Answer
Verified
395.4k+ views
Hint: Clemmensen reduction is a chemical reaction for the reduction of ketones or aldehydes to alkanes using zinc amalgam and concentrated HCl. Fehling’s solution besides Tollen’s reagent is used to differentiate between reducing and non reducing sugars.
Complete answer:
- Tollen’s reagent is a chemical reagent used to identify the presence of aldehyde, aromatic aldehyde, and alpha-hydroxy ketone functional groups.
- Fehling is a deep blue alkaline solution which is used to determine the presence of aldehyde or ketone groups.
- Clemenson reductions are effective at reducing aryl-alkyl ketones.
-Since the compound, A with molecular formula ${{C}_{3}}{{H}_{6}}O$ is not reduced by Tollen’s reagent and Fehling’s solution and is undergoing Clemmensen reduction, so it must be ketone (acetone).
-Acetone is further reacted with conc. ${{H}_{2}}S{{O}_{4}}$ with and distilled water gives Mesitylene which is the compound C. It has the molecular formula as ${{C}_{9}}{{H}_{12}}$ and is an aromatic compound.
Note: You may get confused about compound A thinking it as aldehyde or ketone because the Clemmensen reaction is the reduction reaction for both aldehyde and ketone. Since compound A is not giving any reaction with Tollen’s reagent and Fehling’s solution, this cancels out the chances of compound A being an aldehyde.
Complete answer:
- Tollen’s reagent is a chemical reagent used to identify the presence of aldehyde, aromatic aldehyde, and alpha-hydroxy ketone functional groups.
- Fehling is a deep blue alkaline solution which is used to determine the presence of aldehyde or ketone groups.
- Clemenson reductions are effective at reducing aryl-alkyl ketones.
-Since the compound, A with molecular formula ${{C}_{3}}{{H}_{6}}O$ is not reduced by Tollen’s reagent and Fehling’s solution and is undergoing Clemmensen reduction, so it must be ketone (acetone).
-Acetone is further reacted with conc. ${{H}_{2}}S{{O}_{4}}$ with and distilled water gives Mesitylene which is the compound C. It has the molecular formula as ${{C}_{9}}{{H}_{12}}$ and is an aromatic compound.
Note: You may get confused about compound A thinking it as aldehyde or ketone because the Clemmensen reaction is the reduction reaction for both aldehyde and ketone. Since compound A is not giving any reaction with Tollen’s reagent and Fehling’s solution, this cancels out the chances of compound A being an aldehyde.
Recently Updated Pages
Basicity of sulphurous acid and sulphuric acid are
Three beakers labelled as A B and C each containing 25 mL of water were taken A small amount of NaOH anhydrous CuSO4 and NaCl were added to the beakers A B and C respectively It was observed that there was an increase in the temperature of the solutions contained in beakers A and B whereas in case of beaker C the temperature of the solution falls Which one of the following statements isarecorrect i In beakers A and B exothermic process has occurred ii In beakers A and B endothermic process has occurred iii In beaker C exothermic process has occurred iv In beaker C endothermic process has occurred
What is the stopping potential when the metal with class 12 physics JEE_Main
The momentum of a photon is 2 times 10 16gm cmsec Its class 12 physics JEE_Main
How do you arrange NH4 + BF3 H2O C2H2 in increasing class 11 chemistry CBSE
Is H mCT and q mCT the same thing If so which is more class 11 chemistry CBSE
Trending doubts
Difference Between Plant Cell and Animal Cell
Difference between Prokaryotic cell and Eukaryotic class 11 biology CBSE
What is BLO What is the full form of BLO class 8 social science CBSE
Change the following sentences into negative and interrogative class 10 english CBSE
Fill the blanks with the suitable prepositions 1 The class 9 english CBSE
The cell wall of prokaryotes are made up of a Cellulose class 9 biology CBSE
What organs are located on the left side of your body class 11 biology CBSE
Select the word that is correctly spelled a Twelveth class 10 english CBSE
a Tabulate the differences in the characteristics of class 12 chemistry CBSE