Question

The correct order of $ + I$ effect is-
A. $ - CO{O^ - } > - {O^ - } > - N{H^ - } > - C{H_2}^ - $
B. $ - C{H_2}^ - > - {O^ - } > - CO{O^ - } > - C{\left( {C{H_3}} \right)_3}$
C. $ - C{\left( {C{H_3}} \right)_3} > - {O^ - } > - CO{O^ - } > - N{H^ - }$
D. $ - {O^ - } > - CO{O^ - } > - C{\left( {C{H_3}} \right)_3} > - N{H^ - }$

Answer 1

Hint- Inductive effect: At the point when an electron-discharging or an electron-pulling back species is acquainted with a chain of atoms (for the most part a carbon chain), the comparing negative or positive charge is transferred through the carbon chain by the atoms having a place with it. This makes a permanent dipole emerge in the molecule and is alluded to as the inductive effect.

Complete answer:
Kinds of Inductive Effect-
Negative inductive effect or $ - I$ effect
Positive inductive effect or $ + I$ effect
$ - I$ Effect (Negative Inductive Effect)
At the point when an electronegative particle, for example, a halogen, is acquainted with a chain of atoms (by and large carbon atoms), the subsequent unequal sharing of electrons creates a positive charge which is transferred through the chain.
This makes a permanent dipole emerge in the molecule wherein the electronegative atom holds a negative charge and the comparing effect is known as the electron withdrawing inductive effect, or the $ - I$ effect.
$ + I$ Effect (Positive Inductive Effect)
At the point when a chemical species with the inclination to release or donate electrons, for example, an alkyl group, is acquainted with a carbon chain, the charge is handed-off through the chain and this effect is known as the Positive Inductive Effect or the $ + I$ Effect.

Hence, option D is the correct option.

Note: Inductive effect decreases in the order as there is unequal sharing of the bonding electron through a chain of atoms in a molecule.