
Approximate pH of 0.1 M aqueous solution when and for at 25 are and respectively?
Answer
504.9k+ views
1 likes
Hint: is a dibasic acid i.e. can release two protons per molecule of . The pH of will include the equilibrium constant of both the deprotonation reaction. However, it is important to decide the significance of second equilibrium constant as it has a very low and insignificant value. Based on this you can find the final for and then the pH as well.
Complete step-by-step answer:
Hydrogen sulphide is the chemical compound having the molecular formula . It is a colourless chalcogen hydride gas having the characteristic smell of rotten eggs. It is a highly corrosive and poisonous substance which is easily flammable. Hydrogen sulphide is slightly denser than air. A mixture of hydrogen sulphide and air can be highly explosive. It acts as a reducing agent especially in presence of its conjugate base. Hydrogen sulphide exists as a gas at 298 K temperature. When we observe the values of first dissociation constant and second dissociation constant, it is seen that the main dissociation happens at the first deprotonation only. So, we will consider the second dissociation as insignificant as it is lower than the concentration of hydrogen ions in neutral water.
The dissociation in terms of concentration of products and reactants can be written as,
From the above set of reactions, we can conclude that the pH for 0.1 M hydrogen sulfide is 4.
Therefore, the correct answer is option (A).
Note: It is important to know that we do not consider the dissociation reactions, whose reaction constant is less than that of water. This is because the reaction will never take place.
Complete step-by-step answer:
Hydrogen sulphide is the chemical compound having the molecular formula
The dissociation in terms of concentration of products and reactants can be written as,
From the above set of reactions, we can conclude that the pH for 0.1 M hydrogen sulfide is 4.
Therefore, the correct answer is option (A).
Note: It is important to know that we do not consider the dissociation reactions, whose reaction constant is less than that of water. This is because the reaction will never take place.
Recently Updated Pages
Master Class 11 Business Studies: Engaging Questions & Answers for Success

Master Class 11 Economics: Engaging Questions & Answers for Success

Master Class 11 Accountancy: Engaging Questions & Answers for Success

Master Class 11 Computer Science: Engaging Questions & Answers for Success

Master Class 11 English: Engaging Questions & Answers for Success

Master Class 11 Maths: Engaging Questions & Answers for Success

Trending doubts
Which one is a true fish A Jellyfish B Starfish C Dogfish class 11 biology CBSE

The flightless birds Rhea Kiwi and Emu respectively class 11 biology CBSE

Difference Between Prokaryotic Cells and Eukaryotic Cells

1 ton equals to A 100 kg B 1000 kg C 10 kg D 10000 class 11 physics CBSE

One Metric ton is equal to kg A 10000 B 1000 C 100 class 11 physics CBSE

How much is 23 kg in pounds class 11 chemistry CBSE
