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The CFSE for octahedral [CoCl6]4 is 18,000 cm1. The CFSE for tetrahedral [CoCl4]2 will be:

Answer
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Hint: Draw the CFSE diagram for[CoCl6]4 and [CoCl4]2 to understand the difference in splitting of orbitals in case of octahedral and tetrahedral geometry. Apply the formula given below to find the CFSE for the tetrahedral complex.
Formula: Δt=49Δo
Where,
Δt is the CFSE for tetrahedral complex,
 Δo is the CFSE for an octahedral complex.

Complete step by step answer:
Let us try to understand the crystal field theory.
-The Crystal Field Theory (CFT) is a model for the bonding interaction between transition metal atoms and ligands.
-It describes the attraction between the positive charge of the metal cation and negative charge on the non-bonding electrons of the ligand.
-When the ligands approach the central metal ion, the degeneracy of electronic orbitals (usually d or f orbitals) are broken due to the static electric field produced by the surrounding charge distribution.
CFSE (Crystal field stabilisation energy) is the calculation of energy of a complex compound. When ligands attack the metal ion the d-orbitals of metal loses their degeneracy and split into two groups i.e. eg(dz2,dx2y2) and t2g(dxy,dyz,dxz).
If electron enters the eg orbitals it destabilizes the complex and if electron enters the t2g orbitals it stabilizes the complex in case of an octahedral complex . The below diagrams will help you understand the splitting of orbitals.
For an octahedral complex:

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We will now apply the formula given above to find the CFSE of the tetrahedral complex.
Δt=49Δo
The CFSE for octahedral complex, [CoCl6]4 is given as 18,000 cm1. Substituting the value of Δo in the equation:
Δt=49.18000cm1
Δt=8000cm1
The CFSE for [CoCl4]2is 8000cm1.
So, the correct answer is “Option C”.

Note: The CFSE for octahedral and tetrahedral complexes are not equal because the splitting of orbitals happens differently for the two types of complex as given in the diagram. In case of tetrahedral complex, electrons entering the t2g orbitals destabilise the complex and entering eg orbitals stabilize the complex.