
Which of the following does not undergo alcohol condensation?
(A)
(B)
(C)
(D)
Answer
415.5k+ views
Hint: Aldol condensation reaction is the characteristic reaction of all aldehyde and ketones which have at least one hydrogen atom. Aldol condensation is carried out in the presence of dilute alkali in order to form hydroxy aldehyde or hydroxy ketone as a final product.
Complete Step By Step Answer:
During the aldol condensation reaction the hydrogen atom of the compound reacts with hydroxide ion generated by alkali to form an enolate ion as an intermediate.
hydrogen atom is an atom which is attached to an adjacent carbon of a functional group containing carbon.
The formed enolate ion further reacts with the carbonyl group of another molecule of aldehyde or ketone to form an anion. This anion further abstracts the proton from the water present as solvent to form the aldol or ketol.
As in the case of formaldehyde there is no carbon adjacent to the carbonyl carbon.
Therefore no hydrogen atom is present in it. Hence, does not give an aldol condensation reaction.
As in the case of acetaldehyde there is one carbon adjacent to carbonyl carbon and having three hydrogen atoms. Therefore, it reacts in the presence of alkali to produce aldol.
The final product formed by aldol condensation of acetaldehyde is hydroxy butanal.
As in the case of acetone there are two carbons adjacent to the carbonyl carbon and having total six hydrogen atoms. Therefore, it reacts with alkali to produce the aldol.
The final product formed by aldol condensation of acetone is hydroxy pentan- one.
Similarly in the case of propionaldehyde there are two carbons adjacent to the carbonyl carbon and having total six hydrogen atoms. Therefore, it reacts with alkali to produce the aldol.
The final product formed by aldol condensation of propionaldehyde is methyl hydroxy pentanaldehyde.
Formaldehyde does not give aldol condensation reaction.
Hence, option is the correct option.
Note:
hydroxy aldehyde is commonly known as aldol and hydroxy ketone is commonly known as ketol. Aldol condensation is coming under the category of self-condensation reaction.
Complete Step By Step Answer:
During the aldol condensation reaction the
The formed enolate ion further reacts with the carbonyl group of another molecule of aldehyde or ketone to form an anion. This anion further abstracts the proton from the water present as solvent to form the aldol or ketol.
As in the case of formaldehyde
Therefore no
As in the case of acetaldehyde

The final product formed by aldol condensation of acetaldehyde is
As in the case of acetone there are two carbons adjacent to the carbonyl carbon and having total six

The final product formed by aldol condensation of acetone is
Similarly in the case of propionaldehyde

The final product formed by aldol condensation of propionaldehyde is
Hence, option
Note:
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