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Explain the following:
a. Answer the following -
i. How do you convert benzoic acid to benzamide? Write the reaction.
ii. Complete the reaction:
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b. What happens when carbonyl compounds are treated with hydrazine? Write the reaction.

Answer
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Hint: The first question will be solved by using simple acid base reaction followed by heating. The second part of question ‘a’ is Gatterman Koch reaction. Hydrazine given to us in question ‘b’ refers to NH2NH2.

Complete answer:
In the classes of organic chemistry, we have studied the basic concepts such as some of the named concepts and also some of the basic reactions.
Let us see in detail about the above reaction given and find the related answers.
a).
i. Conversion of benzoic acid to benzamide can be done by the following reaction –
PhCOOH+NH3PhCOONH4+ΔPhCONH2+H2O
As we can see, benzoic acid on reaction with ammonia leads to the formation of ammonium salt which on heating decomposes it further forms benzamide.
ii. The reagents and substrate given in the question is used in Gatterman Koch reaction. It is used for the preparation of Benzaldehyde from benzene using CO and HCl.
Therefore, the complete reaction will be –
C6H6anhy.AlCl3/HClCOHClC6H5CHO
or this can also be shown as,
seo images

Here, in Gutterman-Koch reaction, aromatic compounds are formulated by a mixture of carbon monoxide and acid in the presence of anhydrous aluminium chloride where electrophilic substitution reaction occurs to give the aldehydes.

b). When carbonyl compounds are treated with hydrazine, ‘hydrazone derivatives’ are formed. The reaction is as given below –
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Here, hydrazine is more nucleophilic than a regular amine because of the presence of an adjacent nitrogen.

Note:
Note that the Guttermann-Koch reaction is not applicable to phenols and phenol ethers even if they are aromatic because they can be successfully formulated at atmospheric pressure in benzene as a solvent.
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