Answer
Verified
396.6k+ views
Hint: Metal deficiency defects are caused due to missing cations. So, one of the nearest metal ions acquires an extra positive charge to maintain electrical neutrality and to do so the metal ion must be able to exhibit variable valency.
Complete step by step answer:
-It is a type of non-stoichiometric defect which comes under point defects. It means that this defect does not affect the stoichiometry of the crystalline compound.
-Metal deficiency defect arises due to a vacant lattice site caused by missing cation. Thus one of the nearest metal ions will acquire an extra positive charge to prevent or maintain the electrical neutrality of the crystalline compound.
-This type of defect is usually shown by compounds that exhibit variable valance like the transition metal compounds like NiO, FeS, FeO, etc because they have the ability to take extra positive charge.
-Many crystalline solids which are very difficult to be prepared in the stoichiometric composition and thus the amount of metal they contain is less as compared to the stoichiometric proportions.
-An example of such solids is FeO. The composition of FeO may range from $F{e_{0.93}}O$ to $F{e_{0.96}}O$. But usually it is found with a composition of $F{e_{0.95}}O$. In FeO crystals some $F{e^{ + 2}}$ ions are missing, so this loss of positive ions is made up by turning some $F{e^{ + 2}}$ ions into $F{e^{ + 3}}$ ions.
-Since, this defect can only be shown by compounds exhibiting variable valency state. In the given options the only metal exhibiting variable valency state is Fe (iron).
So, the correct option is: B) FeO.
Note:
Metal deficiency means cationic vacancies and not anionic because metals have the ability to lose electrons and gain positive charge to become a cation. They cannot gain electrons to become an anion.
Complete step by step answer:
-It is a type of non-stoichiometric defect which comes under point defects. It means that this defect does not affect the stoichiometry of the crystalline compound.
-Metal deficiency defect arises due to a vacant lattice site caused by missing cation. Thus one of the nearest metal ions will acquire an extra positive charge to prevent or maintain the electrical neutrality of the crystalline compound.
-This type of defect is usually shown by compounds that exhibit variable valance like the transition metal compounds like NiO, FeS, FeO, etc because they have the ability to take extra positive charge.
-Many crystalline solids which are very difficult to be prepared in the stoichiometric composition and thus the amount of metal they contain is less as compared to the stoichiometric proportions.
-An example of such solids is FeO. The composition of FeO may range from $F{e_{0.93}}O$ to $F{e_{0.96}}O$. But usually it is found with a composition of $F{e_{0.95}}O$. In FeO crystals some $F{e^{ + 2}}$ ions are missing, so this loss of positive ions is made up by turning some $F{e^{ + 2}}$ ions into $F{e^{ + 3}}$ ions.
-Since, this defect can only be shown by compounds exhibiting variable valency state. In the given options the only metal exhibiting variable valency state is Fe (iron).
So, the correct option is: B) FeO.
Note:
Metal deficiency means cationic vacancies and not anionic because metals have the ability to lose electrons and gain positive charge to become a cation. They cannot gain electrons to become an anion.
Recently Updated Pages
Basicity of sulphurous acid and sulphuric acid are
Three beakers labelled as A B and C each containing 25 mL of water were taken A small amount of NaOH anhydrous CuSO4 and NaCl were added to the beakers A B and C respectively It was observed that there was an increase in the temperature of the solutions contained in beakers A and B whereas in case of beaker C the temperature of the solution falls Which one of the following statements isarecorrect i In beakers A and B exothermic process has occurred ii In beakers A and B endothermic process has occurred iii In beaker C exothermic process has occurred iv In beaker C endothermic process has occurred
What is the stopping potential when the metal with class 12 physics JEE_Main
The momentum of a photon is 2 times 10 16gm cmsec Its class 12 physics JEE_Main
How do you arrange NH4 + BF3 H2O C2H2 in increasing class 11 chemistry CBSE
Is H mCT and q mCT the same thing If so which is more class 11 chemistry CBSE
Trending doubts
Difference Between Plant Cell and Animal Cell
Difference between Prokaryotic cell and Eukaryotic class 11 biology CBSE
Fill the blanks with the suitable prepositions 1 The class 9 english CBSE
Change the following sentences into negative and interrogative class 10 english CBSE
Summary of the poem Where the Mind is Without Fear class 8 english CBSE
Give 10 examples for herbs , shrubs , climbers , creepers
Write an application to the principal requesting five class 10 english CBSE
What organs are located on the left side of your body class 11 biology CBSE
What is the z value for a 90 95 and 99 percent confidence class 11 maths CBSE