
Grignard reagent is obtained when magnesium is treated with:
A.alkyl halide in the presence of alcohol
B.alkyl halide in the presence of phenol
C.alkyl halide in the presence of dry ether
D.alkyl halide in the presence of alcoholated ether
Answer
560.7k+ views
Hint:
Grignard reagents are extremely good nucleophiles, reacting with electrophiles like carbonyl compounds (aldehydes, ketones, esters, greenhouse gas, etc) and epoxides. They’re also very strong bases and might react with acidic hydrogens (such as alcohols, water, and carboxylic acids).
Complete step by step answer:
Grignard reagents form via the reaction of an alkyl or aryl halide with magnesium metal. The reaction is conducted by adding the organic halide to a suspension of magnesium in an ethereal solvent, which provides ligands required to stabilize the organomagnesium compound. The halide could also be all ( chlorine, bromine, iodine) except fluorine. It’s slightly easier to make Grignard from the iodides and bromides. The halide is that the “X” observed after we talk over Grignard reagents as “$RMgX$”.
The ether in the presence of which the reaction takes place is also called diethyl ether. It is synthesised by dehydration of ethanol using sulphuric acid.
The chemical action for the assembly of Grignard reagent is as follows:
$\,R - X + Mg\xrightarrow{{dryether}}R - Mg - X\,$ (Grignard reagent)
(Grignard reagent)
So the correct answer is option C.
Note: One in every of the foremost common uses of Grignard reagents is in their reaction with aldehydes and ketones to create alcohols. Grignard Reagents also react with Ketones to grant Tertiary Alcohols. Another important reaction of Grignard reagents is that they are visiting raise epoxides to make carbon-carbon bonds. Grignard reagents also increase carbon dioxide to create carboxylates, during a very reaction like their reactions with ketones and aldehydes. The carboxylates are converted to carboxylic acids after addition of acid. Within the reaction of Grignards with aldehydes, the carbon attacks the carbonyl carbon and performs a $\,1,2 - $ addition to grant an alkoxide. In the second step, acid is added to grant you the alcohol.
Grignard reagents are extremely good nucleophiles, reacting with electrophiles like carbonyl compounds (aldehydes, ketones, esters, greenhouse gas, etc) and epoxides. They’re also very strong bases and might react with acidic hydrogens (such as alcohols, water, and carboxylic acids).
Complete step by step answer:
Grignard reagents form via the reaction of an alkyl or aryl halide with magnesium metal. The reaction is conducted by adding the organic halide to a suspension of magnesium in an ethereal solvent, which provides ligands required to stabilize the organomagnesium compound. The halide could also be all ( chlorine, bromine, iodine) except fluorine. It’s slightly easier to make Grignard from the iodides and bromides. The halide is that the “X” observed after we talk over Grignard reagents as “$RMgX$”.
The ether in the presence of which the reaction takes place is also called diethyl ether. It is synthesised by dehydration of ethanol using sulphuric acid.
The chemical action for the assembly of Grignard reagent is as follows:
$\,R - X + Mg\xrightarrow{{dryether}}R - Mg - X\,$ (Grignard reagent)
(Grignard reagent)
So the correct answer is option C.
Note: One in every of the foremost common uses of Grignard reagents is in their reaction with aldehydes and ketones to create alcohols. Grignard Reagents also react with Ketones to grant Tertiary Alcohols. Another important reaction of Grignard reagents is that they are visiting raise epoxides to make carbon-carbon bonds. Grignard reagents also increase carbon dioxide to create carboxylates, during a very reaction like their reactions with ketones and aldehydes. The carboxylates are converted to carboxylic acids after addition of acid. Within the reaction of Grignards with aldehydes, the carbon attacks the carbonyl carbon and performs a $\,1,2 - $ addition to grant an alkoxide. In the second step, acid is added to grant you the alcohol.
Recently Updated Pages
The number of solutions in x in 02pi for which sqrt class 12 maths CBSE

Write any two methods of preparation of phenol Give class 12 chemistry CBSE

Differentiate between action potential and resting class 12 biology CBSE

Two plane mirrors arranged at right angles to each class 12 physics CBSE

Which of the following molecules is are chiral A I class 12 chemistry CBSE

Name different types of neurons and give one function class 12 biology CBSE

Trending doubts
Which are the Top 10 Largest Countries of the World?

What are the major means of transport Explain each class 12 social science CBSE

Differentiate between insitu conservation and exsitu class 12 biology CBSE

Draw a labelled sketch of the human eye class 12 physics CBSE

State the principle of an ac generator and explain class 12 physics CBSE

Give 10 examples of unisexual and bisexual flowers

