Decomposition brought about by heat is known as thermal decomposition. What is the difference between thermal dissociation and thermal decomposition?
Answer
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Hint: Heating any substance can cause it to decompose or be transformed into ions of its constituent atoms. Thermal decomposition is a type of chemical decomposition that occurs when heat is applied. Thermolysis is another name for it. Compounds decompose during thermal decomposition to produce two or more products from a single reactant. When calcium carbonate is heated, it decomposes into calcium oxide and carbon dioxide gas.
Complete answer:
Thermal dissociation is the breaking down of a chemical into smaller compounds or components by the action of heat, which then recombine to form the original compound in the absence of heat. As a result, thermal dissociation is a sort of thermal degradation that is reversible in nature.
Note:
Examples-
Zinc carbonate decomposes into zinc oxide and carbon dioxide when heated. The molecule decomposes into two simple components, zinc oxide and carbon dioxide, in this example of heat breakdown.
\[ZnC{O_3} \to ZnO + C{O_2}\]
When heated, ammonium chloride dissociates into ammonia and hydrogen chloride. The following is a chemical reaction for the same.
\[N{H_4}Cl \rightleftharpoons N{H_3} + HCl\]
When ammonium chloride is heated, two chemicals are formed: \[\left[ {N{H_3}} \right]\] and \[\left[ {HCl} \right]\]. On cooling, this reaction mixture comprising \[\left[ {N{H_3}} \right]\] and \[\left[ {HCl} \right]\] reacts to generate \[\left[ {N{H_4}Cl} \right]\]. Thermal breakdown happens here, however due to the reversible nature of the chemical process, it is classified as thermal dissociation.
Complete answer:
Thermal dissociation is the breaking down of a chemical into smaller compounds or components by the action of heat, which then recombine to form the original compound in the absence of heat. As a result, thermal dissociation is a sort of thermal degradation that is reversible in nature.
| THERMAL DISSOCIATION | THERMAL DECOMPOSITION |
| It is a chemical process in which heat is used to break down molecules into cation and anion ions, but the reaction is reversible. | It is a type of chemical degradation that occurs as a result of heat. |
| Thermodynamic dissociation is a one-step procedure. | The process of thermal breakdown is multi-step. |
| In nature, it is usually reversible since the compounds generated during dissociation react again to produce reactants. When the reaction mixture containing the products cools, this happens. | It could be either reversible or irreversible. On cooling, products may or may not react to generate reactants. |
Note:
Examples-
Zinc carbonate decomposes into zinc oxide and carbon dioxide when heated. The molecule decomposes into two simple components, zinc oxide and carbon dioxide, in this example of heat breakdown.
\[ZnC{O_3} \to ZnO + C{O_2}\]
When heated, ammonium chloride dissociates into ammonia and hydrogen chloride. The following is a chemical reaction for the same.
\[N{H_4}Cl \rightleftharpoons N{H_3} + HCl\]
When ammonium chloride is heated, two chemicals are formed: \[\left[ {N{H_3}} \right]\] and \[\left[ {HCl} \right]\]. On cooling, this reaction mixture comprising \[\left[ {N{H_3}} \right]\] and \[\left[ {HCl} \right]\] reacts to generate \[\left[ {N{H_4}Cl} \right]\]. Thermal breakdown happens here, however due to the reversible nature of the chemical process, it is classified as thermal dissociation.
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