
Derive an expression for the magnetic dipole moment of a revolving electron.
Answer
515.1k+ views
Hint: In this question,we apply the concept of dipole moment and concept of orbital motion.
Complete step by step answer:
As indicated by Bohr's atom model, the negatively charged electron is rotating around a positively charged nucleus in a circular orbit of radius. The spinning electron in a closed path establishes an electric flow. The movement of the electron in an anticlockwise way produces current in the clockwise direction.
Currently,\[I = \dfrac{e}{T}\], where T is the period of revolution of the electron.
If v is the orbital velocity of the electron, then
\[T = \dfrac{{2\pi r}}{v}\]
\[\therefore \]\[i = \dfrac{{ev}}{{2\pi r}}\]
Due to the orbital motion of the electron, there will be orbital magnetic moment \[\mathop \mu \nolimits_i \]
\[\mathop \mu \nolimits_i = iA\] Where A is the area of the orbit
\[\begin{gathered}
\mathop \mu \nolimits_i = \dfrac{{ev}}{{2\pi r}} \cdot \pi {r^2} \\
\mathop \mu \nolimits_i = \dfrac{{evr}}{2} \\
\end{gathered} \]
If m is the mass of the electron,
Multiply denominator and numerator with m
\[\mathop \mu \nolimits_i = \dfrac{e}{{2m}} \cdot \left( {mvr} \right)\]
Mr is the angular momentum \[\left( L \right)\] of the electron about the central nucleus.
\[\mathop \mu \nolimits_i = \dfrac{e}{{2m}} \cdot L\]- - - - - - - - - - - - - - - \[\left( 1 \right)\]
\[\dfrac{{\mathop \mu \nolimits_i }}{L} = \dfrac{e}{{2m}}\]
Where \[\dfrac{{\mathop \mu \nolimits_i }}{L}\] is the gyromagnetic ratio and it is constant. Its value is \[8.8{\text{ }} \times {\text{ }}{10^{10\;}}C{\text{ }}k{g^{ - 1}}\]Bohr hypothesized that the angular momentum has only discrete set of values given by the equation.
\[L = \dfrac{{nh}}{{2\pi }}\] - - - - - - - - - - - - - - - \[\left( 2 \right)\]
Where n is a natural number and h is the Planck’s constant \[ = 6.626{\text{ }} \times {\text{ }}{10^{ - 34}}\;Js.\]
Substituting equation \[\left( 2 \right)\;\] in equation \[\left( 1 \right)\]
\[\mathop \mu \nolimits_i = \dfrac{e}{{2m}} \cdot \dfrac{{nh}}{{2\pi }}\]
\[ = \dfrac{{neh}}{{4\pi m}}\] - - - - - - - - - - - \[\left( 3 \right)\]
The minimum value of magnetic moment is
\[{\left( {\mathop \mu \nolimits_i } \right)_{\min }} = \dfrac{{eh}}{{4\pi m}}\] , Where \[n{\text{ }} = {\text{ }}1\]
The value of \[\dfrac{{eh}}{{4\pi m}}\]is called Bohr magneton.
By substituting the values of \[e,{\text{ }}h\;\] and \[m,\] the value of Bohr magneton is found to be \[9.27{\text{ }} \times {\text{ }}{10^{-24}}\;A{m^2}\].
Note:Always remember the exact value of Bohr magneton because it is useful in solving various types of numerical problems and also keep proper knowledge of orbital motion.
Complete step by step answer:
As indicated by Bohr's atom model, the negatively charged electron is rotating around a positively charged nucleus in a circular orbit of radius. The spinning electron in a closed path establishes an electric flow. The movement of the electron in an anticlockwise way produces current in the clockwise direction.
Currently,\[I = \dfrac{e}{T}\], where T is the period of revolution of the electron.
If v is the orbital velocity of the electron, then
\[T = \dfrac{{2\pi r}}{v}\]
\[\therefore \]\[i = \dfrac{{ev}}{{2\pi r}}\]
Due to the orbital motion of the electron, there will be orbital magnetic moment \[\mathop \mu \nolimits_i \]
\[\mathop \mu \nolimits_i = iA\] Where A is the area of the orbit
\[\begin{gathered}
\mathop \mu \nolimits_i = \dfrac{{ev}}{{2\pi r}} \cdot \pi {r^2} \\
\mathop \mu \nolimits_i = \dfrac{{evr}}{2} \\
\end{gathered} \]
If m is the mass of the electron,
Multiply denominator and numerator with m
\[\mathop \mu \nolimits_i = \dfrac{e}{{2m}} \cdot \left( {mvr} \right)\]
Mr is the angular momentum \[\left( L \right)\] of the electron about the central nucleus.
\[\mathop \mu \nolimits_i = \dfrac{e}{{2m}} \cdot L\]- - - - - - - - - - - - - - - \[\left( 1 \right)\]
\[\dfrac{{\mathop \mu \nolimits_i }}{L} = \dfrac{e}{{2m}}\]
Where \[\dfrac{{\mathop \mu \nolimits_i }}{L}\] is the gyromagnetic ratio and it is constant. Its value is \[8.8{\text{ }} \times {\text{ }}{10^{10\;}}C{\text{ }}k{g^{ - 1}}\]Bohr hypothesized that the angular momentum has only discrete set of values given by the equation.
\[L = \dfrac{{nh}}{{2\pi }}\] - - - - - - - - - - - - - - - \[\left( 2 \right)\]
Where n is a natural number and h is the Planck’s constant \[ = 6.626{\text{ }} \times {\text{ }}{10^{ - 34}}\;Js.\]
Substituting equation \[\left( 2 \right)\;\] in equation \[\left( 1 \right)\]
\[\mathop \mu \nolimits_i = \dfrac{e}{{2m}} \cdot \dfrac{{nh}}{{2\pi }}\]
\[ = \dfrac{{neh}}{{4\pi m}}\] - - - - - - - - - - - \[\left( 3 \right)\]
The minimum value of magnetic moment is
\[{\left( {\mathop \mu \nolimits_i } \right)_{\min }} = \dfrac{{eh}}{{4\pi m}}\] , Where \[n{\text{ }} = {\text{ }}1\]
The value of \[\dfrac{{eh}}{{4\pi m}}\]is called Bohr magneton.
By substituting the values of \[e,{\text{ }}h\;\] and \[m,\] the value of Bohr magneton is found to be \[9.27{\text{ }} \times {\text{ }}{10^{-24}}\;A{m^2}\].
Note:Always remember the exact value of Bohr magneton because it is useful in solving various types of numerical problems and also keep proper knowledge of orbital motion.
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