
Assertion
$HN{O_3}$ is stronger acid than $HN{O_2}$.
Reason
In $HN{O_3}$ there is two nitrogen to oxygen bonds whereas in $HN{O_2}$ there is only one.
A.Both Assertion and Reason are correct and the reason is the correct explanation for Assertion
B.Both Assertion and Reason are correct but the reason is not the correct explanation for the assertion.
C.The assertion is correct but the Reason is incorrect
D.The assertion is incorrect but Reason is correct
Answer
561.3k+ views
Hint:
In chemistry, there are many acids and bases that exist with their different properties. Some are strong and some are weak according to their pH values. According to Bronsted-Lowry acid-base theory, we got conjugate acid and conjugate base.
Complete answer:
Bronsted-Lowry acid-base - When acid and base react, the acid forms its conjugate base and the base forms its conjugate acid.
Conjugate acid - When acid donates \[{H^ + }\]ion to the base is known as conjugate acid.
Conjugate base - When protons are removed from acid.
We have two acids $HN{O_3}$ and $HN{O_2}$
Here, the conjugate base of $HN{O_3}$ is \[N{O_3}^ - \] and conjugate base of $HN{O_2}$ is $N{O_2}^ - $ .
$N{O_3}^ - $ is a more stable conjugate base than $N{O_2}^ - $ . And strong acid has a stable conjugate base.
Therefore, $HN{O_3}$ is stronger than $HN{O_2}$ . So, the assertion is correct.
$HN{O_3}$ - \[H - \mathop {\mathop O\limits^{..} }\limits_{..} - \mathop {\mathop {\mathop {\mathop N\limits_| }\limits_O }\limits^{||} }\limits^O \] $HN{O_2}$ - \[H - \mathop {\mathop O\limits^{..} }\limits_{..} - \mathop {\mathop N\limits^{||} }\limits^O \]
Here, $HN{O_3}$ has three nitrogen to oxygen bonds while $HN{O_2}$ has two nitrogen to oxygen bonds. Therefore, the reason is incorrect.
So, option C is the correct answer here.
Note:Bronsted-Lowry theory was given by Johannes Nicolaus Bronsted and Thomas Martin Lowry in 1923. A cation can be a conjugate acid and an anion can be a conjugate base. The strength of conjugate acid is directly proportional to the dissociation constant.
In chemistry, there are many acids and bases that exist with their different properties. Some are strong and some are weak according to their pH values. According to Bronsted-Lowry acid-base theory, we got conjugate acid and conjugate base.
Complete answer:
Bronsted-Lowry acid-base - When acid and base react, the acid forms its conjugate base and the base forms its conjugate acid.
Conjugate acid - When acid donates \[{H^ + }\]ion to the base is known as conjugate acid.
Conjugate base - When protons are removed from acid.
We have two acids $HN{O_3}$ and $HN{O_2}$
Here, the conjugate base of $HN{O_3}$ is \[N{O_3}^ - \] and conjugate base of $HN{O_2}$ is $N{O_2}^ - $ .
$N{O_3}^ - $ is a more stable conjugate base than $N{O_2}^ - $ . And strong acid has a stable conjugate base.
Therefore, $HN{O_3}$ is stronger than $HN{O_2}$ . So, the assertion is correct.
$HN{O_3}$ - \[H - \mathop {\mathop O\limits^{..} }\limits_{..} - \mathop {\mathop {\mathop {\mathop N\limits_| }\limits_O }\limits^{||} }\limits^O \] $HN{O_2}$ - \[H - \mathop {\mathop O\limits^{..} }\limits_{..} - \mathop {\mathop N\limits^{||} }\limits^O \]
Here, $HN{O_3}$ has three nitrogen to oxygen bonds while $HN{O_2}$ has two nitrogen to oxygen bonds. Therefore, the reason is incorrect.
So, option C is the correct answer here.
Note:Bronsted-Lowry theory was given by Johannes Nicolaus Bronsted and Thomas Martin Lowry in 1923. A cation can be a conjugate acid and an anion can be a conjugate base. The strength of conjugate acid is directly proportional to the dissociation constant.
Recently Updated Pages
The number of solutions in x in 02pi for which sqrt class 12 maths CBSE

Write any two methods of preparation of phenol Give class 12 chemistry CBSE

Differentiate between action potential and resting class 12 biology CBSE

Two plane mirrors arranged at right angles to each class 12 physics CBSE

Which of the following molecules is are chiral A I class 12 chemistry CBSE

Name different types of neurons and give one function class 12 biology CBSE

Trending doubts
Which are the Top 10 Largest Countries of the World?

What are the major means of transport Explain each class 12 social science CBSE

Draw a labelled sketch of the human eye class 12 physics CBSE

Differentiate between insitu conservation and exsitu class 12 biology CBSE

State the principle of an ac generator and explain class 12 physics CBSE

Differentiate between homogeneous and heterogeneous class 12 chemistry CBSE

