
Which one of the following reductions with lithium aluminium hydride yield a secondary amine?
A.Nitroethane
B.Methyl isocyanide
C.Acetamide
D.Methyl cyanide
Answer
486.3k+ views
Hint: Alkyl isocyanide on reduction with lithium aluminium hydride forms a secondary amine containing methyl as one of the alkyl groups. It involves a catalytic reduction. Methyl isocyanide, also known as iso cyanomethane is an organic compound and a member of the isocyanide family and it is a colourless liquid.
Complete answer:
On catalytic reduction or with lithium aluminium hydride ( ) or with the nascent hydrogen, alkyl isocyanide yields 2-degree amine whereas cyanide gives 1-degree amine on reduction.
Two hydrogen molecules are added across triple bonds.
Therefore, the correct answer is option (B).
Note: Methyl isocyanide which is also known as iso cyanomethane, it is an organic compound and a member of the isocyanide family. It is a colourless liquid which is isomeric to methyl cyanide (acetonitrile), but its reactivity is very different. Its molar mass is 41.053 g/mole. Its Melting point is − ( ; 228 K) The application of Methyl isocyanide is mainly for making 5-membered heterocyclic rings. The C-N distance in methyl isocyanide is very short, as is characteristic of isocyanides. Methyl isocyanide was first prepared by A. Gautier by the reaction of silver cyanide with methyl iodide. The common method for preparing methyl isocyanides is by dehydrating N-methyl formamide. Many metal cyanides react with methylating agents to form complexes of methyl isocyanide. This type of reactivity has been invoked as being relevant to the origin of life.
Methyl isocyanide is very useful for the preparation of diverse heterocycles. It is often used to prepare transition metal isocyanide complexes.
Complete answer:
On catalytic reduction or with lithium aluminium hydride (


Two hydrogen molecules are added across
Therefore, the correct answer is option (B).
Note: Methyl isocyanide which is also known as iso cyanomethane, it is an organic compound and a member of the isocyanide family. It is a colourless liquid which is isomeric to methyl cyanide (acetonitrile), but its reactivity is very different. Its molar mass is 41.053 g/mole. Its Melting point is −
Methyl isocyanide is very useful for the preparation of diverse heterocycles. It is often used to prepare transition metal isocyanide complexes.
Latest Vedantu courses for you
Grade 10 | CBSE | SCHOOL | English
Vedantu 10 CBSE Pro Course - (2025-26)
School Full course for CBSE students
₹37,300 per year
Recently Updated Pages
Master Class 12 Business Studies: Engaging Questions & Answers for Success

Master Class 12 Economics: Engaging Questions & Answers for Success

Master Class 12 Maths: Engaging Questions & Answers for Success

Master Class 12 Biology: Engaging Questions & Answers for Success

Master Class 12 Physics: Engaging Questions & Answers for Success

Master Class 11 Accountancy: Engaging Questions & Answers for Success

Trending doubts
Father of Indian ecology is a Prof R Misra b GS Puri class 12 biology CBSE

Who is considered as the Father of Ecology in India class 12 biology CBSE

Enzymes with heme as prosthetic group are a Catalase class 12 biology CBSE

A deep narrow valley with steep sides formed as a result class 12 biology CBSE

An example of ex situ conservation is a Sacred grove class 12 biology CBSE

Why is insulin not administered orally to a diabetic class 12 biology CBSE
