Questions & Answers

Which of the following will have metal deficiency defects?

Answer Verified Verified
Hint: Metal deficiency defects are caused due to missing cations. So, one of the nearest metal ions acquires an extra positive charge to maintain electrical neutrality and to do so the metal ion must be able to exhibit variable valency.

Complete step by step answer:
-It is a type of non-stoichiometric defect which comes under point defects. It means that this defect does not affect the stoichiometry of the crystalline compound.
-Metal deficiency defect arises due to a vacant lattice site caused by missing cation. Thus one of the nearest metal ions will acquire an extra positive charge to prevent or maintain the electrical neutrality of the crystalline compound.

-This type of defect is usually shown by compounds that exhibit variable valance like the transition metal compounds like NiO, FeS, FeO, etc because they have the ability to take extra positive charge.
-Many crystalline solids which are very difficult to be prepared in the stoichiometric composition and thus the amount of metal they contain is less as compared to the stoichiometric proportions.
-An example of such solids is FeO. The composition of FeO may range from $F{e_{0.93}}O$ to $F{e_{0.96}}O$. But usually it is found with a composition of $F{e_{0.95}}O$. In FeO crystals some $F{e^{ + 2}}$ ions are missing, so this loss of positive ions is made up by turning some $F{e^{ + 2}}$ ions into $F{e^{ + 3}}$ ions.
-Since, this defect can only be shown by compounds exhibiting variable valency state. In the given options the only metal exhibiting variable valency state is Fe (iron).

So, the correct option is: B) FeO.

Metal deficiency means cationic vacancies and not anionic because metals have the ability to lose electrons and gain positive charge to become a cation. They cannot gain electrons to become an anion.