red here:
- When a secondary amine reacts with this reagent, there is no hydrogen atom left in the product which is $N,N-diethyl benzene sulphonamide$. Therefore the product is not soluble in alkali. The reaction is as below:
- Tertiary amines do not react with benzene sulphonyl chloride.
In this way we can separate or distinguish primary, secondary and tertiary amines.
Note: In case of primary amines, when it is said that a product will dissolve in any solution, it just means that a reaction will take place and no precipitate will be left behind. If this is an acid-base reaction, as is the above case, we can get back the reactants if we want to. In this way we can separate our required compound from a mixture.
In case of secondary amines, the alkali cannot react with the product formed. This means there will be no reaction taking place when the alkali is added.
Complete step-by-step answer:
Hinsberg’s reagent is used to distinguish between primary, secondary and tertiary amines. Its chemical formula is benzene sulphonyl chloride (${{C}_{6}}{{H}_{5}}S{{O}_{2}}Cl$). Its structure is as below:
The correct answer for the above question is option (A)${{C}_{6}}{{H}_{5}}S{{O}_{2}}Cl$.
Additional information:
Let’s know more about the reactions using Hinsberg’s reagent that distinguish the amines of different degrees.
- When a primary amine says ethyl amine reacts with this reagent, we get $N-methylbenzenesulfonamide$. This product is soluble in alkali due to the highly acidic hydrogen atom which is shown in red here:
- When a secondary amine reacts with this reagent, there is no hydrogen atom left in the product which is $N,N-diethyl benzene sulphonamide$. Therefore the product is not soluble in alkali. The reaction is as below:
- Tertiary amines do not react with benzene sulphonyl chloride.
In this way we can separate or distinguish primary, secondary and tertiary amines.
Note: In case of primary amines, when it is said that a product will dissolve in any solution, it just means that a reaction will take place and no precipitate will be left behind. If this is an acid-base reaction, as is the above case, we can get back the reactants if we want to. In this way we can separate our required compound from a mixture.
In case of secondary amines, the alkali cannot react with the product formed. This means there will be no reaction taking place when the alkali is added.
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