
How do diastereomers differ from optical isomers?
Answer
540k+ views
Hint: Stereoisomers is the class of isomers under which enantiomers and diastereomers are present. Diastereomers are the compounds which are not mirror images of each other and are non-superimposable. The enantiomers are the mirror image of each other and are non-superimposable.
Complete step by step answer:
When two molecules are stereoisomers which means they possess the same molecular formula, same connectivity but different arrangement of atoms but are not enantiomers then they are considered as diastereomers.
The diastereomers have different physical properties like melting points, boiling point, solubilities. Diastereomers other than geometrical isomers may or may not be optically active. Diastereomers show similar but not identical chemical properties.
Optical isomers are two compounds which contain the same number and kinds of atoms, and bonds but differ in the arrangement of the atoms but are non-superimposable mirror images of each other. Each non-superimposable mirror image structure is called an enantiomer. Molecules or ions that are present in optical isomers are called chiral.
The optical isomers are optically active as they rotate the plane of plane polarized light which is passed through the sample of enantiomers.
Difference can be given in table form as shown below.
Note:
It is not compulsory for a compound to be optically active if it contains a chiral center. Diastereomers contain two or chiral centers but are not able to rotate the plane polarized light as they are superimposable on each other.
Complete step by step answer:
When two molecules are stereoisomers which means they possess the same molecular formula, same connectivity but different arrangement of atoms but are not enantiomers then they are considered as diastereomers.
The diastereomers have different physical properties like melting points, boiling point, solubilities. Diastereomers other than geometrical isomers may or may not be optically active. Diastereomers show similar but not identical chemical properties.
Optical isomers are two compounds which contain the same number and kinds of atoms, and bonds but differ in the arrangement of the atoms but are non-superimposable mirror images of each other. Each non-superimposable mirror image structure is called an enantiomer. Molecules or ions that are present in optical isomers are called chiral.
The optical isomers are optically active as they rotate the plane of plane polarized light which is passed through the sample of enantiomers.
Difference can be given in table form as shown below.
| Diastereomers | Optical isomers |
| Diastereomers come under the class of isomers known as stereoisomers. | Optical isomers come under optical isomerism. |
| contain one or more chiral center | Contain optical center |
| May or may not be optically active | They are optically active |
| They are not enantiomers | Optical isomers are enantiomers |
| Superimposable mirror image | Non-superimposable mirror image |
Note:
It is not compulsory for a compound to be optically active if it contains a chiral center. Diastereomers contain two or chiral centers but are not able to rotate the plane polarized light as they are superimposable on each other.
Recently Updated Pages
The number of solutions in x in 02pi for which sqrt class 12 maths CBSE

Write any two methods of preparation of phenol Give class 12 chemistry CBSE

Differentiate between action potential and resting class 12 biology CBSE

Two plane mirrors arranged at right angles to each class 12 physics CBSE

Which of the following molecules is are chiral A I class 12 chemistry CBSE

Name different types of neurons and give one function class 12 biology CBSE

Trending doubts
State the principle of an ac generator and explain class 12 physics CBSE

Sketch the electric field lines in case of an electric class 12 physics CBSE

Derive an expression for electric potential at point class 12 physics CBSE

What is virtual and erect image ?

Explain the formation of energy bands in solids On class 12 physics CBSE

Draw a neat and well labeled diagram of TS of ovary class 12 biology CBSE

