
Predict the alkanes obtained by
-The action of sodium metal on n-propyl chloride
-catalytic hydrogenation of isobutylene.
Answer
528.3k+ views
Hint:In the first case, wurtz reaction takes place in which two alkyl chloride combines to form a single alkane, hexene.
Double bond breaks to form a single bond due to addition of hydrogen.
Complete step by step answer:
When sodium metal reacts with n-propyl chloride, it results in a formation of n-hexane and the reaction is known as wurtz reaction.
$2{C_3}{H_7}Cl\xrightarrow{{Na}}{C_6}{H_{14}}$
Here in the given reaction two alkyl chloride combines and forms a single alkane ( hexane ) as a major product.
Thus the above reaction leads to the formation of hexane.
Catalytic hydrogenation of isobutylene leads to the formation of isobutene as a major product.
$CH = {C_3}{H_5}\xrightarrow[{Pt}]{{{H^{^ + }}/Pd}}{C_4}{H_8}$
In the given reaction there is addition of hydrogen in place of alkene bond.
Thus the above reaction leads to the formation of isobutene.
Additional Information:
Wurtz reaction: It is a coupling reaction of two compounds in organic chemistry, in which two alkyl halides in reaction with sodium metal in solution of dry ether forms a higher alkane. In this reaction sodium metal is treated in a solution of dry ether to produce higher alkanes.
Catalytic hydrogenation: Catalytic hydrogenation is addition of hydrogen to a compound with a double or triple bond with the help of catalyst. The given compound gets reduced and leaves lesser bonds between the carbons. The process of catalytic hydrogenation uses a metal catalyst such as palladium, nickel or platinum.
Note:
It is a simple wurtz reaction. You just need to have clear knowledge of organic chemistry.
Hydrogen, platinum and palladium just act as catalysts. Don’t include them in the main reaction.
Double bond breaks to form a single bond due to addition of hydrogen.
Complete step by step answer:
When sodium metal reacts with n-propyl chloride, it results in a formation of n-hexane and the reaction is known as wurtz reaction.
$2{C_3}{H_7}Cl\xrightarrow{{Na}}{C_6}{H_{14}}$
Here in the given reaction two alkyl chloride combines and forms a single alkane ( hexane ) as a major product.
Thus the above reaction leads to the formation of hexane.
Catalytic hydrogenation of isobutylene leads to the formation of isobutene as a major product.
$CH = {C_3}{H_5}\xrightarrow[{Pt}]{{{H^{^ + }}/Pd}}{C_4}{H_8}$
In the given reaction there is addition of hydrogen in place of alkene bond.
Thus the above reaction leads to the formation of isobutene.
Additional Information:
Wurtz reaction: It is a coupling reaction of two compounds in organic chemistry, in which two alkyl halides in reaction with sodium metal in solution of dry ether forms a higher alkane. In this reaction sodium metal is treated in a solution of dry ether to produce higher alkanes.
Catalytic hydrogenation: Catalytic hydrogenation is addition of hydrogen to a compound with a double or triple bond with the help of catalyst. The given compound gets reduced and leaves lesser bonds between the carbons. The process of catalytic hydrogenation uses a metal catalyst such as palladium, nickel or platinum.
Note:
It is a simple wurtz reaction. You just need to have clear knowledge of organic chemistry.
Hydrogen, platinum and palladium just act as catalysts. Don’t include them in the main reaction.
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