Reduction of alkyl nitrites yields
A.alcohol
B.base
C.amine
D.acid
Answer
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Hint: Any of a class of chemical reactions that increase the number of electrons associated with an atom or a group of atoms. The electrons taken up by the reduced substance are supplied by another substance, which is oxidized as a result. See also the oxidation-reduction reaction.
Complete answer:
Alkyl nitrites are a class of chemical compounds with the molecular formula \[R-ONO\]. Formally, they are nitrous acid alkyl esters. They differ from nitro compounds \[R-N{{O}_{2}}\].
The first few members of the series are volatile liquids; at room temperature and pressure, methyl nitrite and ethyl nitrite are gaseous. The compounds emit a distinct fruity aroma. Amyl nitrite is another commonly encountered nitrite (3-methyl butyl nitrite).
Alkyl nitrites were and still are widely used as medications and chemical reagents, a practice that dates back to the late 1800s. They are frequently inhaled as medicine to relieve angina and other heart-related symptoms of the disease. Alkyl nitrites, on the other hand, are recreational drugs when referred to as "poppers."
In a sulfuric acid solution, alcohols and sodium nitrite are converted into organic nitrites. They decompose slowly when left alone, with the decomposition products being nitrogen oxides, water, alcohol, and polymerization products of the aldehyde. They are also susceptible to homolytic cleavage to form alkyl radicals, owing to the very weak nitrite bond \[C-O\] (on the order of \[40-50\]\[Kcal.mo{{l}^{-1}}\]).
The reduction of alkyl nitrites yields Alcohol. The reaction is given as follows,
\[\underset{{}}{\mathop{R-O-N}}\,=O+6\left[ H \right]\xrightarrow{Sn/HCL}\underset{Alcohol}{\mathop{ROH}}\,+N{{H}_{3}}+{{H}_{2}}O\]
Thus, the answer is option A: Alcohol.
Note:
Amyl nitrite is used in medicine as an antidote to cyanide poisoning. The light alkyl nitrites cause the formation of methemoglobin, which combines with the cyanide to form nontoxic cyanmethemoglobin as an effective antidote to cyanide poisoning. Typically, first responders carry a cyanide poison kit containing amyl nitrite.
Complete answer:
Alkyl nitrites are a class of chemical compounds with the molecular formula \[R-ONO\]. Formally, they are nitrous acid alkyl esters. They differ from nitro compounds \[R-N{{O}_{2}}\].
The first few members of the series are volatile liquids; at room temperature and pressure, methyl nitrite and ethyl nitrite are gaseous. The compounds emit a distinct fruity aroma. Amyl nitrite is another commonly encountered nitrite (3-methyl butyl nitrite).
Alkyl nitrites were and still are widely used as medications and chemical reagents, a practice that dates back to the late 1800s. They are frequently inhaled as medicine to relieve angina and other heart-related symptoms of the disease. Alkyl nitrites, on the other hand, are recreational drugs when referred to as "poppers."
In a sulfuric acid solution, alcohols and sodium nitrite are converted into organic nitrites. They decompose slowly when left alone, with the decomposition products being nitrogen oxides, water, alcohol, and polymerization products of the aldehyde. They are also susceptible to homolytic cleavage to form alkyl radicals, owing to the very weak nitrite bond \[C-O\] (on the order of \[40-50\]\[Kcal.mo{{l}^{-1}}\]).
The reduction of alkyl nitrites yields Alcohol. The reaction is given as follows,
\[\underset{{}}{\mathop{R-O-N}}\,=O+6\left[ H \right]\xrightarrow{Sn/HCL}\underset{Alcohol}{\mathop{ROH}}\,+N{{H}_{3}}+{{H}_{2}}O\]
Thus, the answer is option A: Alcohol.
Note:
Amyl nitrite is used in medicine as an antidote to cyanide poisoning. The light alkyl nitrites cause the formation of methemoglobin, which combines with the cyanide to form nontoxic cyanmethemoglobin as an effective antidote to cyanide poisoning. Typically, first responders carry a cyanide poison kit containing amyl nitrite.
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