Question

The soap molecule has a:
A) Hydrophilic head and a hydrophobic tail
B) Hydrophobic head and a hydrophilic tail
C) Hydrophobic head and a hydrophobic tail
D) Hydrophilic head and a hydrophilic tail

Answer 1

Hint: The soap are water-soluble compounds that are derivative of fatty acid. In aqueous solution, they break down in soap anion and cation. The soap anion has a polar head and the tail is a large hydrocarbon chain. It is non-polar and water-repelling in nature.


Complete step by step answer:
Soaps or detergents are the large hydrocarbon chains. This is a derivative of fatty acid. The soap has a large hydrocarbon tail and a negative charge head.
The soap in solution dissolves into soap anions and sodium cations. For example sodium palmitate
$\text{ }\begin{matrix}
   \text{C}{{\text{H}}_{\text{3}}}{{\text{(C}{{\text{H}}_{\text{2}}}\text{)}}_{\text{14}}}\text{COO-N}{{\text{a}}^{\text{+}}} & \to & \text{C}{{\text{H}}_{\text{3}}}{{\text{(C}{{\text{H}}_{\text{2}}}\text{)}}_{\text{14}}}\text{COO-} & \text{+} & \text{N}{{\text{a}}^{\text{+}}} \\
   \text{(Sodium palmitate)} & {} & \text{Palmitate ion} & {} & \text{Sodium ion} \\
\end{matrix}$

The hydrocarbon tail is made of the long carbon chain and it is nonpolar. Since it is a carbon chain it doesn’t have the affinity towards the water. Therefore, it is also called the hydrophobic end (or water-hating or repelling). It is readily soluble in oil and grease.
 The sops are fatty acid derivatives therefore one end of the hydrocarbon chain bonded to the carboxylic acid $\text{(}-\text{CO}{{\text{O}}^{-}}\text{N}{{\text{a}}^{\text{+}}})$ , therefore the negatively charged head is polar. It has a great affinity towards the water. It is also known as the hydrophilic end (water-loving). It is readily soluble in water.
Therefore, the soap molecule has a hydrophilic head and a hydrophobic tail


Hence, (A) is the correct option.

Additional information:
In aqueous solution, water molecules are polar thus they surround the head of the molecule and repel the hydrocarbon tail. Therefore when soap or detergent is dissolved in water, the molecules associate to form a cluster of molecules called as the micelles as shown below,

In cleansing, the micelles are arranged in such a way that the hydrophobic tail (hydrocarbon chain) is attached to the oily dirt and the hydrophilic head is moving outward. When the water is shaken vigorously the oily dirt is displaced from the surface and dissociates into the fragments. Thus, more hydrophobic tails can be attached to the oil that prevent the further aggregation of the molecule and removes the dirt from the fabric.


Note: The micelle is a unique capacity of a soap anion to aggregate in solution. They are uniquely oriented such that the hydrophilic head is outward and the hydrophobic tail is inward towards the oil.