
Stephen’s reduction converts nitriles into:
(A) aldehydes
(B) ketones
(C) amines
(D) carboxylic acids
Answer
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Hint: Think about the reagent that is used during this reaction. This will give you an idea about the mechanism of the reaction and how the product is formed. Consider the alternative name for the reaction.
Complete step by step solution:
In this reaction, the reagent that is used is stannous chloride in the presence of hydrochloric acid. These reagents reduce the carbon atom that is present in the nitrile group. The first step of this reaction involved the formation of the intermediate compound which is an imine. This amine then undergoes hydrolysis to give us the product.
Nitrile compounds have the structure . Here, the represents the alkyl group that is present with the nitrile functional group. The Stephen’s reagent is given by . Using this information, the general reaction is:
Here, we can see that an aldehyde is formed, but the detailed mechanism is still not apparent. The mechanism for this reaction is:
Here, we can see that the alkyl nitrile continuously reacts with stannous chloride and hydrochloric acid to form an imine. This imine is then converted into a tin complex which immediately decomposes to form and the amine is converted into an amide by hydrolysis. Thus, an aldehyde is formed.
Hence, the correct answer to this question is ‘A. aldehydes’
Note: Note that this aldehyde usually further reacts with a hydronium ion and gets oxidized to form a carboxylic acid. But this is not a part of Stephen’s Reduction reaction whose alternative name is Stephen’s Aldehyde Synthesis. So, Stephen’s reduction does not form carboxylic acids.
Complete step by step solution:
In this reaction, the reagent that is used is stannous chloride in the presence of hydrochloric acid. These reagents reduce the carbon atom that is present in the nitrile group. The first step of this reaction involved the formation of the intermediate compound which is an imine. This amine then undergoes hydrolysis to give us the product.
Nitrile compounds have the structure
Here, we can see that an aldehyde is formed, but the detailed mechanism is still not apparent. The mechanism for this reaction is:

Here, we can see that the alkyl nitrile continuously reacts with stannous chloride and hydrochloric acid to form an imine. This imine is then converted into a tin complex which immediately decomposes to form
Hence, the correct answer to this question is ‘A. aldehydes’
Note: Note that this aldehyde usually further reacts with a hydronium ion and gets oxidized to form a carboxylic acid. But this is not a part of Stephen’s Reduction reaction whose alternative name is Stephen’s Aldehyde Synthesis. So, Stephen’s reduction does not form carboxylic acids.
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