Courses for Kids
Free study material
Offline Centres
Store Icon

Anhydrous $ AlCl_3 $ is used in Friedel-Crafts reaction because it is
(A) Soluble in ether
(B) Ionisable to Al and Cl ions
(C) Electron rich
(D) Electron deficient molecule

Last updated date: 23rd Jul 2024
Total views: 349.2k
Views today: 5.49k
349.2k+ views
Hint : $ AlCl_3 $ behaves as a Lewis acid in the Friedel-Crafts reaction, which enables the reaction to go forward. It is a catalyst in this reaction. The Friedel-Crafts reaction is a set of reactions where an alkyl or acyl group is added to a benzene molecule by an electrophilic aromatic substitution.

Complete Step By Step Answer:
The electrophile attacks the pi electrons to form a nonaromatic carbocation.
For this reaction to occur, an electron acceptor is required.
Anhydrous $ AlCl_3 $ ionises to form $ Al^(3+) $ and $ 3Cl^- $ ions. Therefore, it is capable of accepting electrons and acts as a Lewis acid.
A Lewis acid is any substance that can accept a pair of nonbonding electrons. It is an electron-pair acceptor. Such as $ AlCl_3 $ in this question.
Being an electron-acceptor implies that there are vacant spots available in the shell of $ AlCl_3 $ for it to accept electrons. Thus, it is electron deficient.
 $ AlCl_3 $ accepts Cl and converts to $ AlCl_4^- $ therefore the organic compound from which Cl had been removed becomes an electrophile.
An electrophile is a molecule that forms a bond to its nucleophile by accepting both bonding electrons from that reaction partner (nucleophile).
Therefore, for this question, the correct answer is (D). $ AlCl_3 $ is used in Friedel-Crafts reaction because it is an electron deficient molecule.

Note :
In contrast, Lewis bases are substances that donate a pair of nonbonding electrons. Such questions can be tricky to answer as they are very specific. But, by knowing the organic compound reactions – such as Friedel-Crafts reaction – such questions can be answered. Also, thoroughly learn about the various reagents used/recommended for such specific organic compound reactions mentioned in the text.