
The amine that reacts with to give oily yellow liquid is:
[A] Ethyl amine.
[B] Dimethyl amine.
[C] Isopropyl amine.
[D] Secondary butyl amine.
Answer
510k+ views
Hint: In presence of sodium nitrite and hydrochloric acid, amines undergo diazotization. Primary amines form a mixture of products and secondary amines cannot complete the diazotization reaction and gives us an oily yellow liquid. Here, the correct answer is a secondary amine.
Complete answer:
The reagent given to us is sodium nitrite which is an inorganic compound and we use it in industrial chemistry for the formation of diazo compounds from amines which is used for the preparation of various diazo dyes.
A diazo group is an organic group which consists of two nitrogen atoms linked together in the terminal position. The nitrogen atoms are termed –azo groups therefore the name di-azo.
An amine will undergo diazotization when it reacts with sodium nitrite in presence of hydrochloric acid.
When we react with a primary amine with sodium nitrite we get an unstable salt of ethyl diazonium chloride. The salt is unstable thus decomposes into a cation and reacts with any nucleophile present in the solution and gives us a mixture of alcohol, alkene and alkyl halides none of which is an oily yellow liquid.
Primary amines are the amines having only one carbon attached to a nitrogen atom.
We can draw the structures of the given amines as –
As we can see from the above diagram, among the given options, ethyl amine, secondary butyl amine and isopropyl amine are primary amines. Therefore, neither of them is the correct option.
All the primary amines will give a mixture of alcohol, alkyl halides and alkenes thus we are left with dimethyl amine so let's discuss its reaction with sodium nitrite and hydrochloric acid.
As we can see in the above reaction, when dimethyl amine undergoes diazotization, we get N-nitrosodimethylamine which is an oily yellow liquid.
So, the correct answer is “Option B”.
Note: Primary amines give us a diazonium salt which forms alcohols in addition to water but secondary amines have one hydrogen atom attached to them therefore, they cannot complete the diazotization reaction and give us a yellow oily nitrosamine product. Three degree amines have no hydrogen atoms attached to them thus they undergo simple acid- base reactions and give us soluble salts.
Complete answer:
The reagent given to us is sodium nitrite which is an inorganic compound and we use it in industrial chemistry for the formation of diazo compounds from amines which is used for the preparation of various diazo dyes.
A diazo group is an organic group which consists of two nitrogen atoms linked together in the terminal position. The nitrogen atoms are termed –azo groups therefore the name di-azo.
An amine will undergo diazotization when it reacts with sodium nitrite in presence of hydrochloric acid.
When we react with a primary amine with sodium nitrite we get an unstable salt of ethyl diazonium chloride. The salt is unstable thus decomposes into a cation and reacts with any nucleophile present in the solution and gives us a mixture of alcohol, alkene and alkyl halides none of which is an oily yellow liquid.
Primary amines are the amines having only one carbon attached to a nitrogen atom.
We can draw the structures of the given amines as –

As we can see from the above diagram, among the given options, ethyl amine, secondary butyl amine and isopropyl amine are primary amines. Therefore, neither of them is the correct option.
All the primary amines will give a mixture of alcohol, alkyl halides and alkenes thus we are left with dimethyl amine so let's discuss its reaction with sodium nitrite and hydrochloric acid.

As we can see in the above reaction, when dimethyl amine undergoes diazotization, we get N-nitrosodimethylamine which is an oily yellow liquid.
So, the correct answer is “Option B”.
Note: Primary amines give us a diazonium salt which forms alcohols in addition to water but secondary amines have one hydrogen atom attached to them therefore, they cannot complete the diazotization reaction and give us a yellow oily nitrosamine product. Three degree amines have no hydrogen atoms attached to them thus they undergo simple acid- base reactions and give us soluble salts.
Recently Updated Pages
Earth rotates from West to east ATrue BFalse class 6 social science CBSE

The easternmost longitude of India is A 97circ 25E class 6 social science CBSE

Write the given sentence in the passive voice Ann cant class 6 CBSE

Convert 1 foot into meters A030 meter B03048 meter-class-6-maths-CBSE

What is the LCM of 30 and 40 class 6 maths CBSE

What is history A The science that tries to understand class 6 social science CBSE

Trending doubts
Father of Indian ecology is a Prof R Misra b GS Puri class 12 biology CBSE

Who is considered as the Father of Ecology in India class 12 biology CBSE

Enzymes with heme as prosthetic group are a Catalase class 12 biology CBSE

A deep narrow valley with steep sides formed as a result class 12 biology CBSE

An example of ex situ conservation is a Sacred grove class 12 biology CBSE

Why is insulin not administered orally to a diabetic class 12 biology CBSE
